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31.
A feasibility analysis methodology adopted from reactive distillation is applied to membrane reactors. A model is formulated to depict the reactive liquid phase composition on the retentate side of a continuous type membrane reactor. The effects of both the chemical reaction kinetics and the membrane mass transfer kinetics on the feasible products are elucidated by means of retentate phase diagrams and bifurcation analysis. The proposed method can be applied to various membrane processes, independent of the specific structure of the membrane. Two quaternary reaction systems are considered to illustrate the methodology. In the first hypothetical system, it is shown how selective membranes can influence the sequence of effective volatilities which in turn affects the feasible products of the system. In the second example of practical importance, i.e. the heterogeneously catalysed synthesis of propyl acetate coupled with permeation through a porous polycarbonate membrane, the dusty gas model is applied to describe the component fluxes through the membrane. For the latter reaction system, the existence of reactive arheotrope is demonstrated. Arheotropes represent mass transfer controlled feasible products of membrane separation process. 相似文献
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镁钴铝类水滑石催化合成安息香甲醚 总被引:1,自引:0,他引:1
采用共沉淀法制备了镁钴铝类水滑石化合物(MgCoAl-HTLcs),并用 X 射线衍射、扫描电子显微镜、NH_3程序升温脱附等方法对 MgCoAl-HTLcs 进行了表征,并以 MgCoAl-HTLcs 为催化剂催化苯甲醛与甲醇反应合成安息香甲醚,研究了n(Mg):n(Co):n(Al)、催化剂用量、原料配比、反应温度、反应时间对合成反应的影响。表征结果显示,MgCoAl-HTLcs 的晶相完整,表面主要为弱酸、弱碱性。催化合成安息香甲醚的适宜条件为:MgCoAl-HTLcs 催化剂用量0.10 g(约为原料总质量的0.23%),n(Mg):n(Co):n(Al)=0.4:1.6:1.0,V(苯甲醛):V(甲醇)=3:50,反应温度50℃,反应时间150 min。在此条件下,苯甲醛的平衡转化率达77.49%,安息香甲醚选择性接近100%。为洁净合成安息香甲醚开辟了一条新的途径。 相似文献
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In this paper, we present a static load balancing method for mapping production rules in an expert system onto processors of a message-passing multicomputer. The method uses simulated annealing to achieve a nearly optimal allocation of production rules onto processor nodes. The approach balances the initial rule distribution to avoid higher communication demand among processor nodes at run time. A formal mapping model is developed and a new cost function is defined for the annealing process. New heuristic swap functions and cooling policies are provided to ensure the quality of the annealing process. A software load balancing package, SIMAL, was implemented on a SUN workstation to carry out the benchmark experiments. The overhead associated with this mapping method is O(m In m), where m is the number of rules in the production system. Two benchmark production systems, Toru-waltz and Tourney, are mapped onto a hypercube computer with 32 nodes. Experimental benchmark results verify the effectiveness of the rule mapping method. The method can be applied for distributed artificial intelligence processing or for the parallel execution of cooperating expert systems on a message-passing multicomputer. 相似文献
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Myung-Sun Baek Hyung-Joon Kook Mi-Jeong Kim Young-Hwan You Hyoung-Kyu Song 《Broadcasting, IEEE Transactions on》2005,51(4):551-559
In this paper, we apply multi-antenna scheme to DAB system for high-rate transmission. In the MIMO-DAB system with a number of transmitting and receiving antennas increases the transmission rate efficiently with low multiplication operations. For channel estimation in the MIMO-DAB system, we propose a new PRS structure and evaluate the channel estimation performance. The proposed PRS structure can estimate multi-channel information based on the semi-blind processing. The performance of proposed PRS is compared with that of conventional training sequence employing Tarokh's transmission matrix. And also we investigate the performance limitation due to the imperfect channel estimation in a MIMO-DAB receiver. It has been shown that the MIMO-DAB system with multi-antennas can achieve the high-rate transmission for multimedia broadcasting and the performance of MIMO-DAB system is impaired by imperfect channel information. 相似文献
38.
Central to cost-based competition is the capability to accurately predict the cost of delivering a project. Most literature on cost estimation focuses on specific estimation methods as generic techniques and little attention has been paid to the unique requirements at each project stage. This note attempts to identify the critical factors for effective estimation at various stages of typical construction projects. Drawing from organization control theory and cost estimating literature, this note develops a theoretical framework that identifies the critical factors for effective cost estimation during each project phase of a conventional construction project. The underlying logic is that as a cost estimating effort progresses, both task programmability and output measurability improve. As a result, control effort will shift from input-oriented control to a combination of output and behavior control. 相似文献
39.
设{Z,(W)}是定义在概率空间上的独立的随机变量序列,Z(W)具有方差为期望E(Zn)=0.本文证明了对任意算数序列{bn}及任意的存在充分大的整数N>0使当N'>N″>N时.有此不等式在随机级数研究中有重要作用. 相似文献
40.
通用串行总线(USB)数据传输模型 总被引:1,自引:1,他引:0
USB作为一种数据传输接口,了解它的通信传输机制是正确利用USB利用数据传输的基础,分层次结构对USB数据传输模型加以分析,可以使读者建立起USB体系结构、通信模型和总线事务的框架和概念,并最终对USB传输工作流程有一个清晰的认识。 相似文献