丙烯酸二甲氨基乙酯的合成

以丙烯酰氯与二甲氨基乙醇为原料 ,乙醚为溶剂 ,过量的二甲氨基乙醇为缚酸剂合成了丙烯酸二甲氨基乙酯。较佳实验条件为 :丙烯酰氯 /二甲氨基乙醇 /乙醚 (物质的量比 ) 1∶2 .0 5∶5 .6 ,反应温度 5℃ ,反应时间 4h ,w(吩噻嗪 ) 0 .5 0 %,产物为无色透明液体 ,相对密度 0 .943 1( 2 0℃ ) ,折光率为 1.435 2 ,收率大于 91%。     

柴油抗蜡分散剂的工业应用

柴油抗蜡分散剂PDN -3 0 2 3应用试验表明 ,抗蜡分散剂能有效改变蜡结晶的形状及尺寸 ,抑制蜡结晶的生长 ,有助于蜡晶体在柴油中分布得更均匀。     

Synthesis and properties of PDMS modified waterborne polyurethane–acrylic hybrid emulsion by solvent-free method

A new type of polysiloxane modified polyurethane–acrylic hybrid emulsion was synthesized by solvent-free method and the polysiloxane was introduced into the soft segment of polyurethane chains using dihydroxybutyl-terminated polydimethylsiloxane (PDMS). The formed film from the hybrid emulsion could provide obviously higher water-resistance property. The preparation technologies such as the content of carboxy group and acrylic monomer, the rate and the time of emulsification were discussed systematically. The chain structure and the particle size were confirmed by the analysis of Fourier transform infrared spectroscopy and transmission electron microscopy, respectively. The effect of PDMS content on the water resistance and the mechanical property were investigated by absorbed water ratio, water contact angle and dynamic mechanical measurement.     

Particle distribution and interfacial reactions of Al–7%Si–10%B<Subscript>4</Subscript>C die casting composite

Aluminum–boron carbide particle reinforced composite is an advanced material which can be used in applications such as neutron-shielding components, aircraft, and aerospace structures. In the microstructural characterization of an Al–7%Si–10%B₄C die casting, attention is particularly focused on particle distribution and interface reaction products between B₄C particles and the aluminum matrix. The quantitative analysis results show that, in a cross-section of the cast part, more particles concentrate in the center and fewer particles are present in the wall regions. Moreover, some particle segregation bands have been observed. The mechanisms of the particle migration are proposed to describe the phenomenon. However, the average particle fraction in any cross-section of the cast part is almost the same. A barrier layer consisting of several sublayers was detected on the surface of B₄C particles. Using electron diffraction in selected areas, it is found that these sublayers are composed of Al₃BC crystals, TiB₂ crystals, Si crystals, and coarse stick-shaped TiB₂ particles. In addition, it is observed that Si plays an important role in the formation of a dense barrier layer. The barrier layer can limit B₄C decomposition and improve B₄C stability in the aluminum melt.     

An empirical investigation of bias and variance in time series forecasting: modeling considerations and error evaluation

Bias and variance play an important role in understanding the fundamental issue of learning and generalization in neural network modeling. Several studies on bias and variance effects have been published in classification and regression related research of neural networks. However, little research has been done in this area for time-series modeling and forecasting. We consider modeling issues related to understanding error components given the common practices associated with neural-network time-series forecasting. We point out the key difference between classification and time-series problems in consideration of the bias-plus-variance decomposition. A Monte Carlo study on the role of bias and variance in neural networks time-series forecasting is conducted. We find that both input lag structure and hidden nodes are important in contributing to the overall forecasting performance. The results also suggest that overspecification of input nodes in neural network modeling does not impact the model bias, but has significant effect on the model variance. Methods such as neural ensembles that focus on reducing the model variance, therefore, can be valuable and effective in time-series forecasting modeling.     

导数火焰原子吸收法对调味品中锌的测定

将微量脉冲进样技术和导数火焰原子吸收法结合，建立了测定调味品中锌含量的新方法。该方法的检出限为0．013μg／mL，精密度4．46％，回收率96．67～113．33。