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排序方式: 共有420条查询结果,搜索用时 31 毫秒
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Jingwen Li Yezhou Hu Xiao Huang Ye Zhu Deli Wang 《Small (Weinheim an der Bergstrasse, Germany)》2023,19(20):2206533
Seawater electrolysis is promising for green hydrogen production but hindered by the sluggish reaction kinetics of both cathode and anode, as well as the detrimental chlorine chemistry environment. Herein, a self-supported bimetallic phosphide heterostructure electrode strongly coupled with an ultrathin carbon layer on Fe foam (C@CoP-FeP/FF) is constructed. When used as an electrode for the hydrogen and oxygen evolution reactions (HER/OER) in simulated seawater, the C@CoP-FeP/FF electrode shows overpotentials of 192 mV and 297 mV at 100 mA cm−2, respectively. Moreover, the C@CoP-FeP/FF electrode enables the overall simulated seawater splitting at the cell voltage of 1.73 V to achieve 100 mA cm−2, and operate stably during 100 h. The superior overall water and seawater splitting properties can be ascribed to the integrated architecture of CoP-FeP heterostructure, strongly coupled carbon protective layer, and self-supported porous current collector. The unique composites can not only provide enriched active sites, ensure prominent intrinsic activity, but also accelerate the electron transfer and mass diffusion. This work confirms the feasibility of an integration strategy for the manufacturing of a promising bifunctional electrode for water and seawater splitting. 相似文献
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柴油机气缸内辐射传热模型研究历程与展望 总被引:3,自引:0,他引:3
综述了国内外内燃机气缸内辐射理论研究的进展,阐述了目前研究的难点和关键总是指出作为气缸内传热的一种重要途径,气缸内辐射传热的研究工作需要进一步深入和加强。 相似文献
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该研究旨在探讨紫菜联合美多芭的抗帕金森(Parkinson’s Disease,PD)作用及其对肠道菌群的影响。以48只C57BL/6J小鼠为研究对象,随机分为4组:正常对照组、帕金森模型组、美多芭治疗组和紫菜联合美多芭治疗组。以添加5%(m/m)紫菜的饲料对PD小鼠干预2周后,进行行为学测试、免疫组化分析、免疫印迹分析、炎症因子测定;利用Illumina平台对小鼠肠道细菌的DNA片段进行双端测序。结果表明,相较于单独使用美多芭,紫菜联合美多芭治疗可以显著改善PD小鼠的脑功能,其中黑质中神经元的数量、酪氨酸羟化酶(TH)的表达量分别增加了46.95%、52.91%,α-突触核蛋白(α-syn)的表达量减少了34.56%;显著降低了IL-1β的含量,改善其炎症水平。16S rRNA结果表明,紫菜联合美多芭治疗组小鼠肠道菌群的丰富度提升、多样性增加;Firmicutes/ Bacteroidota的比值降低了71.59%;与抗炎水平相关的Muribaculaceae、Akkermansia菌属显著富集,而Blautia、Helicobacter等炎症相关菌属相对丰度明显下降。相较于单独服用美多芭,紫菜联合治疗后,其调节肠道菌群、减轻炎症的效果更佳,抗帕金森作用更显著。 相似文献
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Cheng Ding Xinxin Lu Bo Tao Liuqing Yang Xiaoyong Xu Lanqin Tang Haoqiang Chi Yong Yang Debora Motta Meira Lu Wang Xi Zhu Si Li Yong Zhou Zhigang Zou 《Advanced functional materials》2023,33(35):2302824
Simultaneous optimization on bulk photogenerated-carrier separation and surface atomic arrangement of catalyst is crucial for reactivity of CO2 photo-reduction. Rare studies capture the detail that, better than in-plane regulation, interlayer-spacing regulation may significantly influence the carrier transport of the bulk-catalyst thereby affecting its CO2 photo-reduction in g-C3N4. Herein, through a single atom-assisted thermal-polymerization process, single-atom In-bonded N-atom (Inδ+–N4) in the (002) crystal planes of g-C3N4 is originally constructed. This Inδ+–N4 reduces the (002) interplanar spacing of g-C3N4 by electrostatic adsorption, which significantly enhances the separation of bulk carriers and greatly promotes the reactivity of CO2 photoreduction. The CO2 photo-conversion performance of this resulted single-atom In modified g-C3N4 is significantly superior to other single atom loaded carbon nitride catalysts. Moreover, the Inδ+–N4 enhances the CO2 adsorption on g-C3N4, reduces the *COOH formation energy, and optimizes the reaction path. It achieves a remarkable 398.87 µmol g−1 h−1 yield rate, 0.21% apparent quantum efficiency, and nearly 100% selectivity for CO without any cocatalyst or sacrificial agent. Through d(002) modulation of carbon nitride by single In atom, this study provides a ground-breaking insight for reactivity enhancement from a double-gain view of bulk structural control and surface atomic arrangement for CO2-reduction photocatalysts. 相似文献
419.
Hai Dong Huang Zhu Qian Li Mi Zhou Xiancheng Ren Tian Ma Junzhi Liu Zhiyuan Zeng Xianglin Luo Shuang Li Chong Cheng 《Advanced functional materials》2023,33(22):2300294
Noble metal-based electrocatalysts (NMECs), particularly those with active sites at the nano or atomic level, are indispensable in heterogeneous catalysis, which has attracted considerable research interests, especially in the energy communities. Due to the enormous inherent merits, such as ultrahigh surface area, tunable atomic structure, and diverse chemical tailorability, metal-organic frameworks (MOFs) have been proposed as ideal candidates for creating efficient and programmable NMECs. In this review, from an interdisciplinary opinion,the recent progresses on the synthetic principles and catalytic site design protocols for the atomically structured MOFs and their derivatives are comprehensively discussed. Particularly, it is dedicated to summarizing the modulation strategies on creating the catalytic centers and bond microenvironments of MOFs-based NMECs, including the single-atom, dual-atom, cluster, and nanoparticle engineering. Furthermore, the critical mechanisms of how the structures of MOFs-based NMECs affect the corresponding electrochemical behaviors is outlined and disclose the critical essences for their future applications. Finally, the current developments, challenges, and perspectives for engineering the atomically structured MOFs-based NMECs are discussed to inspire the broad utilization of MOFs-based NMECs-equipped catalysts in energy conversion, which offers cutting-edge guidance for future prosperity in developing efficient NMECs. 相似文献
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省区经济作为中国经济系统中的一个子系统,其波动是中国经济波动的大背景下发生的。没有充分发了解中国经济波动的成因机理,将很难透彻底释省区的经济波动问题。分析了中国经济波动机理,在此基础上,利用模糊数学聚类分析模型对黑龙江省近十几年来的经济波动进行聚类,结合该省具体的方针、政策分析波动成因,总结以往经验,认为1994年省委七届三中全会提出的全省经济发展总体思路是行之有效的,根据1998年以来经济形势的 相似文献