Electrochemical properties of some cobalt antimonides as anode materi-als for lithium- ion batteries

Some cobalt antimonides have been prepared and studied as the candidate anode materials for lithium ion batter-ies. Reversible capacities of 424,423 and 546 mA·h·g-1 were measured at the first cycle for as-solidified CoSb2, CoSb3 and annealed CoSb3 respectively. A low lithium ions diffusion coefficient in the order of 10-16 m2·s-1 was estimated from the coulometric titration measurements in the annealed CoSb3 electrode. It was found that the electrochemical properties of fine powders are significantly better than coarse powders. However the SEM picture shows that the nano-sized CoSb3 powders gathered to larger granules, which worsens somewhat the capacity retention of the nano-sized materials, although the volume capacities of the annealed and ball milled CoSb3 remain near twice of that of graphite after 50 cycles.     

Temperature Dependence of the Magnetocrystalline Anisotropy in Nd_2Co_(14)B Compound

Easy and hard magnetization curves of Nd_2Co_(14)B compound have been measured withextracting-sample-magnetometer(μ_0H_(max)=6T)at 10～300 K.Magnetic anisotropy constants K_1 and K_2have been determined by fitting the hard magnetization curves,in which only K_1 ,K_2 and misalignment anglehave been taken as fitting parameters.The values of K_1 and K_2 at 4.2 K were derived by extrapolation.Anisotropy coefficients,x_2~° and x_4~°were derived from the anisotropy constants.The anisotropy constant K_2increases rapidly with increasing temperature when TT_(sr).The temperature depen-dence of the magnetic anisotropy coefficient x_2~° was fitted with the formula.The anisotropy coefficients x_2~°can be well described by the tenth-power law from 4.2 K to T_(sr)and by the sixth-power law from T_(sr_ to 300 K.     

40Cr钢渗氮过程中碳原子的迁移

将正火４０Ｃｒ钢样在不同温度下进行不同时间的气体渗氮，对其横断面进行波谱分析，发现渗氮前沿附近自始至终存在着典型的贫碳区，其两侧为富碳区，透射电镜分析结果表明，碳原子的重新分布包括碳化物的回溶、碳的扩散及碳化物长大三个过程。     

压铸机偶发故障期可靠性管理及应用

机器工作可靠度与机器的固有可靠度和使用可靠度密切相关。设备使用厂家通过对机器偶发故障期使用可靠度的研究，采取有效对策来保证和提高机器工作可靠度，是提高企业效益的途径之一。本文针对压铸机，进行了故障规律分析，介绍了偶发故障期可靠度的计量公式，提供了各故障期的经验数据，详述了应用可靠性技术的基础工作范围和内容，叙述了应用效果     

Cooling strategies for cryogenic machining from a materials viewpoint

This article discusses the cooling strategies for cryogenic machining from a materials viewpoint. It is argued that, because different materials respond to temperature and machining processes differently, different cooling strategies are needed to improve the machinabilities of materials by cryogenic machining. In this work, five workpiece materials such as AISI1010 low-carbon steel, AISI1070 high-carbon steel, AISIE52100 bearing steel, titanium alloy Ti-6Al-4V, and cast aluminum alloy A390 were studied experimentally at various temperatures. Based on the experimental results of the cryogenic properties of the materials and their known machining characteristics, the cooling strategies for cryogenic machining of these materials were analyzed.     

BREAKAGE MECHANISM OF TUNGSTEN BASED ALLOY BLOCK FOR ELECTRO-HEAT UPSETTING

The breakage mechanism of W-Ni-Fe alloy in the process of electro-heat upsetting studied both theoretically and experimetnally, and also the behaviors of crack formation and propagation were analysed. Alloy suffers from corrosion and thermal-mechanical fatigue mutual function. Simultaneously, the practical ways to improve the anvil life was discussed.     

稀土添加剂在镀硬铬中的应用

介绍了标准镀铬液中加入稀土添加剂进行低铬酸镀硬铬工艺及应用生产情况,以及取得的经济效益。     

激光快速成形Rene′88DT高温合金的时效强化研究

研究了时效时间对激光快速成形后时效硬化镍基高温合金Rene′88DT中沉淀相组织演化和力学性能的影响。发现随时效时间的增加，沉淀相y’略有长大，颗粒之间发生大颗粒吞噬小颗粒的粗化，时效40h后沉淀相颗粒粗化明显。对经不同时间时效后的激光快速成形Rene′88DT试样进行了硬度测试。结果显示，在时效时间为28h时，硬度有一峰值HRC49。在此基础上，采用1165℃，2h固溶、空冷＋760℃，28h时效的热处理工艺对激光快速成形标准拉伸棒样进行了热处理，拉伸结果显示成形件的抗拉强度较激光沉积态提高了400MPa，屈服强度接近同种材料的粉末锻造水平。     

含B2O3渣系的热力学计算模型

根据炉渣结构的共存理论和相图，推导了ＣａＯＢ２Ｏ３和ＦｅＯＦｅ２Ｏ３Ｂ２Ｏ３渣系的热力学计算模型。结果表明：（１）理论计算的ＣａＯＢ２Ｏ３渣系的作用浓度ＮＣａＯ及ＮＢ２Ｏ３与实测的活度ａＣａＯ及ａＢ２Ｏ３一致；（２）理论计算的ＦｅＯＦｅ２Ｏ３Ｂ２Ｏ３渣系的氧化能力ＮＦｅｔＯ与实测的炉渣ＦｅｔＯ的活度值相符合。这说明本文提出的热力学计算模型是合理的。     

移动定位技术的现状与发展趋势

基于位置服务为人们的日常生活带来了极大的方便,同时也推动了移动定位技术行业的快速发展。针对移动定位技术发展状况,分析目前主流定位技术的优劣,并对取得的突破作简单的总结归纳。