Co^3＋—modified Surface of LiMn2O4 Spinel for its Improvementof Electrochemical Properties

Cobalt was used to modify the surface of spinel LiMn2O4 by a solution technique to produce Co^3 -modified surface material (COMSM). Cobalt was only doped into the surface of LiMn2O4 spinel. XPS(X-ray photoelectron spectroscopy) analysis confirms the valence state of Co^3 . COMSM has stable spinel structure and can prevent active materials from the corrosion of electrolyte. The ICP(inductively coupled plasma) determination of the spinel dissolution in electrolyte showed the content of Mn dissolved from COMSM was smaller than that from the pure spinel. AC impedance patterns show that the charge-transfer resistance (Rct) for COMSM is smaller than that for pure spinel. The particles of COMSM are bigger in size than those of pure spinel according to the micrographs of SEM(scanning electron microscopy). The determinations of the electrochemical characterization show that COMSM has both good cycling performance and high initial capacity of 124.1 mA/h at an average capacity loss of 0.19 mAh/g per cycle.     

基于B/S模式的汽车零件销存管理信息系统的设计与实现

对于采用连锁经营的汽车零件销售企业来说,各经营网点分布在同一城市的不同区域或不同城市,为了在充分利用原有信息和资源的基础上处理好许多中间环节,减少人员工作量,保证企业销存状态良好,提高管理效率,设计了基于B/S模式的汽车零件销存管理信息系统的技术方案,详细讨论系统的功能设计以及实现技术。     

EPON:下一代接入网的最佳选择

EPON技术具有大带宽、高性价比、结构简单和一定服务质量保证等特点,被业界普遍看好,成为 下一代接入网的最佳候选技术.本文主要介绍了EPON的工作原理、分层结构、接入控制和组帧方式,最后给出 了实现EPON的关键技术和难点以及EPON的发展近况.     

The effect of pack-aluminisation on the microstructure of MCrAlY and the performance of thermal barrier coatings

Plasma spraying and pack-aluminising processes were combined and applied to the nickel-base superalloy Mar-M247 to improve its cyclic oxidation resistance. The performance tests of duplex ZrO₂-8 wt.%Y₂O₃/MCrAlY thermal barrier coatings (TBCs) were conducted at 1050 °C, 1075 °C, 1100 °C, 1150 °C and 1200 °C. The results of the experiments in this study showed that TBC specimens with the aluminised MCrAlY bond coat exhibited higher cyclic lives (except for the Ni-22Cr-10Al-1Y bond coat), at all the temperatures tested, than specimens on which the bond coat was not aluminised. The microstructures of the Co-29Cr-6Al-1Y, Co-32Ni-21Cr-8Al-0.5Y and Ni-22Cr-10Al-1Y bond coats with or without aluminising treatment were examined in detail using a scanning electron microscope equipped with an electron probe microanalyzer.     

非均相成核中间相炭微球的形成过程及其结构演变

以含有喹啉不溶物的煤焦油沥青为原料，在410℃、不同反应时间下获得一系列中间相炭微球(MCMB)和小于0．5μm的碳质颗粒(SCP)。通过对中间相沥青的软化点、族组成和MCMB、SCP的形貌及MCMB断面结构的分析，认为非均相成核MCMB的形成和生长过程不同于均相成核的融并生长过程，而是SCP碳质颗粒的构筑过程，我们称之为“球形基本单元构筑”过程。在MCMB生长过程中，体系的黏度对SCP的形成和MCMB的生长起着重要的作用。非均相成核MCMB的内部结构不是三种模型结构(“地球仪”型、“洋葱”型和“同心圆”型)中的任一种，而是炭层具有收缩点的复杂结构，并且球体的结构不具有“继承性”，即随着反应时间的延长而不断发生变化和调整。MCMB内部分子在球体生长过程中的主要变化趋势是分子的不断缩合长大，而不是分子片层的平行趋向。     

含锂霞石颗粒和硼酸铝晶须的铝基复合材料

为了制备具有低热膨胀系数和较高强度的复合材料，选用具有负体膨胀系数的β-锂霞石颗粒和高强度的硼酸铝晶须作为复合材料组分，用挤压铸造法制备了6061铝基复合材料，并对该复合材料的显微结构、拉伸性能和热膨胀性能进行了研究，结果表明，该复合材料能同时获得较低的热膨胀系数和较高的强度；通过改变复合材料中β-锂霞石和硼酸铝的体积分数，在较大的范围内可以对复合材料的强度和热膨胀系数进行设计和调节。     

产品设计方案的多目标决策分析及其智能支持系统

用模糊多目标决策方法对产品设计方案进行决策分析并设计出相应的智能计算机支持系统，实例证明这一方法在实际应用中是有效的和可靠的。     

An efficient approach for calculating the dispersions of photonic-crystal fibers: design of the nearly zero ultra-flattened dispersion

A novel and efficient approach is proposed to calculate the dispersions of the guided modes of the photonic-crystal fibers (PCFs). Based on the vector boundary-element method (VBEM), the surface integral equations for the first and second derivatives of the propagation constants with respect to the wavelength are explicitly derived. Compared with the three-point finite-difference approach, which needs to solve and search three effective indexes near the interested wavelength, this approach can determine the dispersions of the PCFs by only solving one effective index at this wavelength based on the derived formulations. This novel approach saves over 60% computing time without losing the accuracy. Based on this approach, a novel four-ring PCF is designed by optimizing only three geometrical parameters to achieve the nearly zero ultra-flattened dispersion property. Compared with previously presented dispersion-flattened PCFs, the design procedure for the four-ring structure could be more efficient and easier because relatively lesser parameters need to be optimized.     

60Co辐照预处理对苹果片脱水特性和品质的影响

进行了不同辐照剂量、热风温度、切片厚度对苹果脱水速率及品质的影响试验,结果表明该三因子影响苹果片的脱水速率和外观质量.辐照剂量增加,热风温度增高,脱水速率高,VC含量和复水比下降.辐照剂量、热风温度、切片厚度三因素对脱水速率和干制品的外观质量、VC含量、复水比等四指标大都呈显著影响.     

一种控制盐层段井眼闭合率的钻井液密度新公式

针对钻井过程中钻遇的盐层段井眼蠕变缩径问题,利用弹塑性力学理论,蠕变本构方程采用Heard蠕变方程,在平面应变和均匀地应力假设下,推导出控制井眼收缩的钻井液密度新公式,该公式与前人推导的公式不同。通过理论分析,指出产生差异的根本原因在于蠕变应力差(极坐标下表示的径向应力与切向应力之差)公式的推导上,用有限元法计算结果对理论公式进行检验,证明是可行的。对文中的力学模型采用有限元法建模、求解,利用求解结果对各应力差公式进行验证,得出:根据文中公式计算结果与有限元法计算结果完全一致,而据前人公式计算结果偏离有限元计算值较大,从而间接证明了该钻井液密度新公式的推导更严密,更准确。