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121.
122.
Luciano Senff Pedro A. Barbetta Wellington L. Repette Dachamir Hotza Helena Paiva Victor M. Ferreira João A. Labrincha 《Construction and Building Materials》2009,23(10):3107-3111
This paper reports the effects of distinct contents of silica fume (SF), superplasticizer (SP) and water/binder ratio (W/B) in mortars. Samples with SF (0–10 wt%), SP (1.0–1.2 wt%) and W/B ratio (0.30–0.35) were produced. Flow table test and rheometry were used as parameters to formulate mortars by means of a factorial design experiment. Setting time, water absorption, apparent porosity and compressive strength of mortars at 28 days were also determined. Mortar formulations with lower fluidity are restricting when a rheometer was used. For higher torques, adjustments with the regressive equation of the Bingham model are less accurate, since the flow behavior is less constant. On the other hand, mortars with higher fluidity it is limited by spread test. The spread value on flow table test is more related to yield stress than to plastic viscosity. The design experiments identified the main factors (SF, SP and W/B) and their interactions for all properties on the fresh and hardened state, showing that experimental design with multiple regression equations is an appropriate tool to be applied in this case. Water content was the controlling parameter for practically all properties studied. 相似文献
123.
The solubility and density of the CO2 + 1-ethyl-3-methylimidazolium ethylsulfate system were investigated. The carbon dioxide solubility in the IL was measured in the temperature range 273–413 K, for pressure up to 5 MPa and CO2 mole fractions ranging from 0.02 to 0.5 using the isochoric method, while the system density was carried out at temperatures ranging from 278.15 K to 398.15 K, pressures from 10 MPa to 120 MPa and 0.2, 0.4, 0.7 and 0.8 CO2 mole fractions. Similar to what was previously observed for phosphonate-based ILs, the ionic liquid high polarity leads to positive deviations from ideality resulting from unfavorable interactions with the CO2.The results from the density and solubility derived properties show that the system presents important negative excess molar volumes, over the whole range of compositions and temperatures, and a negative entropy of solvation that suggests an increase in ordering of the solvent molecules surrounding the solute. The observed negative excess molar volumes result from the large difference between the molecular volumes of the species involved, with the small carbon dioxide molecules occupying the empty spaces between the larger IL ions, supporting the notion that the carbon dioxide, upon dissolution, occupies essentially the bulk free volume since the IL does not significantly expand upon gas absorption. These results portray ionic liquids as a porous media, like a soft sponge, with a huge free volume in which large amounts of carbon dioxide are able to accommodate during the dissolution process. 相似文献
124.
Zeolite-A was synthesized and converted into various ion-exchanged catalytic forms successfully. These catalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer Emmett Teller (BET) surface area measurement and thermal programmed desorption (TPD). Their catalytic activity was tested on the synthesis of benzimidazole using o-phenylenediamine (OPDA) and aldehyde at room temperature. The reaction proceeds efficiently under ambient conditions. The catalysts gave a high isolated yield of benzimidazole in a shorter reaction time at room temperature and were recycled several times. 相似文献
125.
Strain sensors can be embedded in civil engineering infrastructures to perform real-time service life monitoring. Here, the sensing capability of piezoresistive cement-based composites loaded with carbon black (CB) particles is investigated. Several composite mixtures, with a CB filler loading up to 10% of binder mass, were mechanically tested under cyclic uniaxial compression, registering variations in electrical resistance as a function of deformation. The results show a reversible piezoresistive behaviour and a quasi-linear relation between the fractional change in resistivity and the compressive strain, in particular for those compositions with higher amount of CB. Gage factors of 30 and 24 were found for compositions containing 7 and 10% of binder mass, respectively. These findings suggest that the CB-cement composites may be a promising active material to monitor compressive strain in civil infrastructures such as concrete bridges and roadways. 相似文献
126.
Vehicular networking is considered a promising and enabling technology that helps in the realization and diversification of vehicle related applications such as road traffic safety, emergency management, and infotainment. For applications such as the road traffic safety, the system has to respond in certain bounded time and ensure higher reliability. A major bottleneck of the existing architectures is the reliability and scalability that results in a considerable performance degradation. Therefore, in this paper, we proposed a software defined peer to peer (P2P) architecture for reliable vehicular communications solution that scales out overall network intelligence into the system components (Road side units, on-board units, Gateways, Control centre) and offer an unprecedented reliability, adaptability and scalability. The reliability of the communication is achieved by using redundant system components such as multiple switches and GWs links that are deployed to achieve lower communication latencies and higher packet success rates. Furthermore, higher reliability is achieved by the application of fast-failover and fast recovery techniques. The proposed architecture is implemented using Docker, and containerized ONOS and Cassandra. The obtained results show that the proposed architecture offer higher reliability by offering higher packet success rate (PSR) and smaller round trip time (RTT). 相似文献
127.
This paper presents a new method for detecting damage in layered composite materials using a simple measurement technique, deflectometry. The aim is to locate the damage in a specimen and provide a “signature” from the measured surface slopes. Firstly, this method is applied to plate specimens using numerical and experimental data. Secondly, damage indicator based on a new application of the virtual fields method to compute local apparent gaps in equilibrium is presented and used to process the measurements on plates. It is shown that the damage indicator is very sensitive, allowing detection of damage that is difficult to identify directly from the strain maps. 相似文献
128.
129.
Protective Zr(Y)O2−δ-based films sputter-deposited onto apatite-type lanthanum silicate ceramics were appraised for potential applications in solid oxide fuel cells with silicate-based solid electrolytes, where the performance may suffer from surface decomposition processes in reducing atmospheres. Dense and crystalline coatings were deposited using radio-frequency magnetron sputtering from an yttria-stabilized zirconia target. On the basis of microstructural analysis and profile measurements, a sputtering power of 300 W was selected in order to achieve deposition rates in the range 0.50-0.75 μm/h. The surface morphology studies using an atomic force microscope revealed typical film structures with small (<50 nm) grains. The polarization of model electrochemical cells with cermet anodes comprising Ni, yttria-stabilized zirconia and Ce0.8Gd0.2O2−δ (50:30:20 wt.%), deposited onto the protective zirconia films, was found quite similar to that of copper-zirconia cermets without interlayers, suggesting that the electrochemical reaction is essentially governed by the oxygen anion transfer from zirconia phase and/or hydrogen oxidation in the vicinity of zirconia film surface. 相似文献
130.
N. ChihaouiM. Bejar E. Dharhi M.A. ValenteM.P.F. Graça 《Journal of Alloys and Compounds》2011,509(36):8965-8969
In this work, structural and magnetic studies have been investigated to explore the influence of the oxygen-deficiency (δ) on the physical properties of Ca2MnO4−δ (δ = 0 to 0.5) compounds. The samples cationic stoichiometry has been studied using energy dispersive X-ray analysis (EDAX). EDAX spectra, taken from the surface of the synthesized powders, have showed a nominal composition near the desired one. The structural study, by X-ray diffraction analysis, has confirmed the single-phase composition of all samples. The Rietveld refinement technique of the X-ray patterns, has revealed that samples crystallize in the tetragonal system with I41/acd space group for δ = 0 and in the orthorhombic one with Bbcm space group for δ > 0.The applied magnetic field (μ0H) and the temperature (T) dependences of the magnetization (M) have been studied using a vibrating sample magnetometer (VSM). From magnetization measurements versus temperature under the field-cooled (FC) and zero-field-cooled (ZFC) modes, we have deduced the presence of a spin-glass behavior characterized by a distinctive separation of the FC and ZFC curves. This behavior was found to become more important, as increasing the oxygen-deficiency δ, which leads to the appearance of magnetic frustration phenomenon. 相似文献