Weathering modification of acrylic emulsion by introducing UV absorbing groups

A new kind of UV-absorbing silicon-fluorinated acrylic emulsion was prepared by emulsion polymerization with 4-allyloxy-2-hydroxybenzophenone, 3-methacryloxypropyltrimethoxysilane (MPS) and hexafluorobutyl methacrylate (HFMA) as functional monomers. The emulsion and its coating were characterized by transmission electron microscope, Fourier transform infrared spectrum (FTIR), X-ray photoelectron spectroscopy, ultraviolet absorption spectrum,thermo-gravimetric analysis, water contact angle (CA), and artificial accelerated aging test. The results indicated that the emulsion with core-shell structure was synthesized and showed prominent absorption peaks at 320 and 350 nm. The water CA of the coating was increased from 70.2° to 86.7° because of the incorporated HFMAs and MPSs. Both of the initial and final decomposition temperatures of the coating were increased by more than 20°C compared with those of the unmodified coating. After 10 days of accelerated aging, the color difference (ΔE) and rate of loss of gloss (ΔG) were only 2.78% and 5.22%, while those of the unmodified coating were as high as 22.94% and 78.57%, respectively. Because of the UV absorbers were incorporated by chemical reaction, the new coating had a more durable and effective anti-ultraviolet performance compared with the coatings the UV absorbers were introduced by physical blending.     

Oxidation Performance of Fe-Al/WC Composite Coatings Produced by High Velocity Arc Sprayed at 650 ℃

Fe-Al intermetallics with remarkable high-temperatureintensity and excellent erosion,high-temperatureoxidation and sulfuration resistance are potential lowcost high-temperature structural material.ProducingFe-Al/WC composite coating by high velocity arcspraying(HVAS)on structural materials would notonly obviate the problems faced in fabrication of thesealloys into useful shapes,but also allow the effectiveuse of their outstanding high-temperature performance,which might thus promisingly mak…     

用含Pb、As、Sn地方生铁砂型铸造生产D型石墨铸铁的研究

基于Ph、As、Sn等元素有增大铁液过冷倾向的作用，利用含Ph、As、Sn的地方生铁，采用合金化和砂型铸造可以获得D型石墨铸铁，对其工艺方案进行了研究。用正交试验法设计试验方案，得到最佳工艺方案为：在亚共晶成分（WB％：3．2C，2．1si）的铁液中加入适量的铝（0．6％）和钛（0．8％），可以得到含有100％D型石墨的铸铁，其抗拉强度最高可达276MPa。     

坯料外形对镁合金矩形盒拉深成形的影响

用商业有限元软件模拟了在同一套模具和成形条件下不同毛坯外形的镁合金矩形盒拉深成形过程．依据数值模拟结果，分析了不同坯料外形对镁合金矩形盒拉深成形的影响。结果表明：使用矩形圆角坯料比其他坯料的成形性能好。     

圆锯片的有限元模态分析

针对金属冷热锯机锯片在锯切轧件过程中出现的振动问题 ,利用 MSC/ NASTRAN有限元软件 ,计算分析了各种参数对锯片模态的影响。从而为锯片的设计及其制造工艺的确定提供了可靠的参考依据 ,为最终解决生产中的实际问题发挥了重要作用     

钨钴硬质合金电化学蚀刻加工研究

对YG6硬质合金电化学蚀刻工艺进行了研究,提出了采用光致抗蚀剂作保护膜,在生成一定钝化膜的情况下进行电化学蚀刻的方法.在一定的蚀刻深度范围内,该工艺的可控性好、腐蚀区表面质量较好.     

Ultrahigh Current Density Ion Implantation

A study of several engineering alloys implanted at ultrahigh current densities has revealed that the process induces no change in the bulk microsctructure of the materials. Even though temperatures induced during processing exceed the transformation (tempering and annealing) temperatures, there is insufficient time for nucleation and growth reactions to occur during the temperature excursion associated with typical implantation dose and energy conditions. Substantially lower costs should accompany the shorter duration ultrahigh current density implantation process. Auger electron spectrographs reveal a substantially extended nitrogen range over those observed at low current densities (four-fold increase). This enhanced range appears to be due to radiation enhanced diffusion effects. Deeper penetration could lead to more durable surface layers.     

基于I2C总线技术的等离子喷焊系统的研究

阐述了基于I^2C总线技术的等离子喷焊过程控制系统的设计原理，介绍了软硬件及接口设计技术。实践表明，采用I^2C总线技术，不仅使系统的芯片大大减少，系统的灵活性增强，而且提高了系统的抗干扰能力。     

Experimental Study of Microstructure Evolution during Tempering of Quenched Steel and Its Application

LARGE-SIZED FORGINGS are usually intensivelyquenched to obtain the desired microstructuredistribution,high strength and hardness.Becauseresidual stresses are high in quenched large-sizedforgings,tempering processes follow quenchingprocesses to reduce the residual stress and obtain goodmechanical properties.Several differentmicrostructures are generated in quenched steelforgings,such as martensite,bainite and retainedaustenite.Modeling of microstructure evolution inquenched steel during …     

椭圆弧数控代码的自动生成方法

提出了一种基于计算机辅助制造的数控加工代码自动生成的方法，着重阐述了该方法针对椭圆弧的数控代码自动生成过程。该方法通过分析加工图形的dxf文件，提取图形的坐标信息，再经过数据拟和，自动生成该图形的数控代码。该方法由VC＋＋6．0实现相应的功能，经实际运行表明，能满足加工精度要求。该方法摆脱了传统数控机床从加工图形到形成数控加工代码时间长且精度不高的缺点，极大她提高了工作效率。