Kinetic model of block photopolymerization of glycidyl methacrylate to high conversion

The kinetics of glycidyl methacrylate block polymerization to high conversion was experimentally investigated with variations of the photoinitiator concentration, temperature, and power of UV illumination. The kinetic curves of this polymerization process contain three characterized sections of coordinates of “conversion–time,” namely: The first one is practically linear to a conversion of ≈0.5, the second represents, by itself, the autoacceleration process, and the third presents the autodecelation process. An additional peculiarity of such a polymerization process is poor reproduction of the kinetic measurements. This reproduction does not correspond to instrumental error. Derivation of a kinetic model for block linear polymerization was done. This model is, quantitatively, in good agreement with all the data of the experimental material. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3556–3569, 2002     

Enhancement of heat and mass transfer in a plane channel with turbulizers on one of the walls

The effect of turbulizing asperities positioned on one of the walls of a plane channel on the intensity of exchange processes near a smooth wall with injection of different working media is studied experimentally. Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 70, No. 3, pp. 404–408, 1997.     

Effect of repositioning of rhodium direct-charge detectors in a RBMK-1000 reactor on fuel and emitter-material burnup coefficients

Scientific-Technical Center “Atomtekhénergo.” Leningrad Nuclear Power Plant. N. V. Sultanov Institute of Nuclear Reactors, Russian Scientific Center “Kurchatovskii institut.” Translated from Atomnaya énergiya, Vol. 76, No. 6, pp. 470–473, June, 1994.     

Analytical solution of a system of nonlinear measuring equations of a 12-pole microwave reflectometer

Analytical solution of a system of nonlinear measuring equations of a 12-pole microwave reflectometer was obtained. Criteria for selecting a true solution in the general case were developed and the analysis was conducted for a number of particular cases that may generate practical interest.     

Structure Formation in Densely Sintered Household Ceramics

The formation specifics of the structure and phase composition of densely sintered ceramics based on a low-melting argillaceous material from Belarus together with a combined flux and a grog additive are investigated. The correlation between the physicochemical properties, structure, phase composition, and the time-temperature firing schedules of the developed materials are investigated. Electron probe microanalysis makes it possible to monitor variations in the chemical composition at various local sites and compare it with the estimated composition of the mixture. The optimum regimes for the heat treatment of articles are determined. __________ Translated from Steklo i Keramika, No. 6, pp. 32 – 36, June, 2005.     

Nutrient removal performance of an anaerobic–anoxic–aerobic process as a function of influent C/P ratio

The laboratory scale anaerobic–anoxic–aerobic (A²O) process fed with synthetic brewage wastewater was designed to investigate the effects of changing feed C/P ratio on the performance of biological nutrient removal (BNR) processes. In the experiment, the influent chemical oxygen demand (COD) concentration was kept at approximately 300 mg L^?1 while the total phosphorus concentration was varied to obtain the desired C/P ratio. Results showed that when the C/P ratio was lower than 32, phosphorus removal efficiency increased as C/P ratio increased linearly, while when the C/P ratio was higher than 32, the P removal efficiency was maintained at 90–98%, and effluent P concentration was lower than 0.5 mg L^?1. However, regardless of the C/P ratio, excellent COD removal (90% or higher) and good total nitrogen removal (75–84%) were maintained throughout the experiments. It was also found that very good linear correlation was obtained between COD uptake per unit P released in the anaerobic zone and C/P ratio. In addition, the P content in the wasted activated sludge increased with the decrease in the C/P ratio. Based on the results, it was recommended that the wastewater C/P ratio and its effects be incorporated into BNR design and operational procedures, appropriate C/P ratios were used to achieve the effluent treatment goals. Copyright © 2005 Society of Chemical Industry