Response surface methodology study on electrochemical adsorption regeneration of water-based drilling fluid waste

ABSTRACT

This study explores an electrochemical adsorption method on the regeneration of aqueous drilling fluid waste. Response surface analysis was applied to investigating the electrochemical factors on the adsorption performance. The response surface polynomial model optimized the preferred electrochemical adsorption conditions with adsorption time of 20 min, spacing electrodes of 5 cm, adsorption concentration of 5% and NaCl concentration of 2 g/L. The model calculated electrochemical adsorption amount of drilling fluid showed only 1.3% deviation from the experimental results. Thus, the model could provide effective support for the device design and application of drilling fluid electrochemical adsorption process.     

Low-temperature methanol synthesis in a circulating slurry bubble reactor

A circulating slurry bubble reactor was developed to synthesise methanol via methyl formate from the gas mixture of carbon monoxide and hydrogen at low temperature. The strategy for designing and scaling up the bubble reactor involved a preliminary understanding of fluid dynamics in a cold model, continuous operations under industrial conditions and a parallel experiment in an autoclave. Per-pass syngas conversion was investigated during 100-h operations. The axial profile of solid catalyst concentration was measured just before the shutdown and the composition of liquid product was analysed after the shutdown. These results show that the circulating slurry bubble column will become a potential reactor for the commercial process of low-temperature methanol synthesis after the catalyst system has been improved.     

氨纶氯水降解及耐氯机理的探讨

应用红外光谱分析方法，对氨纶（ＰＵ纤维）氯水降解及耐氯机理进行了初步的研究。结果表明，ＰＵ浸氯水后，因受活性氯原子的攻击，ＰＵ大分子软链段的碳－碳键发生断裂，形成碳－氯化合物，添加剂加入后，因与ＰＵ大分子的软链段形成螯合物，从而避免了活性氯原子的攻击，有效地保护了软链段，使氨纶耐氯性能明显改善。     

Stochastic stability of semi‐Markovian jump systems with mode‐dependent delays

Semi‐Markovian jump systems, due to the relaxed conditions on the stochastic process, and its transition rates are time varying, can be used to describe a larger class of dynamical systems than conventional full Markovian jump systems. In this paper, the problem of stochastic stability for a class of semi‐Markovian systems with mode‐dependent time‐variant delays is investigated. By Lyapunov function approach, together with a piecewise analysis method, a sufficient condition is proposed to guarantee the stochastic stability of the underlying systems. As more time‐delay information is used, our results are much less conservative than some existing ones in literature. Finally, two examples are given to show the effectiveness and advantages of the proposed techniques. Copyright © 2013 John Wiley & Sons, Ltd.     

橡胶模型制品胶坯精密预成型机

介绍了橡胶工业橡制品生产中胶坯制备的三种方法，其中详细介绍了精密预成型机制备胶坯。以上海德仁橡塑机械有限公司物精密预成型机为例，从结构，性能及工艺参数等方面进行了分析，说明精密预成型机是批量生产橡胶模型制品的一种得力辅助设备。     

基于形变模型的多视图三维人脸重建

本文提出了基于形变模型的多视图三维人脸重建方法,将人脸形变模型与同一人脸在不同视点下的多幅图像进行匹配,从而重建出具有较强真实感的三维人脸模型。本文将对基于形变模型的多视图三维人脸重建方法进行详细的阐述,并把实验结果与单视图重建出的三维人脸模型进行了对比,从而体现出多视图重建的优势所在。     

信息技术在数学教学中的应用研究

以多媒体计算机和网络为核心的信息技术在小学数学教学中的运用,使数学教学活动更加丰富多彩,激发学生的学习兴趣,增强学生的主体意识,培养学生的技能,拓展学生探究的时间和空间,引发学生主动、积极、创新的思维,开发学生的智力,促进学生主动学习,主动发展,从而有效地提高课堂教学效率.     

浸没循环撞击流反应器制备牙膏用磷酸氢钙

采用浸没循环撞击流反应器（SCISR），以焦磷酸钠和磷酸三镁为稳定剂，以磷钙液和石灰乳为原料，通过中和反应法制备出了平均粒度10μm的牙膏用微细磷酸氢钙；探讨了反应温度、熟化时间、反应器装填系数、反应终点pH、磷钙液质量浓度等对产品质量的影响。确定了最优操作条件：磷钙液质量浓度1．17～1．19kg／m^3，反应温度42℃，熟化时间2h，反应终点pH6．3，反应器装填系数0．75。得到产品符合HG3257—2001标准。     

液体连续相撞击流特性及其在超细粉体制备中的应用

20世纪90年代以来撞击流领域研究重点转向以液体为连续相。液体连续相撞击流(US)具有有效促进微观混合和存在压力波动的特性,从而有利于超细粉体的制备。实验结果表明,浸没循环撞击流反应器(SCISR)是反应一沉淀法制取超细粉体的一种优越的反应技术装备。     

Microcellular foaming of PE/PP blends

Three different polyethylene/polypropylene (PE/PP) blends were microcellular foamed and their crystallinities and melt strengths were investigated. The relationship between crystallinity, melt strength, and cellular structure was studied. Experimental results showed that the three blends had similar variation patterns in respect of crystallinity, melt strength, and cellular structure, and these variation patterns were correlative for each blend. For all blends, the melt strength and PP melting point initially heightened and then lowered, the PP crystallinity first decreased, and then increased as the PE content increased. At PE content of 30%, the melt strength and PP melting point were highest and the PP crystallinity was least. The blend with lower PP crystallinity and higher melt strength had better cellular structure and broader microcellular foaming temperature range. So, three blends had best cellular structure at PE content of 30%. Furthermore, when compared with PE/homopolymer (hPP) blend, the PE/copolymer PP (cPP) blend had higher melt strength, better cellular structure, and wider microcellular foaming temperature range, so it was more suited to be microcellular foamed. Whereas LDPE/cPP blend had the broadest microcellular foaming temperature range because of its highest melt strength within three blends. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 4149–4159, 2007