Synthesis of TiO<Subscript>2</Subscript> Hybrid Molecular Imprinted Polymer for Ethofumesate Linked by Silane Coupling Agent

TiO₂ hybrid molecular imprinted polymer (MIP) for ethofumesate using methacrylic acid (MAA) as the functional monomer and silane coupling agent 3-(trimethoxysilyl) propylmethacrylate (KH570) as organic–inorganic connective bridge was synthesized via photo-excitation method. Hydrogen bond was proved to act between MAA and ethofumesate for pre- and post-polymerization binding properties as testified by UV spectrometric method. KH570 modified TiO₂ nanoparticles were prepared via sonochemical reaction, which can accelerate hydrolysis, increase collision chance for the reactive system and improve the dispersion of the nanoparticles. Scanning electron microscope (SEM), transmission electron microscope (TEM), binding and the adsorption kinetics experiments as well as thermogravimetric analysis (TGA) were employed for characterization. The results indicated that the hybrid MIP revealed a larger surface area and more ordered imprinting cavities with improved thermal stability compared to organic-only MIP. Furthermore, faster adsorption kinetics and enhancive adsorption capacity were achieved, which made it promising in chemical sensor applications.     

Formation mechanism of 21R AlN-polytypoids in aluminothermic reduction and nitridation process

Synthesis of 21R AlN polytypoids was investigated using Al and ultrafine SiO₂ powder in a flowing nitrogen atmosphere by means of thermal gravity (TG), differential scanning calorimeter (DSC), X-ray diffractometer (XRD) and scanning electronic microscope (SEM) linked with energy dispersive spectrometer (EDS). The results showed that the formation mechanism of AlN polytypoids was different from that in reaction sintering process using Si₃N₄, AlN, Al₂O₃ and other sintering additive as raw materials. It was suggested that firstly Al reduce SiO₂ into Si and is also nitrided into AlN, then AlN, Al₂O₃ and SiO₂ dissolve into silicon liquid until the AlN polytypoids precipitate in saturated liquid in a flowing nitrogen atmosphere at lower than 1700 °C.     

碳酸盐岩气藏加砂压裂重复改造试验效果分析

针对碳酸盐岩气藏部分气井生产效能低的状况，决定在长庆气田下古生界尝试开展加砂压裂重复改造试验，以期提高低产、低效气井的产量，延长气田稳产期。通过潜心研究、精细设计及现场质检监控，优选了4口老井进行加砂压裂重复改造现场试验。从试验结果来看，虽然只有1口井取得明显的改造效果，但4口井加砂压裂施工都是成功的，说明对碳酸盐岩气藏实施加砂压裂是可以实现的，但在选井思路和压裂工艺方面还有待探索和研究。     

蓝牙技术及应用简析

蓝牙（Bluetooth）技术是一种短距离无线电技术,利用“蓝牙”技术,能够有效使数据传输变得更加迅速高效。本文主要介绍蓝牙的关键技术及其未来的发展趋势。     

新型刮刀钻头的设计及现场试验研究

在理论分析的基础上，综合PDC钻头和刮刀钻头的优点，设计了一种新型的刮刀钻头，并进行了现场试验。现场试验结果表明，该钻头运转平稳，采用低钻压、高转速，钻进速度快，井眼规则通畅，有较明显的防斜作用，该种钻头的推广应用对提高钻井工程的整体效益具有十分重要的意义。     

工程钻机在沙卵石地区的物探钻井

川西平原属沉积平原，不到2m厚的表土下面全是沙卵石，沙卯石厚度达二、三十米。地面覆盖农田，沟垄纵横，限制了车载钻机的进入。以往地震勘探多采取浅井组合方式激发，所获得的地震资料能量差、面波强，对农田破坏面积大。若使用SH30—2A型轻便工程钻机，配上自制的冲击管，采取冲击钻进，从管中下药柱的方式，可实现沙卵石地区的深井激发，提高资料采集质量，且效率高、成本低。     

Aging response of the young’s modulus and mechanical properties of Ti-29Nb-13Ta-4.6Zr for biomedical applications

Alloys for implant devices require improved strength but a reduced Young’s modulus, in order to become mechanically more compatible with adjacent bone tissues. In this study, a new metastable β-type titanium alloy, Ti-29Nb-13Ta-4.6Zr (wt pct), was subjected to aging treatment to produce different microstructures, and the resulting mechanical properties, including the Young’s modulus, were measured. The Young’s modulus of this alloy is found to be sensitive to microstructures generated by various heat treatments. For microstructures varying from (α + β) to (α + β + ω) and (β + ω), the Young’s modulus increases with an accompanying increase in tensile strength and hardness, but decreases in ductility. The (β + ω) microstructure has a low strength, high modulus, and poor ductility and cannot be used for biomedical applications. For an (α + β) microstructure, the volume fraction of the phases is shown to be the main factor that determines the mechanical properties.     

公司大门工程建设施工

大门小品建筑属多项目综合性工程。本文作者从管理者的角度 ,通过对公司大门及附属工程施工质量控制的总结 ,说明了质量控制应贯穿于工程施工的全过程     

On the binomial confidence interval and probabilistic robust control

The Clopper-Pearson confidence interval has ever been documented as an exact approach in some statistics literature. More recently, such approach of interval estimation has been introduced to probabilistic control theory and has been referred as non-conservative in control community. In this note, we clarify the fact that the so-called exact approach is actually conservative. In particular, we derive analytic results demonstrating the extent of conservatism in the context of probabilistic robustness analysis. This investigation encourages seeking better methods of confidence interval construction for robust control purpose.