新型无机絮凝剂聚硅酸铝的制备及其模拟净水试验

以硫酸铝为主要原料，引入硅酸根，在高速剪切的条件下，经过聚合，熟化反应合成出有效铝含量(以Al2O3计)9．5％～12％，碱化度45％～55％，pH2．8～3．8的半透明液体PASS，该产品稳定性好，处理后水中的铝残余远小于PAC。对产品用硅藻土配的浊度水进行絮凝试验，并与PAC、硫酸铝对比，去浊效果是PAC的一倍。且不受pH因素影响。     

Continuous ethanol production from wood hydrolysate by chemostat and total cell retention culture

Chemostat and total cell retention cultures with internal filter system ofSaecharomyc.es cerevisiae H1-7 were carried out to produce ethanol from wood hydrolysate. Maximum ethanol productivity obtained in a chemostat with the aeration rate of 1 vvm was 3.79 g/(L·h). This was 20% higher than that in a chemostat without aeration. However, the substrate was not completely consumed at the dilution rate with the maximum productivity. The realistic productivity, which has higher than 99% conversion rate of substrate, was. 2.95 g/(L·h). The maximum productivity in the total cell retention culture was 6.65 g/(L·h) at the dilution rate of 0.19 h¹ and the residual glucose concentration was negligible.     

褐煤成型的研究

由于褐煤具有含水率高，灰份大，易风化，发热值低等特点，使得成型难度很大．本文重点研究水份粒度、添加剂、成型压力等对褐煤成型的影响．最佳条件：粒度＜１ｍｍ，水份１４～１６％，压力＞５０Ｔｆ，添加剂１０～２０％．     

High clay content nanocomposite hydrogels with surprising mechanical strength and interesting deswelling kinetics

A series of high hectorite content nanocomposite Poly (N-isopropylacrylamide), (PNIPAAm), hydrogels have been successfully synthesized by choosing a special kind of hectorite (Laponite XLS) modified by tetrasodium pyrophosphate. It was found that these hydrogels show surprising mechanical properties (i.e. tensile strength: 1 MPa, elongation at break: 1400%) and complicated deswelling behavior, which are due to the high clay content of the hydrogels and ionic dispersant contained in Laponite XLS, respectively.     

Hydrodynamics of gas-solid flow around immersed tubes in bubbling fluidized beds

A numerical study was conducted based on the gas-solid two-fluid model using the body-fitted coordinate system to analyze the behavior of particles and bubbles flow in bubbling fluidized beds without and with immersed tubes. The kinetic theory of granular flow was implemented in the model. The images of simulated instantaneous particle concentration and velocity gave the process of the formation, coalescence and eruption of bubbles. The effects of the tube pitch and superficial gas velocity on the fluidization in a bubbling fluidized bed were investigated. Calculated bubble frequencies without and with immersed tubes were in agreement with previous experimental and simulation findings. The wavelet multi-resolution analysis was used to analyze the simulated data of instantaneous particle concentration. From the random-like particle concentration fluctuations, the fluctuating components due to particle flow and bubble motion can be extracted based on the wavelet multi-resolution analysis over a time-frequency plane.     

填充床鼓泡电化学反应器行为特性研究──Ⅰ.丙烯阳极直接氧化的数学模拟

本文建立了填充床鼓泡电化学反应器的一维数模．该模型既考虑了反应动力学，也考虑了体系的基本传递特性．模拟结果可以描述床层的径向电势、电流和浓度分布．     

An NMR study of the dissociation of N,N′-(2-propyloximino)-4,4′-methylenebis(phenylcarbamate) and its crosslinking of polymers containing labile hydrogens. II

Nuclear magnetic resonance spectroscopy has been used to study the dissociation and reaction of N,N′-(2-propyloximino)-4,4′-methylenebis(phenylcarbamate), as a crosslinking agent for polymers containing labile hydrogens. The crosslinking of poly(acrylic acid), polyacrylamide, and poly(vinyl alcohol) was found to result upon heating each to 150°C for 10 min with this component at 2–10 wt %.     

Highly moisture-proof polysilsesquioxane coating prepared via facile sol-gel process

A highly moisture-proof polysilsesquioxane coating was obtained from a new bis-silylated precursor, which was synthesized from 3-aminopropyltriethoxysilane (APTES) and m-xylylene diisocyanate (m-XDI) in tetrahydrofuran (THF) and verified by ¹H MAS NMR. For direct comparison purposes, an SiO₂ coating was also prepared by the Stöber method using tetraethoxysilane (TEOS) as the reactant. Interestingly, the coating obtained from the polysilsesquioxane sol exhibited a much higher moisture resistance capability than its counterpart, which was attributed to its more compact feature between nanoparticles as characterized by N₂ absorption experiment and transmission electron microscopy (TEM). Furthermore, its high transparency of about 92% showed potential for application in the protection of optical crystals.     

Microstructure and Properties of Co2+: ZnAl2O4/SiO2 Nanocomposite Glasses Prepared by Sol–Gel Method

Transparent bulk Co²⁺: ZnAl₂O₄/SiO₂ nanocomposites containing nanocrystalline Co²⁺: ZnAl₂O₄ dispersed in silica glass matrix were obtained by the sol–gel method. The gels of composition 89SiO₂–6Al₂O₃–5ZnO− x CoO ( x =0.2, 0.4, 0.6, 0.8, 1.0) (mol%) were prepared at room temperature by using two different aluminum salts, aluminum nitrate and aluminum alkoxide (aluminum-iso-propoxide, Al(OPrⁱ)₃), as starting materials. The transparent gels were converted to the crystalline phase of gahnite by heating above 900°C. The microstructural evolution of gels was characterized. The effect of Co²⁺ concentration on spectroscopic properties was also discussed. Co²⁺: ZnAl₂O₄ nanocrystals dispersed in the SiO₂-based glass are formed at lower heat-treatment temperature and shorter heating time by using Al(OPrⁱ)₃ as raw material.     

覆铜板用环氧树脂的改性研究进展

本文介绍了环氧树脂在覆铜板中的使用情况和当前国内外对环氧树脂进行改性的研究现状，并介绍了今后覆铜板用环氧树脂的研究方向。