Host/guest complex of Me-β-CD/2,2-dimethoxy-2-phenyl acetophenone for initiation of aqueous photopolymerization: Kinetics and mechanism

Methylated-β-cyclodextrin (Me-β-CD) was used to complex the photoinitiator, 2,2-dimethoxy-2-phenyl acetophenone (DMPA), yielding a water-soluble host/guest complex. The comparative studies demonstrated that the Me-β-CD complexed DMPA exhibited a high photoreactivity identical to the uncomplexed DMPA, while the CD complex obviously influenced the products of primary photolysis of DMPA and the photopolymerization kinetics due to the steric effect of CD on the subsequent initiation reactions. The photopolymerization rate of acrylamide can be described by the equation: R_p=K[2a]^0.62[M]^1.37[I]^0.5[Me-β-CD]⁰. The mechanism of polymerization was also discussed.     

成型鼓的软极限保护

通过修改工艺配方,自动完成对成型鼓鼓肩位置极限的设定,并且该软极限的大小根据工艺参数的不同可以自动调整,最终达到了对成型鼓的保护,实际使用效果好.     

Characteristics of Milk Powders Produced by Spray Freeze Drying

Skim and whole milk powders were manufactured at lab scale by spray freeze drying (SFD), using liquid nitrogen as the cryogen. The polydispersity of droplet/particle sizes was limited using an encapsulator nozzle to atomize the feed. Particle morphology was examined using a scanning electron microscope. Samples were compared with equivalent spray-dried powders in tests of wettability and dissolution in water. The spray freeze-dried powders were found to be highly porous, with a uniform structure of pores throughout the entire particles. When tested in water, SFD skim milk powders wetted roughly three times as fast as industrially spray-dried agglomerated skim milk powders and were observed to dissolve rapidly by breaking down into smaller particles.     

镁钴铝类水滑石催化合成安息香甲醚

采用共沉淀法制备了镁钴铝类水滑石化合物(MgCoAl-HTLcs),并用 X 射线衍射、扫描电子显微镜、NH_3程序升温脱附等方法对 MgCoAl-HTLcs 进行了表征,并以 MgCoAl-HTLcs 为催化剂催化苯甲醛与甲醇反应合成安息香甲醚,研究了n(Mg):n(Co):n(Al)、催化剂用量、原料配比、反应温度、反应时间对合成反应的影响。表征结果显示,MgCoAl-HTLcs 的晶相完整,表面主要为弱酸、弱碱性。催化合成安息香甲醚的适宜条件为:MgCoAl-HTLcs 催化剂用量0.10 g(约为原料总质量的0.23%),n(Mg):n(Co):n(Al)=0.4:1.6:1.0,V(苯甲醛):V(甲醇)=3:50,反应温度50℃,反应时间150 min。在此条件下,苯甲醛的平衡转化率达77.49%,安息香甲醚选择性接近100%。为洁净合成安息香甲醚开辟了一条新的途径。     

全方位治理城市交通,促进城市可持续发展

城市交通对城市的社会经济活动和生态资源环境具有双向作用,是城市功能中最活跃的因素.目前城市交通问题突出表现在交通阻塞和汽车尾气污染两个方面,已成为困扰着大中城市发展的主要问题.交通堵塞不仅给人们的生活和工作带来不便,而且增加了城市经济运行的时间成本,影响到城市功能的发挥和城市的健康发展,同时又进一步加剧了能源的消耗.可见城市交通问题是关系到城市可持续发展的关键问题之一.     

非电量微机采集系统

实现水电厂电量快速微机巡回检测，温度采集较其它信号更为困难，本文着重讨论温度信号转换及与微机系统的连接。且介绍某水电厂微机控系统中非电量检测装置的硬件结构和软件编制。     

新型复合弹簧的研究

提出一种金属圆锥弹簧与橡胶圆锥弹簧复合而成的弹簧．分析表明：它可以应用于弹性耦合激励振动筛和座式直线振动筛。