Improved high-rate performance and cycling stability of 1D LiFePO4 nanorods by a facile annealing process

To alleviate the main limitations of lithium ion diffusion rate and poor electronic conductivity for LiFePO4 cathode material, it is desirable to synthesize nano-size LiFePO4 material due to its enhanced electronic and lithium ion transport rates and thus an improved high-rate performance. However, our previous synthesized LiFePO4 nanorods only exhibited low high-rate and slightly unstable cycle performance. Possible reasons are the poor crystallization and Fe2+ oxidation of LiFePO4 nanorods prepared by hydrothermal method. In this paper, LiFePO4 nanorods were simply dealt with at 700 ℃ for 4 h under the protection of Ar and H2 mixture gas. The electrochemical properties of LiFePO4/Li cells were investigated by galvanostatic test and cyclic voltammetry(CV). The experimental results indicated that the annealed LiFePO4 nanorods delivered an excellent cycling stability and obviously improved capacity of 150 mA·h·g-1 at 1C, and even 122 mA·h·g-1 at 5C.     

PLD preparation of GeS6 amorphous film and investigation on its photo-induced darkening phenomenon

GeS6 chalcogenide amorphous fi lm was deposited on glass substrate via PLD（pulsed laser deposition） technique. The performance and structure of the fi lm was characterized by XRD（X-ray diffraction）, SEM（Scanning Electron Microscopy）, EDS（Energy Dispersive Spectroscopy）, optical transmission spectra, and Raman spectra, etc. The GeS6 amorphous fi lm was irradiated by 532 nm linearly polarized light, and its photoinduced darkening was investigated. The results showed that the GeS6 chalcogenide amorphous fi lm was smooth and compact with uniform thickness and combined with the substrate fi rmly, and its chemical composition was in consistency with the bulky target. When laser energy was fi xed, the transparence of the fi lm declined with the increase of the laser irradiation time. Obvious photo-induced darkening and relaxation phenomenon of the fi lm after laser irradiation were observed in this investigation.     

Evaluation of apatite-coated chitosan microspheres for bone regeneration

The apatite-coated chitosan microspheres were fabricated by incubating chitosan in five times simulated body fluid. The apatite deposited on the microspheres was similar to natural bone mineral, as demonstrated by scanning electron microscopy, X-ray diffraction spectra and Fourier transformed-infrared spectroscopy analyses. Rat bone marrow-derived mesenchymal stem cells （BMSCs） were seeded on apatite- coated microspheres to investigate the effect of this scaffold on cell proliferation and differentiation. BMSCs seeded on uncoated microspheres were served as a control. In vivo experiment was evaluated by transplanting the microspheres loaded with or without BMSCs in 5-mm cranial defects of Wistar rats. Bone regeneration was investigated via micro-CT and histological analysis. It was found that apatite-coated chitosan microspheres could significantly promote the proliferation and alkaline phosphatase activity of BMSCs compared with uncoated microspheres. Histological slices and Micro-CT images at 8 weeks revealed much better regeneration of bone in the apatite-coated microspheres loaded with BMSCs than the control. In addition, the defect filled with pure microspheres induced little new bone formation. Our findings suggest that the apatite-coated chitosan microspheres scaffold is a promising carrier of stem cells for cranial bone tissue engineering.     

模块化多电平变换器功率模块的电流与损耗

为了便于对电压源变换器功率器件进行系统设计以及对其参数、冷却装置进行有效选择,需要对电流与损耗进行有效估算.通过介绍新型模块化多电平变换器（MMC）的工作模态,对其电流分布进行了详细分析,给出一种基于电流分布和元件特征曲线线性拟合的简单MMC损耗计算方法,并在此基础上分析了开关频率、功率因数等对MMC损耗的影响.仿真计算结果表明,该方法能简单有效地对不同工况下各个元件的损耗进行计算,其计算结果对功率器件及其散热装置的选择有一定的指导作用.     

边坡工程中抗滑群桩工程特性的数值分析

针对建立抗滑群桩的设计方法问题,分析了抗滑群桩在水平推力作用下的力学行为.以重庆江东边坡的典型断面为例,应用有限元程序CORE3D分析了群桩的桩间颗粒土的土拱区域,结合桩的荷载位移曲线、土拱效应解释了土体应力传递到抗滑桩的规律,通过对影响土拱效应的参数,如桩间距、土体厚度、抗滑桩嵌入深度和桩径等的深入研究,提出了相应的群桩布置参数估算公式.研究成果在重庆江东边坡的防护工程设计中得到了应用,并取得了较好的效果.     

武汉地区结核分枝杆菌链霉素耐药分离株rpsL基因分子特征研究

探讨武汉地区结核分枝杆菌链霉素（SM）耐药临床分离株rpsL基因分子特征。收集71株临床分离株,采用刃天青法测定临床分离株对SM的最低抑菌浓度（MIC）,同时用直接测序法分析rpsL基因的突变情况;用RD105基因缺失检测法鉴定71株临床分离株中＂北京基因型＂菌株。结果显示20株SM敏感株rpsL基因未发现突变（MICs〈0.25 mg/L）;51株SM耐药株中,35株（68.6%）检测到rpsL基因突变,主要发生在第43位和88位密码子,MIC≤1 mg/L的SM耐药株（低水平耐药株）总突变率低于MIC≥2mg/L（高水平耐药株）;北京基因型与耐药株的相关性不大。研究表明SM耐药菌株rpsL基因突变类型存在地域差异;rpsL突变与SM高水平耐药的相关性在本研究中关联度不大;＂北京基因型＂菌株在武汉地区呈流行趋势。     

滑坡作用下输气管道受力分析

以川气东送管道铺设中的管道横穿罗针田滑坡工程为背景,建立管道横穿滑坡情况下的力学模型,并采用静力学解析计算的方法对管道变形、受力状态进行分析研究,获得了滑坡位移、推力与管体的响应特征,如应变或应力的关系,从而为地质灾害安全风险评价及预警提供定量的评价指标。结果表明：该管道横穿滑坡段暂时处于安全状态;管道变形分布曲线呈现正态分布规律,滑坡体正中管道部位变形最大,向两端变形逐渐减小;管道弯矩分布符合两端固定简支梁承受均布荷载弯矩形态,两端应力最大,呈现中部正弯两端负弯态势,管道两端最易发生破坏;研究成果可为类似输油气管道穿越滑坡地质灾害的破坏预警提供理论参考。     

接枝梳型高分子的SCF理论模拟

利用Scheutjens—Fleer自洽场（SF—SCF）理论,对表面接枝梳型高分子的体系进行模拟研究。模拟结果表明,柔性梳型高分子主链的链段密度分布仅与支链的总链段数有关,主链随支链链段数目的增加而伸展。当总链段数一定且主链长度相同时,线性高分子表现出较高的接枝率,比接枝的梳型高分子具有更大的分子伸展程度与更厚的接枝层。对于线性高分子的接枝层,提高链长比提高接枝率能得到更厚的接枝层。     

利他行为的启动因素

结合当前人们的现实表现和社会风气,分析利他行为的启动因素。人格因素包括移情能力、积极体验、责任心等;情境因素包括旁观者效应和应急反应等;文化因素包括传统文化对日常生活的渗透以及“施报观”等独特的社会心理。     

用户体验理论在武汉里分民居环境改善中的应用

住区环境是人类生存最重要的一个空间,里分民居更是武汉历史发展过程中留下的宝贵历史遗产。通过引用用户体验的相关理论,对武汉里分民居的住区环境进行走访调查研究,并从使用者的心理需求出发,提出切实可行的解决方案,认为要实现里分民居住区环境与使用者需求的真正连接,做到里分民居环境的改善,需做到：整改当前混乱境况,保证居民的生理与安全需求;加强人与环境互动,拓展民居住区的交往与休闲空间;充分利用建筑的独特风格,提升民居的艺术与历史价值。