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Haijun Tan Chunyue Pan Gang Wang Yingying Wu Yiping Zhang Yingping Zou Guipeng Yu Min Zhang 《Organic Electronics》2013,14(11):2795-2801
A series of organic dyes (POZ-2, POZ-3, POZ-4 and POZ-5) involving phenoxazine were synthesized as sensitizers for application in dye-sensitized solar cells (DSSCs). For comparison, three different electron donors namely 10-phenyl-10H-phe-nothiazine, 10-phenyl-10H-phenoxazine and triphenylamine were separately appended onto the 7-position of the model dye (POZ-2). The obtained four dyes exhibit considerably high values of conversion efficiencies of 6.6%, 7.8%, 7.1% and 6.4%, respectively, under the simulated AM1.5G conditions. The geometries of the dyes were optimized to gain insight into the molecular structure and electron distribution, and then the charge extraction and transient photovoltage decay measurements were further performed to understand the influence of electron donors on the photovoltaic behaviors. 相似文献
105.
Park G. Huffaker D.L. Zou Z. Shchekin O.B. Deppe D.G. 《Photonics Technology Letters, IEEE》1999,11(3):301-303
Data are presented on the temperature dependence of 1.3-μm wavelength quantum-dot (QD) lasers. A low-threshold current density of 90 A/cm2 is achieved at room temperature using high reflectivity coatings. Despite the low-threshold current density, lasing at the higher temperatures is limited by nonradiative recombination with a rapid increase in threshold current occurring above ~225 K. Our results suggest that very low threshold current density (⩽20 A/cm 2) can be achieved at room temperature from 1.3-μm QD lasers, once nonradiative recombination is eliminated 相似文献
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Sung Hun Wee Yanfei Gao Yuri L. Zuev Karren L. More Jianyong Meng Jianxin Zhong George M. Stocks Amit Goyal 《Advanced functional materials》2013,23(15):1912-1918
Spontaneous self‐assembly of a multication nanophase in another multication matrix phase is a promising bottom‐up approach to fabricate novel, nanocomposite structures for a range of applications. In an effort to understand the mechanisms for such self‐assembly, complimentary experimental and theoretical studies are reported to first understand and then control or guide the self‐assembly of insulating BaZrO3 (BZO) nanodots within REBa2Cu3O7–δ (RE = rare earth elements including Y, REBCO) superconducting films. The strain field developed around BZO nanodots embedded in the REBCO matrix is a key driving force dictating the self‐assembly of BZO nanodots along REBCO c‐axis. The size selection and spatial ordering of BZO self‐assembly are simulated using thermodynamic and kinetic models. The BZO self‐assembly is controllable by tuning the interphase strain field. REBCO superconducting films with BZO defect arrays self‐assembled to align in both vertical (REBCO c‐axis) and horizontal (REBCO ab‐planes) directions result in the maximized pinning and Jc performance for all field angles with smaller angular Jc anisotropy. The work has broad implications for the fabrication of controlled self‐assembled nanostructures for a range of applications via strain‐tuning. 相似文献
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Graphene‐semiconductor nanocomposites, considered as a kind of most promising photocatalysts, have shown remarkable performance and drawn significant attention in the field of photo‐driven chemical conversion using solar energy, due to the unique physicochemical properties of graphene. The photocatalytic enhancement of graphene‐based nanocomposites is caused by the reduction of the recombination of electron‐hole pairs, the extension of the light absorption range, increase of absorption of light intensity, enhancement of surface active sites, and improvement of chemical stability of photocatalysts. Recent progress in the photocatalysis development of graphene‐based nanocomposites is highlighted and evaluated, focusing on the mechanism of graphene‐enhanced photocatalytic activity, the understanding of electron transport, and the applications of graphene‐based photocatalysts on water splitting, degradation or oxidization of organic contaminants, photoreduction of CO2 into renewable fuels, toxic elimination of heavy metal ions, and antibacterial applications. 相似文献
109.
为了实现半导体激光器的单侧模稳定工作,提出了一种在激光器的脊条两侧引入光子晶体结构滤除半导体激光器高阶侧模的方法。通过调整激光器上表面的刻蚀深度、光子晶体区域的条宽和间隔来改变激光器内部的模场分布,同时结合选择性的载流子注入来增强基模的激射优势,进而减少侧模的数量。实验上制作了主脊条宽度为6 m,光子晶体周期5 m,波长1 550 nm的半导体激光器。测试结果表明:在连续工作的情况下,电流300 mA的时候,高阶侧模受到抑制,水平发散角变为10.2,证实了光子晶体结构调制激光器侧模的可行性。 相似文献
110.
Maijia Liao Jianyong Feng Wenjun Luo Zhiqiang Wang Jiyuan Zhang Zhaosheng Li Tao Yu Zhigang Zou 《Advanced functional materials》2012,22(14):3066-3074
Despite the fact that Ta3N5 absorbs a major fraction of the visible spectrum, the rapid decrease of photocurrent encountered in water photoelectrolysis over time remains a serious hurdle for the practical application of Ta3N5 photoelectrodes. Here, by employing a Co3O4 nanoparticle water oxidation catalyst (WOC) as well as an alkaline electrolyte, the photostability of Ta3N5 electrode is significantly improved. Co3O4/Ta3N5 photoanode exhibits the best durability against photocorrosion to date, when compared with Co(OH)x/Ta3N5 and IrO2/Ta3N5 photoanodes. Specifically, about 75% of the initial stable photocurrent remains after 2 h irradiation at 1.2 V vs. RHE (reversible hydrogen electrode). Meanwhile, a photocurrent density of 3.1 mA cm?2 has been achieved on Co3O4/Ta3N5 photoanode at 1.2 V vs. RHE with backside illumination under 1 sun AM 1.5 G simulated sunlight. The reason for the relatively high stability is discussed on the basis of electron microscopic observations and photoelectrochemical measurements, and the surface nitrogen content is monitored by X‐ray photoelectron spectroscopic analysis. 相似文献