Facile synthesis of Ti3+ doped Ag/AgITiO2 nanoparticles with efficient visible-light photocatalytic activity

We successfully synthesized novel Ti³⁺ doped TiO₂ and Ti³⁺ doped Ag/AgITiO₂ nanoparticles with efficient visible-light photocatalytic activity for hydrogen production by facile one-step solvothermal method. The as-prepared Ti³⁺ doped TiO₂ nanoparticles displayed excellent visible-light absorption and visible-light driven hydrogen production activity (115.3 μmol g^?1 h^?1), while the commercial TiO₂ had no visible-light response. Moreover, the as-prepared Ti³⁺ doped Ag/AgITiO₂ nanoparticles in this experiment showed highly enhanced visible-light absorption and efficient visible-light driven activity for hydrogen (571.0 μmol g^?1 h^?1), which was 4.95 times as high as that of the as-prepared TiO₂ nanoparticles. And the surface areas of the as-prepared TiO₂ and Ti³⁺ doped Ag/AgITiO₂ catalysts were up to 138.829 m² g^?1 and 102.988 m² g^?1, much higher than that of the commercial TiO₂ (55.516 m² g^?1). Finally, the visible-light photocatalytic mechanism of the Ti³⁺ doped Ag/AgITiO₂ nanoparticles for hydrogen generation was also proposed in detail.     

使用动态矩形窗求最近点对的几何算法

针对几种经典算法的效率问题,提出了一种最近点对求解算法:算法预先找到X、Y坐标轴最大、最小坐标值,将点集按某坐标轴排序,并根据鸽巢原理计算最近点对i间距离的上限,由此上限将整个点集分割成不同的区域,最后在每个区域中通过动态缩小每个点的矩形窗减少了算法的计算次数.通过理论证明和实际验证得出:初始点集有序时算法的时间复杂度为O(n);无序时在一般情况下为O(n),最坏情况下为O(nlogn);算法的时间复杂度和运行时间明显优于经典分治算法和基于底函数的算法.     

钙试剂和温度对农家干酪品质及乳清OD值的影响

研究了直接加入钙试剂凝乳的方法来生产干酪,从而替代了凝乳酶的使用,根据单因素及L4(23)正交试验设计,筛选出了农家干酪的最佳工艺参数,其最佳的工艺条件:CaCl2添加量为1.6%,凝乳温度为75℃时农家干酪的品质最佳。结果表明,用CaCl2直接凝乳生产农家干酪的工艺所得的制品可以用于实际生产。     

上下回流人工湿地预处理微污染水库水的研究

采用上下回流潜流人工湿地对微污染水库水进行预处理试验。根据试验数据,构建了上下回流潜流人工湿地系统CODCr、TN、TP的一级动力学模拟方程。结果表明:在水力负荷为0.4m3/(m2.d)条件下,CODCr、TN、NH3-N、TP的平均去除率均分别达到56.06%、58.97%、55.91%和50.56%。湿地系统夏季处理效果明显好于其他季节。使用周期按20年考虑,日均进水量3.6m3/d,湿地建设成本为2100元,水的处理成本为0.13元/m3,这表明采用人工湿地预处理微污染水库水是经济可行的。     

Study on the influence factors of the photocatalysis degradation of Humic Acid

The effects of Humic Acid (HA) concentration,pH value and aeration on the photocatalysis degradation of HA by the silica gel supported TiO2 were studied.Moreover,the effect of aeration on the generation of hydroxyl radicals are investigated.The experimental results indicated that the hydroxyl radicals are generated during the photocatalysis process.The generation of hydroxyl radicals is increasing linearly with the reaction time,approximately.Moreover,the generation rate of hydroxyl under the condition of aeration is 1.57 times of that under the condition without aeration,which is the main influent factor on the reaction rate.Therefore,the reaction rate constant with and without aeration is 0.012 min-1 and 0.0063 min-1,respectively.The degradation rate decreases when the initial HA concentration increases,which is due to that more TiO2 active sites are occupied by HA when the HA concentration is higher.Moreover,HA can absorb large amount of photons,which can prevent those available photons to arrive at the activate TiO2 particles.The degradation rate decreases when increasing pH value,which is due to that the adsorption of HA on the TiO2 particles is weakened and not benefit for the degradation process of HA.     

自适应变异粒子群优化算法及在新冠肺炎疫情传播预测中的应用

为克服粒子群算法容易陷入局部最优和全局寻优精度不高的缺点,通过对算法的局部寻优和全局寻优的特点进行分析,首先使用正态分布衰减策略改进惯性权重;同时基于算法运行的时间自适应采用不同的基于高斯分布及柯西分布的变异优化策略,解决全局搜索和局部开发能力的不平衡问题,实现了局部寻优和全局寻优的双重优化,满足了提高寻优速度和寻优精...     

碳纳米管-Ti3AlC2/AZ91D复合材料的微观组织及力学性能

采用化学镀铜的方法对增强相碳纳米管(CNTs)和Ti₃AlC₂进行表面改性,热压烧结制备了CNTs-Ti₃AlC₂/AZ91D复合材料,研究了其微观组织和力学性能的变化及增强机制。结果表明:CNTs-Ti₃AlC₂/AZ91D复合材料内部主要物相为CNTs、Ti₃AlC₂、Mg和Al₁₂Mg₁₇,增强相均匀分布在基体内,在增强相与基体的界面处存在U相(MgAlCu),使二者界面结合良好。当增强相CNTs 和Ti₃AlC₂含量分别为1wt%和25wt%时,较镁合金AZ91D,CNTs-Ti₃AlC₂/AZ91D复合材料的弹性模量、拉伸强度、屈服强度和延伸率分别提高了120.30%、25.72%、126.50%和36.84%,弯曲强度和压缩强度分别为337.92 MPa和436.27 MPa。CNTs-Ti₃AlC₂/AZ91D复合材料的断裂方式表现为脆性断裂,其强化机制主要为热配错强化、Orowan强化和细晶强化机制。      

基于下一代互联网的IPv6路由协议研究

IPv6是下一代互联网发展的基石,它解决了IPv4存在的一些问题和不足,同时还在许多方面进行了改进,如路由协议、QoS和支持移动性等,并大大增加了地址空间。RIPng和OSPFv3等协议是基于IPv6的主要路由技术,目前大多数互联网用户使用IPv4协议,深入开展IPv6在下一代互联网的应用研究具有重要意义。     

Controllable ZnO nanostructures evolution via synergistic pulsed laser ablation and hydrothermal methods

We report the morphology-controlled ZnO nanostructures (ZNSs) evolution synthesized via a novel and facile technique at different growth times, where the pulse laser ablation in liquid (PLAL) is creatively combined with hydrothermal (H) method (hereafter called PLAL-H technique). Four types of ZNSs with varying sizes and shapes such as tapers, multipods, flowers, and hollow flowers are produced on Si substrate via PLAL-H technique. Furthermore, multipod- and flower-like ZNSs are grown using direct hydrothermal method to compare them with the one obtained via synergistic effects of PLAL-H method. This catalyst-free fabrication method is not only cost-effective but greatly useful for the rapid production of different quality of ZNSs at low temperature. ZNSs synthesized under prolonged growth time (60 min) exhibited structural deformation. Growth technique and time dependent morphology, structure, composition, and optical properties of these as-grown ZNSs are characterized using FESEM, X-ray diffraction, FTIR, photoluminescence, and UV–vis measurements. Synthesized ZNSs revealed excellent crystallinity and growth process dependent variation in the physical and optical features. The ZNSs growth mechanism is understood. Excellent features of the results demonstrate that this synergized new growth technique may constitute a basis for modifying the morphology, sizes, and optical properties of ZNSs in a controllable manner useful for diverse applications.     

Two Keggin compounds constructed from tri −/tetra-nuclear Cu clusters linked mono copper(II)-substituted phosphomolybdates

Two new compounds based on mono copper(II)-substituted phosphomolybdate, [Cu₄(tea)₆(H₄PMo₁₁CuO₃₉)(PMo₁₂O₄₀)]₂·33H₂O (1) and [Cu₃(tea)₆(H₂O)₂(H₂PMo₁₁CuO₃₉)₂]₂·30H₂O (2) (tea = 2- [1,2,4]triazol-4-yl-ethylamine), have been synthesized under hydrothermal conditions. Compound 1 owns tetra-nuclear clusters [Cu₄(tea)₆], linking a pair mono copper(II)-substituted and saturated Keggin anions to form a 2D structure. Compound 2 contains tri-nuclear clusters [Cu₃(tea)₆], fusing four mono copper(II)-substituted anions to construct a discrete four-membered cycle structure.