抗氧剂3114合成反应热力学和动力学的研究

研究了常温溶剂法合成抗氧剂3114反应热力学和动力学过程。控制温度在117±2℃,研究结果表明,反应是零级反应,反应速率常数k=1.91×10-3/min,反应的平衡常数K=138.4(mol/L)-6,反应活化能Ea=1366.2J/mol。     

Synthesis and Morphology of TiO2 Nanotube Arrays by Anodic Oxidation Using Modified Glycerol-Based Electrolytes

Titanium dioxide (TiO₂) nanotube arrays were prepared by electrochemical anodization of titanium sheets in the glycerol 176 mL/H₂O 44 mL/NH₄F 0.5 wt% electrolytes modified with H₂SO₄ and NaAc addition. The surface morphologies, average inner diameter, and the length of the nanotube arrays changed with the solution pH in the range from 5.6 to 4.0 by adding H₂SO₄. A uniform surface morphology of the nanotubes with average inner diameter of ∼80 nm and a length of ∼1000 nm was obtained when the solution pH was 5.0. The growth rates of the nanotubes were remarkably enhanced by NaAc addition in the range of 0.04–0.14 M . With NaAc addition of 0.10 M , the length of the nanotube arrays reached 4.16 μm after an 8-h anodization, increasing 3.23 μm compared with no NaAc addition. The relationship between solution pH and growth of TiO₂ nanotubes was analyzed by current–time curves, solution electrical conductivities, and scanning electron microscopy (SEM), and the role of NaAc was also discussed based on SEM and solution electrical conductivities.     

Nanocrystalline CeO2 in SBA-15: Performance of Pt/CeO2/SBA-15 Catalyst for Water-gas-shift Reaction

CeO₂ particles confined within the pores of an SBA-15 mesoporous silica host were prepared by incipient wetness impregnation (IMP) and deposition precipitation (DP) methods. The materials were characterized by XRD, N₂-adsorption and temperature programmed reduction (TPR) to evaluate the structure, texture, and redox properties. The preparation procedure had significant impact on the assembling mode of CeO₂ inside the SBA-15 mesopores. A high dispersion of CeO₂ particles was achieved via DP, whereas the dispersion of CeO₂ prepared by IMP was found to be inhomogeneous and CeO₂ partially blocked the pores. The CO conversion in the water-gas-shift reaction was enhanced over 1 wt% Pt supported on CeO₂-modified SBA-15 obtained by DP.     

CGA560增强助磨剂在水泥粉磨中的应用研究

研究了CGA560增强助磨剂在水泥粉磨中对台时产量和水泥质量的影响。试验结果表明:在磨机状况不改变的条件下,CGA560增强助磨剂的加入可提高磨机产量10%-30%;同时可有效减少过粉磨现象,优化水泥颗粒级配,提高了水泥粉磨细度及比表面积;因而使水泥强度等性能得到了明显改善和提高。     

红外热象仪对大化肥装置高压渣油气化炉的监测

介绍高压渣油气化炉炉温监测仪表红外热象仪的工作原理、组成和监测实例,并对此仪表的干扰因素ε提供了详细的去除办法。     

Oxidative dehydrogenation of ethane over Co–BaCO3 catalysts using CO2 as oxidant: effects of Co promoter

Co–BaCO₃ catalysts exhibited high catalytic performance for oxidative dehydrogenation of ethane (ODE) using CO₂ as oxidant. The maximal formation rate of C₂H₄ was 0.264 mmol · min⁻¹ · (g · cat.)⁻¹ (48.0% C₂H₆ conversion, 92.2% C₂H₄ selectivity, 44.3% C₂H₄ yield) on 7 wt% Co–BaCO₃ catalyst at 650 °C and 6000 ml. (g · cat.)⁻¹. h⁻¹. Co–BaCO₃ catalysts were comparatively characterized by XRF, N₂ isotherm adsorption-desorption, XRD, H₂-TPR and LRs. It was found that Co⁴⁺–O species were active sites on these catalysts in ODE with CO₂. The redox cycle of Co–O species played an important role on the catalytic performance of Co–BaCO₃ catalysts. On the other hand, the co-operation of BaCO₃ and BaCoO₃ was considered to be one of possible reasons for the high catalytic activity of these catalysts.     

Synthesis, isolation, spectroscopic and electrochemical characterization of some calcium-containing metallofullerenes

A few Ca-containing mono-metallofullerenes, i.e. Ca@C₇₆, Ca@C₈₈, Ca@C₉₀ (I, II), were synthesized by an improved DC arc discharge method and isolated by a multi-stage HPLC method for the first time. These isomer-separated metallofullerenes were characterized by LD-TOF MS and UV-vis-NIR spectrometry. Their HOMO-LUMO band gaps and possible molecular geometries are discussed according to the absorption spectra in this report. In addition, the cyclic and differential pulse voltammetry of Ca@C₇₆ was conducted in MeCN/C₆H₅CH₃ (1:4 v/v). The voltammograms of Ca@C₈₂ (II, III) and Ca@C₈₄ (II) were also recorded. Their electrochemical behaviors are discussed compared with those of corresponding ytterbium metallofullerenes. The features of the Ca metallofullerenes’ electronic structures are also discussed.     

Study of different effect on foaming process of biodegradable bionolle in supercritical carbon dioxide

Microcellular foaming of biodegradable Bionolle in supercritical CO₂ has been produced. The effects of a series of variable factors, such as saturation temperature, saturation pressure, and depressurization time and step on the foam structures and density, were studied through measurement of density and SEM observation. The experimental results show that higher saturation temperatures lead to an increase in bulk densities; and different depressurization time and step result in different product cell morphology. In addition, at some saturation temperature, the orientation of the cells can be found in the product morphology. XRD experimental results show that the foaming treatment with SC CO₂ increased the crystallinity of Bionolle. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2901–2906, 2006     

提纯乙型脑炎细胞培养疫苗的研究

应用截留分子量10万的超滤系统,将地鼠肾细胞乙型脑炎疫苗浓缩10～20倍,再以差速离心法提纯。所得提纯乙脑疫苗免疫原性及抗原效价均比原制苗明显提高,达到日本提纯苗的水平。经人体接种反应和效果观察表明,提纯苗反应轻微,血凝抗体4倍增长率占100%,GMT258.9,与常规苗相比有非常显著差异。     

传统民本论与现代民主的异同

分析了中国传统的民本思想与现代民主思想在权利主体、价值目的、实现方式和经济基础方面存在的本质区别和在重视人民作用、反对统治者专权、专利方面存在的一致性。发展当代中国的民主,应积极培育民众政治参与意识,清除官本位思想,加强法制建设,大力发展市场经济。