A new efficient method for one‐pot conversions of aryl carboxylic acids into nitriles without solvent

A new efficient method for synthesising nitriles, important organic reagents, is reported in this paper. In an environmentally benign solvent‐free system, aryl carboxylic acids were converted into the corresponding nitriles via one‐pot reactions, by amidation with ethyl carbamate followed by dehydration with thionyl chloride, in excellent yields. The results showed that the method has the advantages of lower cost, higher yield, less pollution and greater ease of work‐up. Copyright © 2008 Society of Chemical Industry     

Facile modifications of polyimide via chloromethylation: II. Synthesis and characterization of thermocurable transparent polyimide having methylene acrylate side groups

From chloromethylated polyimide, a useful starting material for modification of aromatic polyimides, a thermocurable transparent polyimide having acrylate side groups was prepared. In the presence of 1,8‐diazabicyclo[5,4,0]undec‐7‐ene, chloromethylated polyimide was esterified with acrylic acid to synthesize poly(imide methylene acrylate). The polymer was soluble in organic solvent, which makes it possible to prepare a planar film by spin coating. The polymer film became insoluble after thermal treatment at 230 °C for 30 min. Optical transparency of the film at 400 nm (for 1 µm thickness) was higher than 98 % and not affected by further heating at 230 °C for 250 min. Adhesion properties measured by the ASTM D3359‐B method ranged from 4B to 5B. Preliminary results of planarization testing showed a high degree of planarization (DOP) value (>0.53). These properties demonstrate that poly(imide methylene acrylate) could be utilized as a thermocurable transparent material in fabricating display devices such as TFT‐LCD. Copyright © 2004 Society of Chemical Industry     

S盒设计中的一种新准则

本文提出了强扩散准则,强雪崩效应以及扩散效应的逼近优势等相关概念,给出了差分均匀性与强k阶扩散准则之间的相互关系,利用给出的设计准则改进了Rijndael密码的S盒。     

略论中国传统合院住宅形式的固化与沿用

合院式住宅是中国人沿用了二千多年的典型形制，除了其能满足采光、通风的要求和建造相对简化外，中国传统社会早期的中霤祭祀和以五行为基本元素的统括万物的宇宙模式对于中国式合院住宅的固化与沿用，也起了不可忽视的作用。     

尼龙66高强力轻型帘布的开发与应用

神马尼龙66高强力轻型帘布在保持帘布高强力、尺寸稳定性、耐热性、耐疲劳、耐冲击的良好特性的前提下，采用SNT高强度工业丝生产技术，充分挖掘工业丝的强力优势，把富余的强力通过进一步降低纤维密度转化为帘布面积优势的扩大，从而提高轮胎生产的帘布出胎率，使轮胎生产厂享受尼龙66帘布品质的同时，实现降低成本的目的。     

择形催化合成2,6-DMN的研究进展

介绍了2,6-二甲基萘(2,6-DMN)的制备方法,详细论述了萘、甲基萘在分子筛催化剂上择形催化合成2,6-DMN的研究进展,提出了择形催化合成2,6-DMN的研究方向。     

憎水性栀子蓝色素制备的研究

以浓盐酸为催化剂,采用乙酸酐酯化处理水溶性栀子蓝色素,制备了憎水性栀子蓝色素.探讨了栀子蓝色素与乙酸酐料液比、反应时间和反应温度等因素对憎水性栀子蓝色素色价的影响.结果表明:采用料液比1:20,在常温下反应4 h,为制备憎水性栀子蓝色素的最优条件.同时,通过红外光谱、可见吸收光谱及溶解性对栀子蓝色素的酯化改性进行了初步的探讨.     

基于OpenGL和MFC的石油井管道的绘制

介绍了O penGL的知识和石油井的基本概念,利用O penGL实现石油井管道的绘制,包括石油井数据的变换和管道起始点的跟踪和角度的旋转。纹理光照效果增强图形生动性,交互操作改变图形视角。并且利用DAO数据库和L istv iew控件实现数据保存和修改。该程序能够完成石油井的管道绘制和数据保存。     

Tri-Gate Bulk MOSFET Design for CMOS Scaling to the End of the Roadmap

A tri-gate bulk MOSFET design utilizing a low-aspect-ratio channel is proposed to provide an evolutionary pathway for CMOS scaling to the end of the roadmap. 3-D device simulations indicate that this design offers the advantages of a multi-gate FET (reduced variability in performance and improved scalability) together with the advantages of a conventional planar MOSFET (low substrate cost and capability for dynamic threshold-voltage control).