聚萘二甲酸乙二醇酯(PEN)的研究及发展

综述了聚萘二甲酸乙二醇酯(PEN)的发展历史,合成工艺,应用领域及其与PET的性能比较。     

《动态网站开发》课程教学改革探索

《动态网站开发》课程是中职学校计算机专业的核心课程,传统的授课方式以讲授理论为主,实际操作较少,这种方式很难适应现在中职学校的教学,必须打破传统的教学理念,对《动态网站开发》课程进行改革。     

Morphologies-Controlled Synthesis and Optical Properties of Bismuth Tungstate Nanocrystals by a Low-Temperature Molten Salt Method

Well-crystallized bismuth tungstate (Bi₂WO₆) powders with different morphologies were successfully synthesized via a low-temperature molten salt method. The powders were characterized by X-ray diffraction, transmission electron microscopy, and UV-Vis, respectively. It was found that the variation of morphology of the obtained Bi₂WO₆ powder mainly depends on the different reaction temperatures and the weight ratio of LiNO₃–NaNO₃ salt to precursor. In addition, the UV-Visible absorption spectra showed that the synthesized powders had strong light absorption properties not only in the ultraviolet light but also in the visible light region.     

Integrated size and topology optimization of skeletal structures with exact frequency constraints

The present paper studies the integrated size and topology optimization of skeletal structures under natural frequency constraints. It is found that, unlike the conventional compliance-oriented topology optimization problems, the considered problem may be strongly singular in the sense that the corresponding feasible domain may be disconnected and the global optimal solutions are often located at the tips of some separated low dimensional sub-domains when the cross-sectional areas of the structural components are used as design variables. As in the case of stress-constrained topology optimization, this unpleasant behavior may prevent the gradient-based numerical optimization algorithms from finding the true optimal topologies. To overcome the difficulties posed by the strongly singular optima, some particular forms of area/moment of inertia-density interpolation schemes, which can restore the connectedness of the feasible domain, are proposed. Based on the proposed optimization model, the probability of finding the strongly singular optimum with gradient-based algorithms can be increased. Numerical examples demonstrate the effectiveness of the proposed approach.     

橡胶对HIPS树脂落锤指标的影响

通过对高抗冲聚苯乙烯树脂出现产品落锤指标偏低问题的分析，从橡胶配量及其粒径大小上进行了改进，同时改进了工艺操作，采取了提高反应釜搅拌速度、降低乙苯浓度等措施。结果产品合格率达到９９％以上，优级品率达到９８％以上。     

Nanocrystalline CeO2 in SBA-15: Performance of Pt/CeO2/SBA-15 Catalyst for Water-gas-shift Reaction

CeO₂ particles confined within the pores of an SBA-15 mesoporous silica host were prepared by incipient wetness impregnation (IMP) and deposition precipitation (DP) methods. The materials were characterized by XRD, N₂-adsorption and temperature programmed reduction (TPR) to evaluate the structure, texture, and redox properties. The preparation procedure had significant impact on the assembling mode of CeO₂ inside the SBA-15 mesopores. A high dispersion of CeO₂ particles was achieved via DP, whereas the dispersion of CeO₂ prepared by IMP was found to be inhomogeneous and CeO₂ partially blocked the pores. The CO conversion in the water-gas-shift reaction was enhanced over 1 wt% Pt supported on CeO₂-modified SBA-15 obtained by DP.     

PVC╱NBR╱BR三元共混弹性体的制备

采用结合丙烯腈含量为26％的NBR、分子量适中的悬浮法Ⅲ型PVC和BR共混,制得了综合性能较PVC/NBR并用胶优异的弹性体。优选的工艺条件为:PVC/NBR/BR=30/60/10(质量比);补强剂选用炭黑40份,超细碳酸钙50份,轻质碳酸钙20份;硫化体系选用过氧化物加少量硫磺;混炼温度为140—170℃,混炼时间为10—15min。通过电子显微镜和动态力学分析,弹性体存在两个T,PVC为分散相,橡胶为连续相。     

高职院校软件教学体系研究

本文在概述软件教学体系及其理论的基础上,结合软件教学的特点,阐述了软件教学体系的结构、应用环境以及在教学中将遇到的问题和解决对策,并描述了＂软件教学资源网系统＂建立的目的、设计方案、功能及开发环境。     

基于安全隔离的边界防护体系的设计与实现

本文针对电子政务信息系统的特点,设计了基于安全隔离的边界防护体系。将安全隔离技术应用到电子政务中,实现了数据的安全高效实时传输,形成了多方位的安全边界防护体系架构。     

Photocross-linking of low-density polyethylene. III. Supermolecular structure studied by SALS

The supermolecular structure of photocross-linked polyethylene (XLPE) has been studied by small-angle light scattering (SALS). The data show that the spherulitic structure of XLPE gradually deteriorates with increasing degree of cross-linking and increasing irradiation temperature from well-developed spherulites to rodlike aggregates and disordered lamellar structures. A photocross-linked sample of PE has lower crystallinity, smaller crystallites, and smaller spherulites than does the original sample. At high degrees of cross-linking, the SALS patterns show little or no spherulitic structure. Results with photocross-linked polyethylene demonstrate that the overall effect of cross-linking on the morphological structure is similar to that of an increase in molecular weight of the polymer. © 1993 John Wiley & Sons, Inc.