Phenyl Selenosulfides as Cathode Materials for Rechargeable Lithium Batteries

The Se? Se bond in an organo‐diselenide (RSeSeR, R is an organic group) can break in a 2e^? reduction reaction, but it has limited capacity as a cathode material for rechargeable lithium‐ion batteries. To increase its capacity, redox active species (e.g., sulfur) can be added in the middle of the selenium atoms. Herein, phenyl diselenide (PDSe, PhSeSePh) is mixed with sulfur to form two hybrid compounds with 1:1 and 1:2 molar ratios, which almost double and triple the capacity of PDSe, respectively. Theoretical calculations suggest that phenyl selenosulfide (PDSe‐S, PhSe‐S‐SePh) and phenyl selenodisulfide (PDSe‐S₂, PhSe‐SS‐SePh) can form via addition reactions, which is supported by mass spectrometry analysis. The hybrid materials exhibit three highly reversible redox plateaus and enhanced cycling stability due to the reduced solubility of the discharge products. PDSe‐S and PDSe‐S₂ show initial capacities of 252 and 330 mAh g^?1, respectively, followed by stable cycling performance with a capacity retention of >73% after 200 cycles at C/5 rate. In addition, they show steady rate capabilities. This study reports a novel strategy to increase the electrochemical performance of organo‐diselenide by addition of sulfur.     

InP衬底上InAlAs异变缓冲层和高铟组分InGaAs的生长温度优化

利用气态源分子束外延技术在InP衬底上生长了包含InAlAs异变缓冲层的In0.83Ga0.17As外延层.使用不同生长温度方案生长的高铟InGaAs和InAlAs异变缓冲层的特性分别通过高分辨X射线衍射倒易空间图、原子力显微镜、光致发光和霍尔等测量手段进行了表征.结果表明, InAlAs异变缓冲层的生长温度越低, X射线衍射倒易空间图 (004) 反射面沿Qx方向的衍射峰半峰宽就越宽, 外延层和衬底之间的倾角就越大, 同时样品表面粗糙度越高.这意味着材料的缺陷增加, 弛豫不充分.对于生长在具有相同生长温度的InAlAs异变缓冲层上的In0.83Ga0.17As外延层, 采用较高的生长温度时, X射线衍射倒易空间图 (004) 反射面沿Qx方向的衍射峰半峰宽较小, 77K下有更强的光致发光, 但是表面粗糙度会有所增加.这说明生长温度提高后, 材料中的缺陷得到抑制.     

An authenticated re‐encryption scheme for secure file transfer in named data networks

With the fast progress of the Internet and communication technologies, the digital communication is increasingly based on the architecture of TCP/IP. Nevertheless, in TCP/IP's architecture, there are limitations such as data uncertainty and flow overloading. In response to this, a novel architecture has been proposed, which is known as the named data network (NDN). Named data network is an alternative network architecture based on the data each user accesses. Users gain accesses to the data by using an adjacent router (node) that verifies the correctness of the data. In NDN, the router has the capability to store and search for the data. Hence, this architecture largely improves the disadvantages in TCP/IP's architecture. Named data network is a new proposal and relatively under‐researched now. Thus far, an adequate secure file transfer protocol is still unavailable for NDN. In some cases, files are broken or the source fails to authenticate, which results in the need to discover the owner of the file. Furthermore, we believe that NDN should involve an authentication mechanism in the secure file transfer protocol. In view of the above, this paper presents an authenticated re‐encryption scheme for NDN, which offers sender authentication, data confidentiality, and support for potential receivers. Finally, we also propose a security model for sender authentication and prove that the proposed scheme is secure.     

Chromium-Based Metal–Organic Framework as A-Site Cation in CsPbI2Br Perovskite Solar Cells

Inorganic CsPbI_xBr_3−x perovskite solar cells (PSCs) have gained enormous interest due to their excellent thermal stabilities. However, their intrinsically poor moisture stability hampers their further development. Herein, a chromium-based metal–organic framework group is intercalated inside the inorganic Pb I framework, resulting in a new multiple-dimensional electronically coupled CsPbI₂Br perovskite. In this structurally and electronically coupled perovskite, the π-conjugated terpyridyl can delocalize the excited valence electrons of metal Cr³⁺ ion, enabling multi-interactive charge-carrier transport channels within CsPbI₂Br perovskites. The stability and efficiency of the produced devices are substantially enhanced in comparison to their counterparts with only a pristine CsPbI₂Br active layer. The optimized all-inorganic PSC yields a power conversion efficiency (PCE) as high as 17.02%. Remarkably, the stabilized device retains 80% of its PCE after 1000 h in the ambient atmosphere. This study provides a new paradigm toward addressing the stability challenge of the inorganic perovskite while enhancing its carrier transport ability.     

双信号单通道红外光传输

以FPGA作为控制核心,设计了一种脉冲频率调制(PFM)与脉冲宽度调制(PWM)对信号先后调制,并用红外光来进行同时传输的装置。发送端通过FPGA自带的高速AD对音频信号采样,通过PFM与PWM来实现音频信号的调制,接收端FPGA对光脉冲进行解调输出。设计中发射电路与接收电路完全采用分离元件进行构建,具有成本低、功耗小、传输效率高等优点。通过对设计结果的分析可以得到在12 m内,1～10 kHz的音频信号和数字信号能够在一个通道里进行无失真的实时传输。传输信号经过中继站实现信号向不同方向转发的功能。同时中继站的功耗为0.08 W,满足节能的要求。     

智能车载终端数据处理的优化设计

通过分析传统的GPS和车辆航位推算导航系统定位方法的不足,提出使用GPS/DR组合导航技术来获取定位数据,并使用一种新的数据融合方法优化定位数据,通过CDMA 1X无线数据网络改善传输方式.经过实验验证,此优化方案为车辆的实时监控提供了稳定可靠的实时数据传输,提高了ITS系统的性能.     

纳入城市规划、规范移动通信基站建设

本文分析了目前移动基站建设存在的主要问题及其产生根源,提出规范移动通信基站建设,将其作为城市公用设施纳入城市规划的观点.并根据国家及政府有关部门的政策法规及国内先行城市的成功经验,结合本市的实际情况,对规范移动通信基站建设的本地立法工作提出了建议.     

HSDPA引入后对原R99覆盖规划的影响

本文结合HSDPA覆盖策略,阐明在引入HSDPA后对原R99覆盖规划的影响.     

移动增值实时扣费业务的解决方案

通过理论与实例介绍如何针对移动预付费增值业务多样化、复杂化以及业务不断变更的需求。快速、灵活实现各种新增值业务的实时扣费，为广大移动预付费用户提供灵活费率资费的解决方案。