Magnesium Ion Doping and Micro-Structural Engineering Assist NH4V4O10 as a High-Performance Aqueous Zinc Ion Battery Cathode

Layered ammonium vanadate materials exhibit significant mass-specific capacity and ion transport rate due to their small molecular weight and large ionic radius. However, the strong electrostatic interactions of Zn²⁺ and V–O bonds and the fragile ionic bonding of N-H^…O bonds hinder their development. Therefore, this work reports Mg²⁺ doping NH₄V₄O₁₀ materials accompanied by flower-like morphology to lower the migration energy barrier and inhibit amine dissolution. Owing to the 3D-flower-like morphology and the combined impact of Mg²⁺ and structural water, the binding of Zn^2+…V-O is significantly enhanced and additional ion channels were constructed. Pre-intercalated Mg²⁺ enhances the structural integrity and prevents irreversible deammoniation from obtaining excellent cyclic stability. Density functional theory (DFT) calculations show that MNVO provides a smoother Zn²⁺ diffusion path with a lower migration barrier. Benefited from these advantages, the MNVO cathode exhibits a high specific capacity of 410 mAh g⁻¹ at 0.1 A g⁻¹, satisfactory cyclic stability (90.2 % capacity retention at 10 A g⁻¹ after 5000 cycles), and capable rate ability (118 mAh g⁻¹ at 25 A g⁻¹) within 0.4-1.5 V. Furthermore, the zinc ion storage mechanism in the MNVO cathode is investigated through multiple analyses.     

“生物医学传感器与测量”课程教学改革探索

＂生物医学传感器与测量＂是生物医学工程专业的一门重要专业课。本文针对专业培养目标和课程教学特点,提出兴趣引导,自主学习,实践探索的指导思想,对教学内容和教学方法进行了一系列改革。根据学生的反馈信息,显示改革后获得良好的教学效果,取得了一些有益的探索和尝试。     

Microstructure evolution and corrosion resistance in simulated CGHAZ of X80 high-deformability pipeline steel

In this study, the microstructure evolution and corrosion resistance in 0.5M Na₂CO₃-1 M NaHCO₃ solution of X80 high-deformability (X80HD) pipeline steel coarse-grained heat-affected zone (CGHAZ) with several heat input levels were investigated. It is shown that the microstructure of CGHAZ changes from bainite ferrite to granular bainite as the heat input increasing. In addition, the corrosion resistance and the stability of passive film of base material are better than those of CGHAZ with several heat input levels. Too small or too big heat input is inadvisable and better corrosion resistance of CGHAZ is attained when heat input is 30kJ/cm.     

An FBG impact location system based on broadband light source and improved TDoA algorithm

When a structure material is damaged by impact events, the reliability and lifetime of the material will be severely affected. So impact location is considered as the prime approach for structural health and damage monitoring. In this study, a novel fiber Bragg grating (FBG) impact location system based on broadband light source is designed, aiming at the shortcoming of existing location systems based on FBG. An improved localization algorithm based on the time difference of arrival (TDoA) is proposed for impact location. According to this algorithm, the impact position can be accurately predicted without wave velocity. Impact planar location experiments are carried out for verification of the FBG impact location system and algorithm on a400 mm×400 mm×3 mm aluminum alloy plate. The resulted locating error shows high precision and good stability of the proposed system. This work has been supported by the National Natural Science Foundation of China (Nos.61503218, 61403233, 61573226 and 61473176), the Excellent Young and Middle-Aged Scientist Award Grant of Shandong Province of China (No.BS2013DX018), and the Natural Science Foundation of Shandong Province for Outstanding Young Talents (No.ZR2015JL021). E-mail:pangdan@163.com      

一种基于激光诱导荧光法的心肌钙蛋白Ⅰ检测系统

基于激光诱导荧光的测量原理,研制了一种用于心肌钙蛋白Ⅰ(cTnⅠ)快速检测的便携式系统。首先在测试杯中cTnⅠ与荧光试剂发生免疫反应,经过分离除去多余的荧光试剂,测试杯中的荧光分子与cTnI的量成相关性,通过对荧光分子进行诱导激发,使其发出荧光信号,然后经过光电转换、微弱电信号放大、信号采集与处理,最终实现对cTnⅠ的快速定量检测。临床实验显示,在cTnT为1.5~12.2 ng/mL范围内,本系统与TosohAIA-360生化分析仪的检测结果具有很好的线性关系,样品数为6时两者的相关系数达到0.97。     

Analytical impulse response of a fractional second order filter and its impulse response invariant discretization

In this paper, we derive the impulse response of a fractional second order filter of the form (s²+as+b)^−γ, where a,b?0 and γ>0. The asymptotic properties of the impulse responses are obtained. Moreover, based on the derived analytical impulse response, we show how to perform the discretization of the above fractional second order filter. Finally, a number of illustrated examples in time and frequency domains are provided as proofs of concepts.     

基于双LPFG解调的高灵敏度振动检测系统

基于边缘滤波解调原理,提出了一种利用双长周期光纤光栅（LPFG）解调光纤布拉格光栅（FBG）振动传感信号的新方法。利用传输光谱叠加后的双LPFG作为边缘滤波器,增大了FBG传感信号解调灵敏度。静态实验结果表明,利用单、双LPFG作为滤波器解调的灵敏度分别为-1．1965dB／nm和-2．4836dB／nm,双LPFG解...     

基于单片机的多功能智能钟的设计

本文给出了一种多功能智能钟的设计，详细介绍了硬件设计和软件的设计，实验结果表明：这种多功能智能钟系统可靠性高，体积小，成本低，功能强，有着良好的人机对话功能，易于推广，有着很好的应用前景。     

电力系统远动传输规约实验软件的设计

本文介绍了一种用于电力系统远动传输规约教学实验的软件系统。该系统利用Visual C++编写完成,模拟了主站和分站之间利用循环式、问答式传输规约进行数据传输的过程,学生可通过上机操作学习不同规约中数据帧(报文)的生成与传输过程,有效改善了专业课的教学效果。     

超声行波微流体驱动模型的耦合分析

介绍了带有微沟道的超声行波微流体驱动的圆环模型。在对模型结构部分进行模态分析和瞬态动力学分析的基础上,基于有限元分析,针对耦合模型作声固耦合分析,分别得到与空气和水耦合时模型的固有频率;进行耦合场的流固耦合分析,采用瞬态动力学方法,得到沟道内流体在超声行波激励下的流场情况。比较不同时间子步时流体域和固体域的位移云图,得到流体随固体振动情况;分析不同时间子步时流体域的速度矢量图,得到流体在超声行波方向上的流动情况,验证了超声行波微流体驱动的可行性。