Estimating parameters of the synchronous twofold-stochastic flow of events

Consideration was given to estimation of the parameters of the synchronous twofold-stochastic flow of events which makes up a mathematical model of the information flow of demands circulating in the queuing systems and networks. Two variants were studied. For the first variant, the problem of optimal estimation of the parameters of a synchronous flow of events with a finite arbitrary number of states was solved. The second variant differs in that the event flow operates in the environment where part of events is lost during the so-called dead time. Consideration was given to a synchronous flow with two states. The problem of estimating the length of the dead time in the conditions of continued dead time was solved. The results of numerical estimation based on the simulation model of the synchronous flow were presented for both variants.     

Amine Coordinated Electron-Rich Palladium Nanoparticles for Electrochemical Hydrogenation of Benzaldehyde

Electrocatalytic hydrogenation (ECH) is a burgeoning strategy for the sustainable utilization of hydrogen. However, how to effectively suppress the competitive hydrogen evolution reaction (HER) is a big challenge to ECH catalysis. In this study, amine (NH₂ R)-coordinated Pd nanoparticles loaded on carbon felt (Pd@CF) as a catalyst is successfully synthesized by a one-step solvothermal reduction method using oleylamine as the reducing agent. An exceptional ECH reactivity on benzaldehyde is achieved on the optimal Pd@CF catalyst in terms of a high conversion (89.7%) and selectivity toward benzyl alcohol (89.8%) at −0.4 V in 60 min. Notably, the Faradaic efficiency for producing benzyl alcohol is up to 90.2%, much higher than that catalyzed by Pd@CF-without N-group (41.1%) and thecommercial Pd/C (20.9%). The excellent ECH performance of Pd@CF can be attributed to the enriched electrons on Pd surface resulted from the introduction of NH₂ R groups, which strengthens both the adsorption of benzaldehyde and the adsorbed hydrogen (H_ads) on Pd, preventing the combination of H_ads to form H₂, that is, inhibiting the HER. This study gives a new insight into design principles of highly efficient electrocatalysts for the hydrogenation of unsaturated aldehydes molecules.     

Privacy Preserving distributed smart grid system based on Hyperledger Fabric and Wireguard

Smart grid has drawn a lot of attention and investment in recent years, which not only helps the modern generation and distribution of traditional power but also highly widens the application of renewable energy sources. However, the main challenges in the application of smart grid are 1. the privacy preservation of users' information and 2. the trustful transmission channel among peers. In order to solve these problems, VPN and blockchain can be considered since they have some features perfectly suitable for these situations. In this paper, we propose a smart grid system based on WireGuard and Hyperledger Fabric to solve the problems mentioned above. And we also implement the whole system and give a view by web application. What's more, all the functionalities are displayed and tested, including building a smart device simulator, deploying data visualization and making some performance evaluations about transactions and WireGuard communication. Experiment results show that the introduction of WireGuard into network infrastructure does not cause too much loss of bandwidth and delay, but it ensures a certain degree of communication security. And Fabric provides the consistency and traceability of transactions in smart grid system.     

Semi-supervised transformable architecture search for feature distillation

Pattern Analysis and Applications - The designed method aims to perform image classification tasks efficiently and accurately. Different from the traditional CNN-based image classification methods,...     

Effect of Sintering Temperature on Magnetic and Electrical Properties of GdBaCo<Subscript>2</Subscript><Emphasis Type="Italic">O</Emphasis><Subscript>5 + <Emphasis Type="Italic">δ</Emphasis></Subscript>

In this study, we report the results of an investigation into the sintering temperature dependence of magnetic and transport properties for GdBaCo₂ O _{5 + δ} synthesized through a sol-gel method. The lowering of sintering temperature leads to the increase of oxygen content and the reduction of grain size. The increase of oxygen content results in the enhancement of magnetic interactions and the weakening of Coulomb repulsion effect, while the reduction of grain size improves the magnetoresistance effect. Metal-insulator transition accompanied with spin-state transition is observed in all samples.     

Viscosity of high-entropy melts in the Cu—Bi—Sn—In—Pb system

High-entropy melts in the Cu—Bi—Sn—In—Pb system have been studied by viscosity measurements during heating and subsequent cooling. The experimental data have been used to determine the temperatures at which microinhomogeneities in the melts irreversibly disappear.     

Tensile Properties and Failure Mechanism of a New 3D Nonorthogonal Woven Composite Material

Tensile properties and failure mechanism of a newly developed three-dimensional (3D) woven composite material named 3D nonorthogonal woven composite are investigated in this paper. The microstructure of the composite is studied and the tensile properties are obtained by quasi-static tensile tests. The failure mechanism of specimen is discussed based on observation of the fracture surfaces via electron microscope. It is found that the specimens always split along the oblique yarns and produce typical v-shaped fracture surfaces. The representative volume cell (RVC) is established based on the microstructure. A finite element analysis is conducted with periodical boundary conditions. The finite element simulation results agree well with the experimental data. By analyzing deformation and stress distribution under different loading conditions, it is demonstrated that finite element model based on RVC is valid in predicting tensile properties of 3D nonorthogonal woven composites. Stress distribution shows that the oblique yarns and warp yarns oriented along the x direction carry primary load under x tension and that warp yarns bear primary load under y tension.