Reductive acid leaching of manganese dioxide with glucose: Identification of oxidation derivatives of glucose

The oxidation of glucose during the reductive leaching of pure MnO₂ and manganese ore in sulphuric acid at 90 °C MnO₂ was investigated. The aim was to identify the derivatives and the chemical pathway of glucose oxidation. Organic derivatives were monitored by HPLC using an Aminex HPX-78H column and UV detection. Chromatographic patterns of leaching solutions showed that major compound formed was formic acid. Minor quantities of glycolic, glyceric and traces of gluconic acids were identified. Results suggest that during the leaching reaction, the carbon chain of glucose is shortened by detachment of one carbon atom as formic acid.     

The reduction of chromite in the presence of silica flux

The mechanism and kinetics of the carbothermic reduction of a natural chromite was studied at 1300–1500 °C in the presence of silica. Thermogravimetry, X-ray diffraction (XRD) analysis, energy dispersive X-ray analysis (EDAX) and metallography were the experimental techniques used. Silica affected the reduction at and above 1400 °C. A two stage reduction mechanism was established. The first stage, up to about 40% reduction, is primarily limited to iron metallization and zoning is observed in partially reduced chromites. In this stage silica does not interfere with the reduction. The second stage is mainly confined to chromium metallization and formation of a silicate slag alters the reduction mechanism. Ion-exchange reactions between the reducible cations (Cr³⁺ and Fe²⁺) in the spinel and the dissolved cations (A1³⁺ and Mg²⁺) in the slag allow further reduction. Due to the very high driving force for the diffusion, the overall process is shifted toward a more chemical reaction controlled mechanism. A generalized rate equation was then applied to the individual metallization curves of iron and chromium from which respective rate constants and diffusion coefficients were derived. The rate constants were in the range 6.74 × 10⁻⁴–9.01 × 10⁻⁴ s⁻¹ for iron and 7.20 × 10⁻⁴–8.50 × 10⁻⁴ s⁻¹ for chromium reduction at 1500 °C in the presence of silica. At 1500 °C, the corresponding diffusion coefficients were in the range 3.14 × 10⁻⁸–4.78 × 10⁻⁸ m²/s for Fe²⁺ diffusion in the spinel and in the range 1.70 × 10⁻⁸–2.03 × 10⁻⁸ m²/s for the respective diffusion of Cr³⁺. Finally using Arrhenius plots activation energies were derived.     

A computational model for reinforced concrete members confined with fiber reinforced polymer lamina: Implementation and experimental validation

This study presents a computational model to simulate the behavior of confined concrete in column plastic hinge zones. The model describes the distribution of confining stresses within a circular column cross-section and the hysteretic behavior of concrete under passive confinement. Of particular interest is the ability of the model to predict the maximum circumferential strains and thus estimate the limit state of the confining medium rather than relying on empirical limits such as concrete compressive strain or drift ratio. This is performed with fiber-discretized beam column analysis without the computational expenses of a continuum finite element (FE) model. The confined section and material model are implemented in an object-oriented computational platform for structural analysis. New classes are developed and presented for a confined fiber section, a confined concrete material, and associated hysteretic behavior rules. Finally, the results from two experimental programs on columns strengthened using fiber reinforced polymer (FRP) lamina are reproduced using the developed computational model. Comparison of simulation and experiment shows that the computational model can closely match the observed response characteristics and can adequately predict the deformation level leading to FRP rupture.     

Fouling study of silicon oxide pores exposed to tap water

We report on the fouling of Focused Ion Beam (FIB)-fabricated silicon oxide nanopores after exposure to tap water for two weeks. Pore clogging was monitored by Scanning Electron Microscopy (SEM) on both bare silicon oxide and chemically functionalized nanopores. While fouling occurred on hydrophilic silicon oxide pore walls, the hydrophobic nature of alkane chains prevented clogging on the chemically functionalized pore walls. These results have implications for nanopore sensing platform design.     

Optimizing random walk search algorithms in P2P networks

In this paper we develop a model for random walk-based search mechanisms in unstructured P2P networks. This model is used to obtain analytical expressions for the performance metrics of random walk search in terms of the popularity of the resource being searched for and the random walk parameters. We propose an equation-based adaptive search mechanism that uses an estimate of the popularity of a resource in order to choose the parameters of random walk such that a targeted performance level is achieved by the search. We also propose a low-overhead method for maintaining an estimate of popularity that utilizes feedback (or lack there-off) obtained from previous searches. Simulation results show that the performance of the equation-based adaptive search is significantly better than the non-adaptive random walk and other straight-forward adaptive mechanisms.     

Interpretation of the morphology and crystallography of precipitate γ1-Ti4Nb3Al9 in L10-TiAl(Nb)-based intermetallics by invariant line theory

The coherent precipitate γ₁-Ti₄Nb₃Al₉ in the Nb-modified TiAl-based intermetallic compound with a nominal composition of Ti–48 at% Al–10 at% Nb was investigated by transmission electron microscopy. The crystallographic and morphologic characteristics of the precipitating phase have been calculated based on invariant line theory. It is revealed that in the γ-TiAl(Nb)/γ₁-Ti₄Nb₃Al₉ couples, both the morphological and crystallographical characteristics of the precipitate γ₁-Ti₄Nb₃Al₉ could be predicted by the three-dimensional phase transformation invariant line model. The needle direction of [001] at the early stage for coherent precipitate γ₁-Ti₄Nb₃Al₉ and [111] for equilibrium phase γ₁-Ti₄Nb₃Al₉ have both been explained well. The characterization of morphology and crystallography of the precipitate reaction in γ-TiAl/γ₁-Ti₄Nb₃Al₉ system sustain the postulate that precipitates are bounded by unrotated planes (eigenplanes) when three real eigenvalues exist.     

用赤平极射投影法分析节理岩体中巷道的破坏形式

利用赤平极射投影法，分析节理岩体中巷道受节理构造破坏而失稳的条件。认为采取以管缝式锚杆为主的喷、锚、网支护是防止巷道周围岩块塌落的有效措施。     

基于特征选择的集成分类器抗噪性能分析

特征选择有助于增强集成分类器成员间的随机差异性,从而提高泛化精度。研究了随机子空间法（RandomSub-space）和旋转森林法（RotationForest）两种基于特征选择的集成分类器构造算法,分析讨论了两算法特征选择的方式与随机差异程度之间的关系。通过对UCI数据集引入噪声,比较两者在噪声环境下的分类精度。实验结果表明：当噪声增加及特征关联度下降时,基本学习算法及噪声程度对集成效果均有影响,当噪声增强到一定程度后。集成效果和单分类器的性能趋于一致。     

根据客户网络应答的DNS服务器设计与实现

为了解决网络互连带宽"瓶颈"问题,很多单位的WWW服务器或邮件服务器同时申请不同网络的IP。若这些服务器所申请的不同网络IP对应不同的域名,即通过不同域名来区分不同的访问线路,会给用户访问服务器时带来不便。而一种能根据客户源IP地址所归属网络,把同一个域名解析成不同IP地址的DNS服务器的实现,既解决带宽"瓶颈"问题又方便网民。在Windows平台下,设计和实现了具有根据客户所归属网络应答功能的DNS服务器。     

一种分析时序逻辑电路的补充方法

介绍一种分析时序逻辑电路的补充方法,并应用于教学实践中。其特点是原理简单、易于理解、直观方便,相对于传统的分析方法,避免了对次状态方程的分析处理计算,有时比传统方法简便、快捷。通过两个示例展示其优越性。