Application of ultrasonic waves in activation of microcrystalline cellulose

In this work, microcrystalline cellulose (MCC) was activated with ultrasonic waves. The influences of ultrasonic treatment on the changes of supramolecular structures and morphology structure were studied by WAXS and SEM. The accessibility of the MCC was characterized by water retention value (WRV) and specific surficial area. The influence of ultrasonic treatment on the reactivity of MCC was investigated through the reaction of MCC being oxidized into 2,3‐diadehyde cellulose (DAC) by periodate sodium. The mechanism of the reactivity change of ultrasonically treated MCC was examined. The results showed that the degree of crystallinity of MCC decreased and the degree of polymerization showed little change after treatment with ultrasonic waves. The morphologial variation of the treated MCC was significant when compared with the untreated MCC, which contribute to the improvement of accessibility. The aldehyde content of DAC prepared from ultrasonically treated MCC was improved from 64.19 to 85.00%, indicating that the regioselective oxidation reactivity of MCC was significantly improved. The aldehyde content was found to first increase with time of ultrasonic treatment to a point, and then decrease as time progressed. In addition, the aldehyde content was found to increase with an increase in ultrasonic power. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Study of the effect of ultrasonic treatment on the surface composition and the flotation performance of high-sulfur coal

This paper highlighted the use of X-ray diffraction, scanning electron microscopy and X-ray fluorescence spectroscopy to investigate the changes on the surface composition of high-sulfur coal and pyrite before and after ultrasonic conditioning. The results showed that ultrasonic conditioning resulted in a decrease in the contents of iron and sulfur in coal, an increase in the content of element carbon, and an increase in the purity of the coal. Conversely, ultrasonic conditioning led to an increase in the content of iron and sulfur in pyrite, a decrease in the impure content of calcium, and a relative increase in the purity of the pyrite after ultrasonic conditioning. This study verified that on the one hand, ultrasonic conditioning can promote the pyrite separation from the high-sulfur coal, with the separated pyrite taking the form of FeS; on the other hand, it can produce a cleaning effect on the surface of coal and pyrite with the consequent increase both in hydrophobicity of coal and hydrophilicity of pyrite. The paper introduced ultrasonic pre-treatment of the slurry and stepped froth removal tests of high-sulfur coal and the study on the yield, ash and sulfur content of clean coal in different phases. The results gave further evidence of the increases both in the rate and the selectivity of flotation. This study shows that ultrasonic conditioning can enhance the performance of de-sulphurization of high-sulfur coal flotation.     

Facile synthesis of ordered nanocrystalline alumina thin films with tunable mesopore structures

Mesoporous alumina layers have attracted attention for their potential use in ultrafiltration of salts, as a heterogeneous catalyst support, an adsorbent in environmental cleanup, and in petroleum refinement. The ability to control the fast hydrolysis rate of the inorganic precursors using simple and inexpensive routes is important for that potential to be realized. Herein, we introduce a novel and facile route to synthesize mesoporous alumina thin films from the combination of inexpensive and commercially available copolymer with aluminum chloride or nitrate (salts) in an EtOH–surfactant–NH₃ · H₂O–salts (EsNs) system through the evaporation-induced self-assembly (EISA) method. Mesoporous alumina layers obtained utilizing the EsNs system have ordered and tunable pore structures. The ability to easily control the mesophases of the alumina layers within a short time provides distinct advantages over previously reported synthesis procedures. Most importantly, we demonstrate that the binding of surfactant and NH₃ · H₂O for the formation of hydrogen bond between them in the EsNs system controls the fast hydrolysis rate of the inorganic species. This allows for the synthesis of nanocrystalline alumina layers via the aluminum oxo-clusters’ assembly with the surfactant. Such simple route may be applied in the synthesis of other non-silica mesostructured oxides.     

地面驱动螺杆泵恒液面控制方法

恒液面控制有利于提高泵效,降低抽油杆柱和泵等设备的失效率。为此结合地面控制装置,研究了一种控制方法和软件。该软件根据控制装置实时测量的转速、扭矩等参数并结合地层开采能力、杆泵型号等参数,分析计算出液面高度和控制范围,并计算出转速改变量,由控制装置实行闭环控制。经大庆油田5口井试验表明,液面高度误差均在50 m内,实现了螺杆泵恒液面控制目的。     

高炉冲渣水在采暖工程中的应用

随着我国经济的迅速发展,能源消耗不断增加,节约能源、降低能源消耗势在必行,余热利用是节约能源的一个重要环节,冶金行业高炉冲渣水作为采暖热媒可以节约大量能源。     

Distributed multi-join query processing in data grids

Query processing in data grids is a difficult issue due to the heterogeneous, unpredictable and volatile behaviors of the grid resources. Applying join operations on remote relations in data grids is a unique and interesting problem. However, to the best of our knowledge, little is done to date on multi-join query processing in data grids. An approach for processing multi-join queries is proposed in this paper. Firstly, a relation-reduction algorithm for reducing the sizes of operand relations is presented in order to minimize data transmission cost among grid nodes. Then, a method for scheduling computer nodes in data grids is devised to parallel process multi-join queries. Thirdly, an innovative method is developed to efficiently execute join operations in a pipeline fashion. Finally, a complete algorithm for processing multi-join queries is given. Analytical and experimental results show the effectiveness and efficiency of the proposed approach.     

三种驱油剂在聚驱后二维非均质物理模型上的驱油效果

在模拟大庆油田条件下，在3种K值的二维纵向非均质人造岩心上，在45℃考察了水驱、1．0g／L普浓聚合物驱之后，3种聚驱后驱油剂的驱油效果。所用聚合物为M=2．5×10^7，HI）=26．5％的耶AM。这3种驱油剂的组成（g／L）为：12／5／1．4的Na2CO3／烷基苯石油磺酸盐／HPAM溶液（ASP）；加入17．5mg／L Cr^3＋的ASP（铬交联ASP）；2．5g／L高浓耶AM溶液。两种ASP体系与原油间界面张力在10^-4mN／m量级。随岩心K值增大，水驱采收率大幅度降低，普浓聚驱采收率增值显著升高，聚驱后驱油荆的采收率增值与岩心坛值和驱油剂类型有关。高浓聚合物、ASP、铬交联ASP的采收率增值。在K=0．50岩心上分别为7．7％、10．6％、12．1％，在坛=0．65岩心上分别为7．8％、12．3％、22．5％，在K=0．72岩心上分别为10．3％、9．8％、11．2％。铬交联ASP注入压力升幅大，后续注水压力维持高值；高浓聚合物溶液注入压力升幅较大或很大，但后续注水压力迅速下降；ASP注入压力升幅最小，后续注水压力不断下降。因此，聚驱后采用洗油效率特别是扩大波及体积能力更强的驱油剂，可以进一步提高采收率。图3表4参9。     

SVPWM三相电压型逆变器的仿真研究

以三相电压型逆变器为基础,根据空间矢量脉宽调制（SVPWM）基本原理详细分析研究了电压矢量作用时间和扇区分配问题,以α-β坐标为基础,建立了互差π/3的x-y-z时间坐标系,提出了不同扇区矢量作用时间长短根据期望极值判断的原则。介绍了MATLAB中M文件编程的仿真方法,建立了MATLAB程序嵌入式主要功能模块,逆变器采用数字PID控制,利用Simulink对系统进行了综合仿真分析及试验,给出了仿真及实验波形,为实现SVPWM逆变器的数字控制提供参考。     

基于像素拓展的图形分割与合成的方法研究

提出了一种新的图像分割与合成方法。对于图像的分割,提出了新的分割算法,先是手工将一些明显属于物体和明显属于背景的像素分割出来,然后创建一个小矩形区域进行像素拓展迭代,迭代到图像边界为止。对于图像的合成,采用平均法,设计了新的算法,使物体的基本颜色保持不变的同时,降低了合成图像中从源图像分割的物体与新背景的差异,并使得其饱和度、色度、强度更加自然真实。     

虚拟红外成像器件的模拟输出电路设计

虚拟红外成像器件是能输出红外图像数据源的器件,在调试图像采集系统的硬件和软件时能替代非制冷红外焦平面阵列。虚拟成像器件的输出具有很好的线性度和精度,可作为图像采集电路的标定器件。文设计了虚拟红外成像器件的模拟输出电路,根据UL03401性能参数,设计了信号调理电路,通过在FPGA上使用ROM中查表方式校正模拟端口输出误差,在实际应用中表现了良好的精确性。