Poly(3‐chlorothiophene) films prepared by the direct electrochemical oxidation of 3‐chlorothiophene in mixed electrolytes of boron trifluoride diethyl etherate and sulfuric acid

3‐Chlorothiophene (CT) was electrochemically polymerized in mixed electrolytes of a boron trifluoride diethyl etherate solution containing 0–20% (by volume) sulfuric acid. The oxidation potentials of the monomer in these media were measured to be only 1.06–1.31 V (vs Ag/AgCl). These values were much lower than that of CT in acetonitrile and 0.1 mol/L (Bu)₄NBF₄ (1.92 V vs Ag/AgCl). Poly(3‐chlorothiophene) (PCT) films with conductivities of 0.1–2 S cm^?1 were obtained. The structure, morphology, and electrochemical behavior of the PCT films also were investigated. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 502–509, 2003     

扬巴工程中承包商合同控制

阐述扬巴项目中合同控制的基本做法,比较国内工程与涉外工程项目中合同控制的差异,提出承包商在涉外工程项目中做好合同控制工作的建议。     

A survey of traffic-based routing metrics in family of expected transmission count for self-organizing networks

Self-Organizing Networks (SONs) are attractive for applications where flexibility, resilience, and a large network service area are required. In order to meet the requirements of those applications, the principal issue is to guarantee efficient routing in SONs. Hence, the design and selection of appropriate routing metrics is important. A mass of metrics have been proposed in the past several decades. Among all the metrics, Expected Transmission Count (ETX) has drawn the most attention. Since the proposal of ETX, many ETX-based or extended metrics have been proposed. ETX and its descendants compose the ETX family. This paper is an attempt to analyze, compare and summarize traffic-based routing metrics in the ETX family. Details of each routing metric are presented and analyzed. Some of our viewpoints on the principal for designing metrics in SONs are presented.     

国产核电厂蒸汽发生器下封头接管区模拟装置承受循环载荷能力的试验

国产核电厂蒸汽发生器下封头群孔接管区具有应力分布复杂、焊接施工条件差的特点。为考核其承受循环载荷的能力，设计制造了与实物相似的模拟试验装置，根据核电厂运行寿命期内的载荷特点，确定了模拟试验装置的试验载荷与试验循环数。循环加载试验的结果表明，蒸汽发生器下封头群孔接管区承受循环载荷的能力在寿命期内是符合要求的。     

集成电路密封用高纯邻甲酚醛环氧树脂的制备

ECN树脂中的可水解氯含量是决定树脂质量的—个重要指标。本文研究了反应温度、ECH/OCN配比、反应时间和碱用量等因素的影响,取得了规律性的认识,并获得最佳配方,制备出高纯度的ECN树脂系列产品。     

2003年上半年我国染料、有机颜料生产及进出口情况浅析（一）

20 0 2年我国染料及有机颜料生产和进出口数量达到历史最好水平 ,2 0 0 3年上半年虽然经受了SARS的影响 ,但我国染料及有机颜料工业仍然取得了稳定增长的成绩。上半年染料产量总计 19 5 9万t,同比增长 2 4 7%;颜料产量为 4 30万t,同比增长 2 1 6 9%。上半年出口增长幅度减缓 ,染料出口总量为 9 92万t,同比增长 3 1%;有机颜料出口为 4 2万t,同比增长 3 1%。进口基本稳定 ,上半年染料进口量为 3 2 5万t,同比增长 9 1%;有机颜料进口为1 6 9万t,同比增长为 11 5 %。总之 ,上半年主要经济指标完成情况良好 ,进出口数量和经济效益继续保持稳定增长。但染料和纺织品的生产与出口都遇到一定的困难 ,纺织品出口又直接影响染料的内销市场 ,由于内外市场的变化 ,使染料生产和进出口的增长幅度减缓。     

Morphologies-Controlled Synthesis and Optical Properties of Bismuth Tungstate Nanocrystals by a Low-Temperature Molten Salt Method

Well-crystallized bismuth tungstate (Bi₂WO₆) powders with different morphologies were successfully synthesized via a low-temperature molten salt method. The powders were characterized by X-ray diffraction, transmission electron microscopy, and UV-Vis, respectively. It was found that the variation of morphology of the obtained Bi₂WO₆ powder mainly depends on the different reaction temperatures and the weight ratio of LiNO₃–NaNO₃ salt to precursor. In addition, the UV-Visible absorption spectra showed that the synthesized powders had strong light absorption properties not only in the ultraviolet light but also in the visible light region.     

Zinc hydroxystannate and zinc stannate as flame‐retardant agents for flexible poly(vinyl chloride)

The flame‐retardant and smoke‐suppressant properties of inorganic tin compounds such as zinc hydroxystannate (ZHS) and zinc stannate (ZS) were investigated in a comparison with alumina trihydrate, magnesium hydroxide, and Sb₂O₃ through the limiting oxygen index test and smoke density test. The flame‐retardant mechanisms were studied through the char yield test, SEM, quantitative analysis, thermogravimetry and differential thermal analysis. The thermal degradation in air of flexible PVC treated with the above compounds was studied by thermal analysis from ambient temperature to 800°C. The results showed that tin compounds such as ZHS and ZS could be used as a highly effective flame retardant for flexible PVC, and it appears that the tin compound may exert its action in both the condensed and vapor phases, but mainly in condensed phases as a Lewis acid. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 1469–1475, 2005     

十二烷基苯磺酸钠水溶液聚集性质的研究

用滴体积法测出十二烷基苯磺酸钠（ＳＤＢＳ）稀水溶液的表面张力；然后求出其临界胶束浓度（ＣＭＣ）。同时通过溶液的电导率、吸收光谱以及荧光光谱测定求出其ＣＭＣ。这样测出的ＣＭＣ值为１．２～１．６×１０－３ｍｏｌ／Ｌ，与文献值相符。也研究了部分水解的聚丙烯酰胺（ＰＨＰＡＭ）对ＳＤＢＳ聚集性质的影响；发现ＳＤＢＳ的ＣＭＣ值随ＰＨＰＡＭ的加人而减少并且ＰＨＰＡＭ水溶液的粘度随ＳＤＢＳ的存在而急剧降低（类似盐效应）。这些方法与性质对强化采油（ＥＯＲ）是重要的。