云桌面技术在高职院校的运用与推广分析

基于计算机信息技术的高速发展,高校实验室对协同作业与资源自适应调配等个性化需求日益增加.针对传统计算机实验室在建设与维护过程中的存在一些弊端,如:前期投入成本高、设备整体利用率低、管理效率低、数据安全性与网络传输效率较差等客观问题,文章将对现有教学资源及需求进行分析,结合云桌面技术优势,论证云桌面技术可行性研究,推动实...     

高阶表面结构刚挠结合印制板制作技术

高阶表面结构刚挠结合印制电路板集合了混压设计,不对称设计等特点,且挠性板在外层,导致开窗处高度差较大,这一特点给制作增添了较大难度.本文选取此类典型刚挠结合板产品,分享部分关键制作技术.     

Bifunctional Edge-Rich Nitrogen Doped Porous Carbon for Activating Oxygen and Sulfur

Oxygen reduction reaction (ORR) and sulfur reduction reaction (SRR) play key roles in advanced batteries. However, they both suffer from sluggish reaction kinetics. Here, an interesting nitrogen doped porous carbon material that can simultaneously activate oxygen and sulfur is reported. The carbon precursor is a nitrogen containing covalent organic framework (COF), constituting periodically stacked 2D sheets. The COF structure is well preserved upon pyrolysis, resulting in the formation of edge-rich porous carbon with structure resembling stacked holey graphene. The nitrogen containing groups in the COF are decomposed into graphitic and pyridinic nitrogen during pyrolysis. These edge sites and uniform nitrogen doping endow the carbon product with high intrinsic catalytic activities toward ORR and SRR. The COF derived carbon delivers outstanding performances when assembling as cathodes in the Li-S and Li-O₂ batteries. Simultaneous activation of oxygen and sulfur also enables a new battery chemistry. A proof-of-concept Li-S/O₂ hybrid battery is assembled, delivering a large specific capacity of 2,013 mAh g⁻¹. This study may inspire novel battery designs based on oxygen and sulfur chemistry.     

Doped/Undoped A1-A2 Typed Copolymers as ETLs for Highly Efficient Organic Solar Cells

The electron transport layer (ETL) is a critical component in achieving high device performance and stability in organic solar cells. Conjugated polyelectrolytes (CPEs) have become an attractive alternative due to film-forming properties and ease of preparation. However, p-type CPEs generally exhibit poor charge mobility and conductivity, incorporation of electron-withdrawing units forming alternated D-A conjugated backbone can make up for these deficiencies. Herein, the ratio of electron withdrawing moieties are further increased and two poly(A1-alt-A2) typed PIIDNDI-Br and PDPPNDI-Br based on the combination of naphthalene diimide (NDI) with isoindigo (IID) or diketopyrrolopyrrole (DPP) via direct arylation polycondensation are synthesized. These CPEs possess excellent alcohol solubility, a suitable lowest unocuppied molecular orbital energy level, and work function tunability. Surprisingly, the incorporation of IID and DPP units generate distinct self-doping behaviors, which are confirmed by UV–vis absorption and ESR spectra. However, no matter doped or undoped, both CPEs present better charge-transporting properties and conductivity when utilized as ETLs. The PIIDNDI-Br and PDPPNDI-Br display good universal compatibility with the blend of PM6:Y6 and PM6:L8-BO, and PCEs of 18.32% and 18.36% are obtained, respectively, which also present excellent storage stability. In short, the combination of two different acceptors demonstrates an efficient strategy to design highly efficient ETLs for high performance photovoltaic devices.     

Macro-Sized All-Graphene 3D Structures via Layer-by-Layer Covalent Growth for Micro-to-Macro Inheritable Electrical Performances

Creating 3D-engineered macroscopic architectures while inheriting the superior properties of individual building blocks remains one of the fundamental challenges in nanotechnology. Stable covalent interconnection between micro/nanoblocks is a desired but underexplored strategy to meet the challenges, rather than current dependently-used weak physical forces or organic cross-linking, which disrupts the continuity of chemical composition and electrical properties. Herein, a novel layer-by-layer covalent growth protocol is developed to construct all-graphene macrostructures (AGM) with micro-to-macro inheritable electrical properties by laser-assisted covalent linkage of polyethersulfone-derived 3D porous graphene microblocks without introducing any catalysts, templates, and additives. Creatively, along with graphene generation and inter-layer bonding, a quality optimization process is integrated into one-step laser irradiation, which is unique and efficient for synthesizing high-crystalline graphene. With the covalently nondestructive bridge and free of non-graphene foreign phase impurities, AGM shows unprecedented electrical conductivity, especially a more than 100-fold improvement in cross-layer conductivity compared with non-covalent assembly. Furthermore, the covalent growth mechanism of AGM is clarified by molecular dynamics simulations. Finally, the application efficacy of AGM with enhanced isotropic conductivity is verified by using it as a supercapacitor electrode. This methodology enables the as-obtained AGM to possess the potential for high-performance-pursuing, multi-disciplinary, or large-scale applications.     

Development of an Asymmetric Hydrophobic/Hydrophilic Ultrathin Graphene Oxide Membrane as Actuator and Conformable Patch for Heart Repair

A conductive engineered cardiac patch (ECP) can reconstruct the biomimetic regenerative microenvironment of an infarcted myocardium. Direct ink writing (DIW) and 3D printing can produce an ECP with precisely controlled microarchitectures. However, developing a printed ECP with high conductivity and flexibility for gapless attachment to conform to epicardial geometry remains a challenge. Herein, an asymmetrical DIW hydrophobic/hydrophilic membrane using heat-processed graphene oxide (GO) ink is developed. The “Masked spin coating” method is also developed that leads to a microscale GO (hydrophilic)/reduced GO (rGO, hydrophobic) physiological sensor, as well as a macroscale moisture-driven GO/rGO actuator. Depositing mussel-inspired polydopamine (PDA) coating on the one side of the DIW rGO , the ultrathin (approximately 500 nm) PDA-rGO (hydrophilic)/rGO (hydrophobic) microlattice (DrGOM) ECP is bestowed with the flexibility and moisture-responsive actuation that allows gapless attachment to the curved surface of the epicardium. Conformable DrGOM exhibits a promising therapeutic effect on rats' infarcted hearts through conductive microenvironment reconstruction and improved neovascularization.     

Multiuser OFDM Using Cyclic Time Shift for Wireless Uplink Broadcasting

A combination of orthogonal frequency division multiplexing (OFDM) with frequency-division multiple access (FDMA) called orthogonal frequency-division multiple access (OFDMA) is regarded as a promising solution for improving the performance of interactive wireless broadcasting systems. This paper presents our investigation into reducing the multiple access interference (MAI) introduced by symbol timing misalignment in an OFDMA uplink system. To combat the MAI, we provide a new OFDMA symbol frame employing a simple symbol repetition coupled with a cyclic time shift for typical OFDMA uplink scenarios. Theoretical analysis and computer simulations are used to assess the performance of the proposed OFDMA uplink system. It is found that this scheme can decrease the probability of destroying the orthogonality among the users and provide the MAI-free reception.