（E）-2-壬烯酸合成方法的改进

(E)-2-壬烯酸是有机合成的一种重要中间体,我们利用Knoevenagel反应机理,改进了(E)-2-壬烯酸的合成工艺,在不使用脱水剂条件下,使用少量吡啶作催化剂,获得了83%的反应收率。     

各向异性损伤理论与复合材料层板损伤的实验研究(一)-各向异性损伤理论

本文讨论了各向异性损伤力学的基本概念并介绍了以应变等效性假设为基础的Lemaitre模型和以能量等效性假设为基础的Cordebois模型.在此基础上作者导出了两种损伤模型的损伤能释放率的表达式.文中作者定义了一维损伤时弹性材料板单元的一些损伤定义,并导出了两种模型在一维损伤时损伤能释放率Y₂的简单表达式,从而为复合材料层板损伤测量的实验研究提供了理论基础,     

Monodispersed thermoresponsive hydrogel microspheres with a volume phase transition driven by hydrogen bonding

We report the synthesis and characterization of monodispersed thermoresponsive hydrogel microspheres with a volume phase transition driven by hydrogen bonding. The prepared microspheres, composed of poly(acrylamide-co-styrene) (poly(AAM-co-St)) cores and poly(acrylamide)/poly(acrylic acid) (PAAM/PAAC) based interpenetrating polymer network (IPN) shells, were featured with high monodispersity and positively thermoresponsive volume phase transition characteristics with tunable swelling kinetics, i.e. the particle swelling was induced by an increase rather than a decrease in temperature. The monodisperse poly(AAM-co-St) seeds were prepared by emulsifier-free emulsion polymerization, the PAAM or poly(acrylamide-co-butyl methacrylate) (poly(AAM-co-BMA)) shells were fabricated on the seeds by free radical polymerization, and the core-shell microspheres with PAAM/PAAC based IPN shells were finished by a method of sequential IPN synthesis. The microsphere size increased with increasing both AAM and BMA dosages. The increase of hydrophilic monomer AAM dosage resulted in a better monodispersity, but the increase of hydrophobic monomer BMA dosage led to a worse monodispersity. With increasing the crosslinker methylenebisacrylamide (MBA) dosage, the mean diameter of the microspheres decreased and the monodispersity became better. An equimolar composition of AAC and AAM in the IPN shells of the microspheres resulted in a more complete shrinkage for the microspheres at temperatures lower than the upper critical solution temperature. Both BMA and MBA additions depressed the swelling ratio of the hydrodynamic diameter of the microspheres.     

催化重整装置的扩能改造

介绍湛江东兴炼油厂的重整装置由200kt／a扩能至300kt／a中有关催化重整反应动力学模拟计算软件的应用、反应工艺技术的改造、装置标定的情况。结合装置实际情况，采用两段装填、两段混氢技术提升了装置的技术水平。标定结果表明，改造后的装置达到了预期目的。     

互联网市场:理性的高速发展——直击“2007中国互联网市场年会”

<正>2006岁末,美国《时代》周刊年度风云人物的揭晓让人意外之余又都颇感认同——全球逾10亿“互联网使用者”共同获此殊荣。的确,历经十几年的发展,“互联网”已密切融入人们的生活。与此同时,互联网市场也发展成为今天涵盖基础接人服务、电子商务、网络游戏、即时通讯、网络搜索等诸多领域的庞大产业。那么目前我国互联网产业整体发展状况以及未来的发展趋势究竟如何呢?透过1月19日于北京成功举办的“2007中国互联网市场年会”,我们可以对此有一个比较深入的了解。     

国际承包工程中业主的反索赔

简述了国际承包工程中业主反索赔的类型 ,分别讨论了各类反索赔的处理原则和方法 ,并提出了业主利用反索赔这个有力武器在保护自己的合法权益时的重要性     

Density Measurement of Liquid Ni-Ta Alloys by a Modified Sessile Drop Method

The density of liquid Ni- Ta alloys was measured by using a modified sessile drop method. It is found that the density of the liquid Ni- Ta alloys decreases with the increasing temperature, but increases with the increase of tantalum concentration in the alloys. The molar volume of liquid Ni- Ta binary alloys increases with the increase of temperature ancl tantalum concentration.     

一方水土养一方人

我国幅员辽阔，产物众多，各地的饮食习惯也不同。非常有趣的是，特别的饮食习惯不仅影响了各地人的生活，甚至还塑造了他们的性格。正所谓“一方水土养一方人”。     

车辆位置实时监测网的研制

ＲＴ－ＡＧＶＳ是物流管理中十分重要的课题，车辆位置监测网是其重要的组成部分。本文详细介绍了一个基于单片机系统的车辆位置实时监测网，本监测网设计先进，性能价格比高，它的设计方法和技术对其他许多领域有借鉴作用。     

Simulation of frequency nonselective mobile channel with LOScomponent: a deterministic approach

A deterministic digital simulation model with finite sum of properly weighted sinusoids is used to simulate a frequency nonselective mobile channel with LOS component. Measurement data are used to optimise the parameters. Which are then used in the deterministic simulation model. The probability distribution and level cross rate (LCR) obtained from the measured data agree well with the analytical and simulation results