The working mechanism of organic photovoltaic cell by using copper phthalocyanine as exciton blocking layer

We demonstrate the working mechanism of organic photovoltaic (OPV) cell with copper phthalocyanine (CuPc) as exciton blocking layer (EBL). The new EBL material CuPc, commonly has been used as electron donor in the organic solar cells due to its electron-donating and hole-transporting properties. But here we proves that the α-polymorph CuPc layer can transfer electrons to Al cathode through the half-filled b_1g level, this mechanism is different from that of general EBL material with larger band gap and electron-transporting property, which is based on damage states induced by the heat of evaporating Al.     

Carbon Metabolism of a Soilborne Mn(II)-Oxidizing Escherichia coli Isolate Implicated as a Pronounced Modulator of Bacterial Mn Oxidation

Mn(II)-oxidizing microorganisms are generally considered the primary driving forces in the biological formation of Mn oxides. However, the mechanistic elucidation of the actuation and regulation of Mn oxidation in soilborne bacteria remains elusive. Here, we performed joint multiple gene-knockout analyses and comparative morphological and physiological determinations to characterize the influence of carbon metabolism on the Mn oxide deposit amount (MnODA) and the Mn oxide formation of a soilborne bacterium, Escherichia coli MB266. Different carbon source substances exhibited significantly varied effects on the MnODA of MB266. A total of 16 carbon metabolism-related genes with significant variant expression levels under Mn supplementation conditions were knocked out in the MB266 genome accordingly, but only little effect on the MnODA of each mutant strain was accounted for. However, a simultaneous four-gene-knockout mutant (namely, MB801) showed an overall remarkable MnODA reduction and an initially delayed Mn oxide formation compared with the wild-type MB266. The assays using scanning/transmission electron microscopy verified that MB801 exhibited not only a delayed Mn-oxide aggregate processing, but also relatively smaller microspherical agglomerations, and presented flocculent deposit Mn oxides compared with normal fibrous and crystalline Mn oxides formed by MB266. Moreover, the Mn oxide aggregate formation was highly related to the intracellular ROS level. Thus, this study demonstrates that carbon metabolism acts as a pronounced modulator of MnODA in MB266, which will provide new insights into the occurrence of Mn oxidation and Mn oxide formation by soilborne bacteria in habitats where Mn(II) naturally occurs.     

Chemical Coupled PEDOT:PSS/Si Electrode: Suppressed Electrolyte Consumption Enables Long‑Term Stability

Huge volume changes of Si during lithiation/delithiation lead to regeneration of solid-electrolyte interphase(SEI)and consume electrolyte.In this article,γ-glycidoxypropyl trimethoxysilane(GOPS)was incorporated in Si/PEDOT:PSS electrodes to construct a flexible and conductive artificial SEI,effectively suppressing the consumption of electrolyte.The optimized electrode can maintain 1000 mAh g^−1 for nearly 800 cycles under limited electrolyte compared with 40 cycles of the electrodes without GOPS.Also,the optimized electrode exhibits excellent rate capability.The use of GOPS greatly improves the interface compatibility between Si and PEDOT:PSS.XPS Ar+etching depth analysis proved that the addition of GOPS is conducive to forming a more stable SEI.A full battery assembled with NCM 523 cathode delivers a high energy density of 520 Wh kg^−1,offering good stability.     

基于免疫否定选择算法的机场航班延误状态检测与实现

把免疫算法中的否定选择算法运用到航班延误状态的诊断检测与预测中,将生物免疫系统机制与机场航班运行机制联系起来,建立了相应的自体集合、检测细胞、抗原信息及它们之间的匹配模型,给出了检测方法。首先根据机场航班运行数据生成航班检测的成熟检测器和记忆检测器,然后用否定选择算法和航班数据对检测器进行训练和改进,最后利用检测器中的信息对机场航班状态分段进行预测,获得每个时段的航班延误状况,为机场有关部门对航班延误应急处理提供决策支持。仿真实验表明,该方法能较准确地预测航班的延误状态,且实时性好。     

柴达木盆地油泉子储油构造分析

通过对野外露头、地震反射剖面和钻井资料的综合分析,查明柴达木盆地油泉子储油构造为共轭膝褶带夹持的不对称半箱状背斜,具有北北东倾的平直转折端,北翼为一宽超过800m的大型膝褶带,高角度倾向南南西,带内岩层产状直立。带内岩层的旋转指示南侧沿膝褶带向北逆向剪切。南翼发育四条规模较小的膝褶带,向南逆冲剪切,导致该翼呈阶梯状产出,总体南南西倾,倾角约20°。沿南北两翼膝褶带边界仅见小型高角逆断层,膝褶带内裂隙发育,主要为顺层张裂隙,其次为与层理近垂直的张裂隙(主要出现在坚硬的钙质粉砂岩中),偶尔见有小型低角逆冲断层。这些断裂普遍被纤维状石膏充填,并见少量油迹,表明这些断裂为高流体压力下的产物。鉴于膝褶带及相关背斜高点为裂隙发育带,具有油气运移和聚集的双重功能,在缺乏足够理想的岩性储集层的情况下,为寻找裂隙型油气藏提供了新途径。     

Multistimuli‐Responsive Display Materials to Encrypt Differentiated Information in Bright and Dark Fields

Visually readable codes play a crucial role in anticounterfeiting measures. However, current coding approaches do not enable time‐dependent codes to be visually read, adjusted, and differentiated in bright and dark fields. Here, using a combined strategy of piezoelectric lattice selection, oxygen vacancy engineering, and activator doping, a lanthanide ion‐doped titanate is developed that integrates mechano‐, thermo‐, and photo‐responsive color change (>18 h for bright field), persistent luminescence (>6 h for dark field), and stimulus‐triggered multimodal luminescence. The feasibility of optical encoding, visual displaying, and stimulus‐responsive encrypting of time‐dependent, dual‐field information by using the developed material is demonstrated. In particular, the differentiated display of dual‐field modes is achieved by combining mechanostimulated abolition of only the persistent luminescence and thermo‐ and photostimulated reversal of both the color change and persistent luminescence. The results provide new insights for designing advanced materials and encryption technologies for photonic displays, information security, and intelligent anticounterfeiting.     

Up?Scalable Fabrication of -SnO2 with Multifunctional Interface for High Performance Perovskite Solar Modules

Tin dioxide -(SnO2) has been demonstrated as one of the promising electron transport layers for highefficiency perovskite solar cells (PSCs). However, scalable ...     

工艺因素对319铝合金热分析特征值的影响

运用热分析技术研究了冷却曲线特征值与319铝合金中化学成分之间的关系,并进行回归分析。结果表明,在不考虑工艺因素的情况下,试样的硅含量与α-Al枝晶生长回升温度T_G~(αDEN)之间的相关性最大,相关系数r为-0.65,以硅含量可预测α-Al枝晶生长回升温度。在浇注过程中,冷却速度与α-Al枝晶生长回升温度T_G~(αDEN)密切相关,相关系数为r=-0.72。在相同的冷却条件下,铝合金的浇注温度和浇注量对冷却速度有明显的影响,因此,可以通过调整浇注温度和浇注量,控制铝合金的冷却速度,进而也可预测铝合金中α-Al枝晶生长回升温度T_G~(αDEN)。     

新型投影机高效光源——LED

该文详细介绍了LED作为微型投影机高效投影光源的优势和存在的不足之处,分析了LED作为投影光源需要改进的地方,指出了LED最终会成为未来投影机光源的主流趋势。