Organic light-emitting diodes based on an ambipolar single crystal

Slice-like organic single crystals of 1,4-bis(2-cyano-2-phenylethenyl)benzene (BCPEB) are grown by the physical vapor transport (PVT) method, and exhibit a very high photoluminescence quantum efficiency (Φ_PL) of 75%. The ambipolar behavior of BCPEB single crystals are confirmed using the time of flight technique. The high efficiency and balanced (μ_h = 0.059 cm²/Vs and μ_e = 0.070 cm²/Vs) carriers’ mobility imply that the BCPEB single crystal is a promising light-emitting layer in the diodes structure. Intense green electroluminescence (EL) from a diode has been successfully demonstrated at an applied electric field of 2 × 10⁵ V/cm.     

协同异构蜂窝层叠网络中的终端直通通信技术

终端到终端(device-to-device,D2D)的直通通信实现了联合蜂窝和移动自组网的无缝操作,大幅提高了系统频谱效率和网络容量.介绍了D2D局域网的理论概念和在实践中的应用挑战;并着重论述了跨层资源管理在解决D2D通信中于扰避免问题的重要性,给出了一个无线资源管理实例.数据结果显示,所提出的算法性能接近穷举搜索最优算法,并具有相对较低的复杂度.目前,D2D通信技术表现出能够获得系统高容量和充分利用无线资源的巨大潜力.     

关注健康，关注PM2．5——室内空气污染与正确选择家用空气净化器

对我国大气环境和室内环境空气污染的危害,空气净化技术和如何正确选择家用空气净化器给予介绍和分析。     

Microstructure, Thermal and Wetting Properties of Sn-Bi-Zn Lead-Free Solder

The microstructures, phase transformations, and wettability of Sn-Bi-Zn solder alloys were investigated by scanning electron microscopy, x-ray diffraction, and differential scanning calorimetry (DSC). The results show that the alloys are composed of primary Sn-rich phase or Zn-rich phase, (Sn + Zn) eutectic structure, and (Sn + Bi + Zn) ternary eutectic structure. The microstructural characterization of Sn-xBi-Zn alloys indicates that, with increasing Bi content, more of the eutectic (Sn-Bi-Zn) structures is formed. DSC profiles reveal that the eutectic peak of the samples did not differ very much, but the reaction temperature of the alloys decreases with increased Bi content. The spreading rates of solders increased with the addition of Zn, which affects the interfacial reactions between the solders and copper.     

UVOC-MAC: a MAC protocol for outdoor ultraviolet networks

As an alternative to radio-frequency (RF) communications, optical wireless communications can support high data rates and low power operations while providing good jamming resistance. Our focus in this paper is on deep ultraviolet (UV) outdoor communications (UVOC) where solar blind and non-line-of-sight operations are attractive. Light beams from UV light-emitting diode (LED) arrays serve as information carriers. In an abstract sense, this is similar to directional transmissions in RF; however, the physical (PHY) layer characteristics significantly differ due to atmospheric scattering. First, we perform extensive experiments on a UV testbed towards understanding signal propagation and the impact of the PHY on medium access. We find that UV propagation supports (a) fully duplex communications and (b) multiple data rate transmissions. Next, we propose a novel contention-based media access control (UVOC-MAC) protocol that inherently accounts for the UV PHY layer and fully exploits multi-fold spatial reuse opportunities. Evaluations via both simulations and analysis show that UVOC-MAC effectively mitigates collisions and achieves high throughput. In particular, up to a 4-fold increase in throughput and 50 % reduction in collision are possible compared to a MAC protocol agnostic to the UV PHY properties.     

Bioinspired Graphene Actuators Prepared by Unilateral UV Irradiation of Graphene Oxide Papers

Inspired by natural autonomous systems that demonstrate controllable shape, appearance, and actuation under external stimuli, a facile preparation of moisture responsive graphene‐based smart actuators by unilateral UV irradiation of graphene oxide (GO) papers is reported. UV irradiation of GO is found to be an effective protocol to trigger the reduction of GO; however, due to the limited light transmittance and thermal relaxation, thick GO paper cannot be fully reduced. Consequently, by tuning the photoreduction gradient, anisotropic GO/reduced GO (RGO) bilayer structure can be easily prepared toward actuation application. To get better control over the responsive properties, GO/RGO bilayer paper with a certain curvature and RGO patterns are successfully prepared for actuator design. As representative examples, smart humidity‐driven graphene actuators that mimic the cilia of respiratory tract and tendril climber plant are successfully developed for controllable objects transport.     

Supramolecular Chemistry in Molten Sulfur: Preorganization Effects Leading to Marked Enhancement of Carbon Nitride Photoelectrochemistry

Here, a new method for enhancing the photoelectrochemical properties of carbon nitride thin films by in situ supramolecular‐driven preorganization of phenyl‐contained monomers in molten sulfur is reported. A detailed analysis of the chemical and photophysical properties suggests that the molten sulfur can texture the growth and induce more effective integration of phenyl groups into the carbon nitride electrodes, resulting in extended light absorption alongside with improved conductivity and better charge transfer. Furthermore, photophysical measurements indicate the formation of sub‐bands in the optical bandgap which is beneficial for exciton splitting. Moreover, the new bands can mediate hole transfer to the electrolyte, thus improving the photooxidation activity. The utilization of high temperature solvent as the polymerization medium opens new opportunities for the significant improvement of carbon nitride films toward an efficient photoactive material for various applications.     

Strategies to Improve Field Emission Performance of Nanostructural ZnO

Nanostructural ZnO is a good candidate for field emission (FE) because of its high aspect ratio, controllable electrical conductivity, and good thermal and chemical stability. In order to improve the FE performance, ZnO nanopins, gallium-doped nanofibers, periodic nanorod arrays, and aligned nanotubes were designed and fabricated by a vapor-phase transport method using ZnO + C and ZnO + C + Ga₂O₃ powder mixtures, electrochemical deposition, and hydrothermal decomposition, respectively. The FE behaviors including threshold of electric field, emission current density, field enhancement factor, and stability are reviewed in this paper based on our previous works. Some strategies to improve the performance of the nanostructural ZnO field emitters are demonstrated.     

(Semi-)blind channel estimation for space time block coded system with transmit diversity

This paper deals with a blind channel estimation method for space-time coded block transmission system. By concatenating the real part and imaginary part of the received signal to form an elongated vector, we derive an equivalent input–output system model. Then channel state information (CSI) is blindly estimated using subspace method, utilizing only the redundancy inherent in space-time block coding (STBC) and cyclic prefix (CP). The estimation ambiguity, which is common to all blind methods, is analyzed in detail and we prove that there only exist four scalar indeterminacies. Three effective methods to eliminate the ambiguities are also proposed. Compared with other blind channel estimation methods for space time systems, this method needs neither redundant precoding nor oversampling, and thus has higher data rate. Besides, this method is robust to channel order overestimation, which is effectively demonstrated by numerical simulations. This work was supported by NSFC (60496310, 60672093), NSFJS(BK2005061) and BK2005061.