HPLC法测定L-丙氨酸甲酯盐酸盐中L-丙氨酸含量

建立了HPLC法分离测定L-丙氨酸甲酯盐酸盐中L-丙氨酸含量。色谱条件为:Shim-packVP-ODS柱(150mm×4.6mm,5μm);流动相为甲醇-NaH2PO4水溶液,NaH2PO4溶液浓度为0.05mol·L-1、pH值为6.50(H3PO4调节),甲醇与NaH2PO4溶液体积比为1∶9;流速0.80mL·min-1;柱温为30℃;检测波长为210nm;进样量5μL。该方法的建立为L-丙氨酸甲酯盐酸盐的测定提供了新方法。     

Development of niobiumtin conductors at SLE

Superconductors Lips ECN is a recently formed company which produces NbTi and Nb₃Sn multifilament wires as well as superconducting cables. Multifilamentary Nb₃Sn wire, produced by the powder route, is developed commercially. About 30 km of strand material has been produced for the SULTAN 12 T project. These wires showed good performance. Developments are underway to reduce gradually the filament diameter at the same current performance to meet the full requirements for the NET and LHC conductors.     

Comments on “Electron microscopic analysis of composite precipitates in an Al-2.21 WT%Li-0.14WT%Zr alloy”

In summary, the image analysis technique of SKKT has clarified the very significant effects of dynamical scattering on the appearance of “composite” precipitates. However, the calculations presented by SKKT have no direct relationship to our studies, studies where conclusions, which remain valid, have been drawn about the Li content of α′. Further, no analytical results from the literature have proved the absence of Li in α′ and several studies substantially support our results showing significant Li in the α′ phase.     

无机及分析化学课程教学改革与实践

结合无机及分析化学课程的内容和特点,介绍了无机及分析化学课程教学改革的一些新举措,取得了良好的效果。主要研究内容和成果有:优化教学内容,选择合适的教材,合理安排教学进度;改进课堂教学方法和手段,将传统教学方式与多媒体教学相结合;理论与实验教学相结合,加深学生对理论知识的理解,培养学生的研究能力和创新意识。     

Synthesis of oxygen deficient BiOI for photocatalytic degradation of methyl orange

Oxygen defects are introduced into BiOI by a simple glycerol treatment. This deficient BiOI demonstrated 3.5 times higher photocatalytic performance than the untreated BiOI nanosheets for methyl orange (MO) degradation under visible light irradiation. Moreover, the deficient BiOI nanosheets have excellent cycling stability. The improved efficiency can be ascribed to the significantly enhanced separation efficiency of photogenerated and utilized more solar light.     

An advanced GA–VNS combination for multicriteria route planning in public transit networks

Nowadays, passengers in urban public transport systems do not only seek a short-time travel, but they also ask for optimizing other criteria such as cost and effort. Therefore, an efficient routing system should incorporate a multiobjective analysis into its search process. Several algorithms have been proposed to optimally compute the set of nondominated journeys while going from one place to another such as the generalization of the algorithm of Dijkstra. However, such approaches become less performant or even inapplicable when the size of the network becomes very large or when the number of criteria considered is very important. Therefore, we propose in this paper an advanced heuristic approach whereby a Genetic Algorithm (GA) is combined with a Variable Neighborhood Search (VNS) to solve the Multicriteria Shortest Path Problem (MSPP) in multimodal networks. As transportation modes, we focus on railway, bus, tram and pedestrian. As optimization criteria, we consider travel time, monetary cost, number of transfers and the total walking time. The proposed approach is compared with the exact algorithm of Dijkstra, as well as, with a standard GA and a pure VNS. Experimental results have been assessed by solving real life itinerary problems defined on the transport network of the city of Paris and its suburbs. Results indicate that the proposed combination GA–VNS represents the best approach in terms of computational time and solutions quality for a real world routing system.     

A multi-objective evolutionary algorithm guided by directed search for dynamic scheduling

This paper considers dynamic multi-objective machine scheduling problems in response to continuous arrival of new jobs, under the assumption that jobs can be rejected and job processing time is controllable. The operational cost and the cost of deviation from the baseline schedule need to be optimized simultaneously. To solve these dynamic scheduling problems, a directed search strategy (DSS) is introduced into the elitist non-dominated sorting genetic algorithm (NSGA-II) to enhance its capability of tracking changing optimums while maintaining fast convergence. The DSS consists of a population re-initialization mechanism (PRM) to be adopted upon the arrival of new jobs and an offspring generation mechanism (OGM) during evolutionary optimization. PRM re-initializes the population by repairing the non-dominated solutions obtained before the disturbances occur, modifying randomly generated solutions according to the structural properties, as well as randomly generating solutions. OGM generates offspring individuals by fine-tuning a few randomly selected individuals in the parent population, employing intermediate crossover in combination with Gaussian mutations to generate offspring, and using intermediate crossover together with a differential evolution based mutation operator. Both PRM and OGM aim to strike a good balance between exploration and exploitation in solving the dynamic multi-objective scheduling problem. Comparative studies are performed on a variety of problem instances of different sizes and with different changing dynamics. Experimental results demonstrate that the proposed DSS is effective in handling the dynamic scheduling problems under investigation.     

Implementation of generic algorithm in map-matching model

This paper proposed a novelty map-matching method based on multi-criteria genetic algorithm. In addition, the new ideas are introduced, such as incorporation of dynamic time wrapping method and dynamic programming technique. Dynamic time wrapping is used to evaluate the geometric similarity between recorded trajectory and observed route, while dynamic programming is used to accelerate the calculations of fitness functions in genetic algorithm. Model is tested on real data collected from the street network, which yielded good results with regard to accuracy and running time. Furthermore, it is shown that proposed model is capable to process the GPS data, recorded on dense street network with negligible amount of errors, which is the most challenging task for majority of map-matching algorithms. Therefore, the main impact of this research is observed through the development of better and more precise global map-matching algorithm. This is really important for expert and intelligent transport systems, which are based on input data collected by floating car data systems. This type of system relies on high quality post-processing map-matching model, which should provide accurate results in order to ensure that intelligent transport system makes more precise estimations and predictions of traffic conditions.     

Non-linear PEG-based thermoresponsive polymer systems

Poly(ethylene glycol) (PEG) is one of the most used polymers in medical and biological applications. Its non-toxicity, non-immunogenicity, biocompatibility and solubility in a wide range of solvents offer various possibilities of utilization and explain the amount of studies dealing with this polymer. More recently, non-linear PEG-based monomers attracted much interest due to their thermal behavior. The present review aims at presenting many PEG-based thermoresponsive systems from structural and synthesis point of view and at highlighting all their fascinating properties from their behavior in solution, the fine-tuning of the transition temperature until the formation of smart materials.     

Monomeric complexes of Re(CO)3+ ion with tridentate N∩N∩O−ligands — Schiff base derivatives of salicylic aldehyde

Simple synthetic procedures, reactions of Re(CO)₅Cl with potentially tridentate N∩N∩OH ligands (Schiff bases prepared from aliphatic or aromatic amines and salicylic aldehyde) lead to formation of monomeric complexes of fac-Re(CO)₃⁺ ion. Three obtained complexes have been characterized by means of elemental analyses and IR, UV–vis, and EI-MS techniques. Molecular structures of the synthesized species were investigated using X-ray diffraction measurements. Depending on the nature of N∩N∩OH ligand the investigated Schiff bases form with fac-Re(CO)₃⁺ ion bidentate or tridentate chelates with N∩N, N∩O⁻ or N∩N∩O⁻ coordination types.