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91.
A series of novel block polymers of polyurethane (PU) and chitosan have been prepared in two steps. The first step is the preparation of PU prepolymer, obtained from polytetramethylene oxide glycol (PTMO, Mn = 1000), isophrone diisocyanate (IPDI), and 2,2′-dimethylol propionic acid (DMPA), followed by ionizing PU prepolymer with triethylamine (TEA). The second step involves PU chain-extended by water-soluble chitosan of low molecular weight (Mn = 5000) by self-emulsion polymerization method. The sizes of the latex particles, morphology, and copolymer architecture have been characterized by dynamic light scattering (DLS), general tensile test, infrared spectroscopy (IR), surface contact angle measurement, and transmission electron microscopy (TEM). Furthermore, it shows that the addition of chitosan remarkably increases anticoagulative property of PU elastomers confirmed by the recalcification time. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
92.
A simple method has been devised for immobilization of acetylcholinesterase (AChE) covalent bonding to a multiwall carbon
nanotube (MWNT)-cross-linked cellulose acetate composite on a screen-printed carbon electrode (SPCE) and a sensitive and disposable
amperometric sensor for rapid determination of carbaryl pesticide is proposed. The immobilized enzyme was preserved on this
film because of the excellent biocompatibility and non-toxicity of cellulose acetate. Based on the inherent conductive properties
of the MWNT, the immobilized AChE had greater affinity for ATCl and excellent catalytic effect in the hydrolysis of ATCl.
MWNT improved the interface enzymatic hydrolysis reaction and increased the amperometric response of the sensor. Under optimum
conditions, the inhibition of carbaryl on AChE increased linearly with the increasing concentration of carbaryl in two ranges,
from 0.01 to 0.5 μg mL−1 and from 2 to 20 μg mL−1, with the correlation coefficients of 0.9985 and 0.9977, respectively. The detection limit was 0.004 μg mL−1 taken as the concentration equivalent to 10% decrease in signal. The sensor showed acceptable stability, accuracy and could
be fabricated in batches, thus it is economic and portable. This type of disposable enzyme-based amperometric sensor has extensive
application potential in environmental monitoring of pesticides. 相似文献
93.
奇异值分解压制随机噪声的方法及应用 总被引:9,自引:0,他引:9
针对随机噪声压制问题,通过对多项式确定的同相轴形状重新选取数据矩阵,再对新选取的数据矩阵进行SVD滤波,从而压制随机噪声。通过对矩阵奇异值分解的研究,揭示了奇异值分解的原理和SVD滤波原理,将一个多道地震记录看作一个图,它可分解为由一系列正交的子图,通过对子图适当选择并结合其它手段,从而达到提高信噪比的目的,为奇异值分解在地球物理中的进一步应用提供了理论依据。实际数据应用表明,该方法去噪手段灵活、保真性好、分辨率高,对一些突然的脉冲干扰、侧反射、以及其他的反向干扰有明显效果。 相似文献
94.
一个通用代理计费系统开发框架的设计与实现 总被引:4,自引:4,他引:0
用户在不同的网络环境中选择不同的代理软件实现上网和用户管理,这些代理软件既有共性又各具特色,为减少开发不同代理计费软件的工作量,提高开发效率,加快开发周期,提出利用软件重用的思想,将代理软件的差异集中到少数几个类的实现上,设计并实现一个通用代理计费系统开发框架,基于此框架利用相对简单的步骤开发了基于SQUID的代理计费系统,验证了框架的实用性和可行性,达到了设计目标。 相似文献
95.
96.
Wei Fen Zhang Xi Guang Chen Pi Wu Li Cheng Sheng Liu Qiang Zhi He 《Drying Technology》2008,26(1):108-115
Three kinds of carboxymethyl chitosan/β-cyclodextrin microspheres loaded with theophylline were prepared by spray drying intended for pulmonary delivery. Mucociliotoxicity, permeation rate, and drug release characteristics of the product were investigated. The microspheres obtained by spray drying were found to be spherical with smooth or wrinkled surfaces. The mean particle size was between 3.39 and 6.06 µm. The microspheres demonstrated high product yield (43.7-50.2%), high drug loading (13.7-38.1%), and high encapsulation efficiency (86.9-92.8%). FT-IR indicated that there were interactions of theophylline with carboxymethyl chitosan matrix. Further studies on mucociliotoxicity and permeation confirmed that microspheres had better adaptability and high permeation rate. In vitro drug release from the microspheres was not related to the drug/polymer ratios. 相似文献
97.
98.
99.
Summary Building blocks containing multi-aryl ethers linkage in larger size for rapid building larger dendrimers were prepared with 3,5-di(4-hydroxyphenoxy)benzyl alcohol (1) as branch monomer and 1,3,5-tri(4-hydroxyphenoxy)benzene (2) as core molecule. Two generation of dendritic polyethers (12 and 15) were obtained by Fréchet convergent approach with 3,5-diphenoxybenzyl bromide (3) as starting molecule. They were characterized firstly by 1H-NMR, 13C-NMR, and MS. 相似文献
100.