基于语义分析的设计实体智能搜索

本文提出了在设计联盟组织过程中实现互联网上设计实体智能搜索的方法。根据对互联网上设计实体搜索问题的分析建立了设计实体智能搜索策略；定义了提取设计实体查询向量和描述向量的语义分析规则；提出了基于语义分析的设计实体智能搜索算法；最后编程实现了各项功能。     

近终型金属铸造模具制造工艺设计分析与应用

近终型制模技术，可以缩短制模周期、降低生产成本。本文介绍近终型技术在制模工艺实际中的应用概况。并举出实例，指出近终型制模技术可以提高生产效率，快捷地制造出各种复杂的零件/金属模具，该技术有着广阔的应用前景。     

微晶纤维素在稀硫酸中的热解机制研究

以微晶纤维素为原料,通过热转化可以得到葡萄糖、乙酰丙酸等多种用途广泛的有机化合物,在此过程中也存在脱水碳化竞争反应,得到生物碳副产物.分别以酸浓度和温度为实验变量,采用高效液相色谱(HPLC)对样品的液体产物进行表征,探索微晶纤维素在稀硫酸溶液中的热分解转化机制.结果表明:微晶纤维素的热分解转化是连续反应和竞争反应同时存在的复杂反应过程;控制温度在180～200℃,酸浓度在0.05～0.1 mol/L时,可获得最大产率的葡萄糖(约21.90％);若温度为200℃,酸浓度为0.2 mol/L时,则主要产物为乙酰丙酸.     

Synergistic Flame Retardant Effects of Carbon Nanotube-Based Multilayer Nanocoatings

In an effort to develop highly functionalized flame retardant materials, hybrid nanocoatings are prepared by alternately depositing a positively charged polyaniline (PANi) and negatively charged montmorillonite (MMT) using the layer-by-layer (LbL) assembly technique. Carbon nanotubes (CNTs) are employed in polymer nanocomposites as effective reinforcement, where nanotubes are stabilized in MMT aqueous solution. The 3D structure and high density of CNTs deposited in the PANi/CNTs-MMT multilayers produce thicker and heavier coatings in comparison to the LbL assemblies without CNTs. Vertical and horizontal flame testing show that the incorporation of CNTs improves fire resistance. Additionally, cone calorimetry reveals that stacking two nanomaterials (MMT and CNTs) in a single coating shows a significant reduction in peak heat release rate (up to 51%), total smoke release (up to 47%), and total heat release (up to 37%) for the polyurethane foam. The enhancement of flame retardancy is attributed to a synergistic effect; MMT serves as a physical barrier that retards the diffusion of heat and gas. The addition of CNTs strengthens the thermal stability and high char yield. These results, coupled with the simplicity with which the LbL deposition is applied, present a viable alternative to halogen-free flame retardant nanocoatings to natural and synthetic fibers.     

Natural Polysaccharides as Multifunctional Components for One-Step 3D Printing Tough Hydrogels

Natural polysaccharides (NPS) are regarded as biomolecular and structural components for preparing high-performance tough hydrogels. But the one-step fabrication of NPS-containing hydrogels in seconds and the template-free design of complicated high-resolution structures are still significant challenges in this field. To meet these requirements, various NPS-containing tough hydrogels are fabricated and processed into 2D/3D structures via the combination of Ru(bpy)₃²⁺-mediated photochemistry and extrusion 3D printing technique. The whole fabrication process is one-step, completed in tens of seconds under visible light irradiation. It is found that the used NPS plays a key role in achieving the fabrication of high-performance structured tough hydrogels. The high reactivity of functional groups in the used NPS can shorten their gelation times. Long rigid chains of the used NPS, their hierarchical assemblies, and contrasting multinetworks benefit from the efficient dissipation of mechanical energy and enhancement of its operational stability. Strong supramolecular interactions enable hydrogel precursors to have high viscosities, therefore providing good controllability to design high-resolution and complicated tough hydrogel structures via extrusion 3D printing. It is anticipated that this straightforward fabrication strategy and findings will open new horizons for NPS-containing materials.     

炼厂硫腐蚀的典型案例分析及解决措施

通过硫在不同温度与环境下对金属材料腐蚀的典型案例分析，简述其腐蚀机理与解决,工对今后炼厂高硫油加工提出进一步建议。     

液压夹轨装置夹不紧原因分析及夹轨装置的改造

本文通过对液压夹轨装置结构和机理分析，指出原设计夹轨装置预留压紧量(Smax-S)不足是导致夹轨装置锁不紧的主要原因，并对相应间隙和零件进行了调整和改造，解决了拖车的锁紧问题。     

CoCrPtNb／CrTi／C多层膜记录介质的制备和性能研究

采用CoCrPtNb四元合金作磁记录介质，并采用多层膜结构（CoCrPt）100-Nbx/CrTi／C／Glass制备玻璃盘基硬盘。实验结果表明：采用适宜厚度的籽晶层与合适组分的底层和磁性层的多层膜结构，即使在室温下溅射，此种薄膜磁记录介质也可得到高达260kA／m的矫顽力；在550℃高温下，经过30min真空退火后，其矫顽力有较大幅度提高，并在Nb含量为2．4％（原子分数）时达到极大值386kA／m，适用于高密度磁记录。同时，也详细分析了磁性层和底层组分、籽晶层厚度以及真空退火对磁记录介质磁性能和微结构的影响。     

季胺萃取锌的动力学研究

以恒界面池法研究了氯化物介质中季胺萃锌的动力学。考查了搅拌转速、传质界面积和温度对萃取速率的影响，判定季爱萃锌为界面化学反应的动力学模式。进一步研究了季胺萃取剂浓度和水相Ｚｎ＾２＋浓度对萃取速率的影响，得到了与理论推断相吻合的速率方程。