Curing performance and print accuracy of oxidized SiC ceramic via vat photopolymerization

To improve the print quality of SiC ceramic, an amorphous SiO₂ layer is prepared on the surface of SiC by oxidation (SiC@SiO₂). The changes in curing depth and width direction of SiC@SiO₂ curing sheets with different degrees of oxidation were investigated. The results showed that curing depth increased while curing width decreased with an increasing degree of oxidation. The edge morphologies of SiC@SiO₂ curing sheets changed from serration to flat shape with increasing degree of oxidation, and uneven overcuring regions appear in the width direction. Additionally, 12% SiC@SiO₂ ceramic was fabricated via vat photopolymerization combined with reaction sintering. The dimensional deviation ratio of printed green bodies increased with decreasing printed line width and pore diameter. The minimum printed line width of 329 μm and pore diameter of 483 μm with good print quality were obtained. Furthermore, the flexural strength of 225.4 MPa and bulk density of 2.77 g cm⁻³ for sintered 12% SiC@SiO₂ parts were obtained.     

Boosting the antimicrobial and Azo dye mineralization activities of ZnO ceramics by enhancing the light-harvesting and charge transport properties

Herein, we report the wet-chemical synthesis of a ferromagnetic nickel-doped ZnO (Zn_1-xNi_xO) nanocatalyst as a novel and visible-light-driven photocatalyst. Through X-ray diffraction, UV/Vis absorption, electronic studies, and current-voltage experiments, the effect of the ferromagnetic nickel dopant on the structural, optical, morphological, and electrical properties of the synthesized Zn_1-xNi_xO nanocatalyst was studied. The Ni-doping introduced the structural variation in the Zn_1-xNi_xO nanocatalyst, exhibiting a visible light-triggered optical band gap of 2.96 eV and an excellent current conductivity of 6.3 × 10⁻⁴ Sm⁻¹. Moreover, the synthesis of the Zn_1-xNi_xO catalyst at the nanoscale enhanced its surface energy, showing a robust affinity to stick with the dye and pathogenic microbes. The synergistic effects of all the mentioned features enable our Zn_1-xNi_xO nanocatalyst to efficiently generate and transport reactive oxygen species (ROS) under visible light illumination. Regarding antibacterial action, the as-synthesized Zn_1-xNi_xO nanocatalyst showed 1.7% higher activity against E. coli than that of the drug Ciprofloxacin. In addition, doped nanocatalysts mineralize almost 97% of the Allura red dye in just 80 min with a constant rate value of 0.036 min⁻¹. The impedance study and post-application XRD proposed that our Zn_1-xNi_xO nanocatalyst has good conductivity and structural stability. Applications studies show the unusual photocatalytic activity of as-synthesized Zn_1-xNi_xO nanocatalysts, which makes it a suitable candidate for industrial discharge treatment applications at the expense of solar light.     

Determinations of Ce solid solution mechanism and limit thermal conductivity of YTaO4 ceramics

x mol% CeO₂-YTaO₄ (x = 0, 3, 6, 9, 12) ceramics have been synthesized by the spark plasma sintering (SPS) technique. We focus on the changes in lattice distortion, bonding length, thermal conductivity, thermal expansion, and phase stability of the prepared samples. XRD, Raman, and XPS are used to determine the chemical valence and solid solution mechanism of Ce in the lattice of YTaO₄, while its effects on thermal/mechanical properties are elucidated from microstructures. Y³⁺ is substituted via Ce³⁺, and all samples maintain a monoclinic phase. The limit thermal conductivity (1.2 W?m^?1?K^?1, 900 °C) is realized in 9 mol% CeO₂-YTaO₄, and the thermal expansion coefficients are increased to 10.2 × 10^?6 K^?1 at 1200 °C. Furthermore, the exceptional phase stability and mechanical properties of all samples indicate that they can provide good thermal insulation at high temperatures, and have higher working temperatures than the current YSZ thermal barrier coatings.     

Raman spectra,bond characteristics,and microwave dielectric properties of Gd2Mo3O12 ceramics

Gd₂Mo₃O₁₂ ceramics were prepared using the traditional solid-phase reaction method. All samples were found to possess an orthorhombic crystal structure with a space group of Pba2, as revealed by refined XRD results. The ceramic sintered at 1000 °C exhibited a high relative density of 96.95 % and superior microwave dielectric properties, including ε_r of 9.42 ± 0.05,  × f of 49258 ± 1200 GHz, and τ_f of −71.8 ± 0.7 ppm/°C. The results suggest a correlation between an increase in ε_r and higher relative density, and a more compact and uniform microstructure can lead to higher  × f value. Chemical bonding theories and Raman spectroscopy analysis reveal that Mo-O bonds, rather than Gd-O bonds, dominate the microwave dielectric properties. Furthermore, the ε_r of Gd₂Mo₃O₁₂ ceramic was closely related to bond ionicity, while  × f and τ_f were mainly determined by lattice energy and bond energy, respectively.     

氟化铝生产副产物-硅渣酸化过程及其动力学

为解决实际生产中氟化铝生产残渣(简称硅渣)难利用问题,以云南某地硅渣为研究对象,以浓硫酸为酸化浸出介质,以浸出率为指标,以单因素实验为基础,研究了酸化过程中酸用量、反应温度、反应时间的影响。结果表明,最佳酸化条件为：加入理论酸用量(23.66 g) 1.3倍的浓硫酸,反应温度170℃,反应时间90 min,该条件下SiO₂的纯度迅速提升至大于99.00%,Al浸出率大于99%,F浸出率大于97%;该反应为液-固多相反应中的收缩未反应核模型,反应活化能为62.97 kJ/mol,浸出过程由化学反应控制。该方法的提出对硅渣的利用提供了一种新思路,具有反应时间短、耗水少、酸化后有价元素浸出率高的优点。     

大豆多肽的生理功能及在食品工业中应用前景探讨

以大豆分离蛋白为原料经现代生物技术加工研制大豆多肽和大豆多肽的营养生理功能厦加工特性进行综述，并进一步探讨了大豆多肽作为一种新型的食品功能因子在一些食品开发中的应用前景。     

发酵酸化技术对乳饼蛋白质降解及蛋白肽生物活性的影响

通过发酵酸化技术研制发酵型乳饼,以传统的直接酸化技术为对照,通过十二烷基硫酸钠-聚丙烯酰胺凝胶电泳（sodium dodecyl sulfate-polyacrylamide gel electrophoresis,SDS-PAGE）、液相色谱-质谱测定乳饼蛋白质降解情况和游离氨基酸含量,通过用液相色谱-串联质谱鉴定乳饼蛋白肽。并通过测定体外抗氧化活性、α-葡萄糖苷酶抑制率和血管紧张素转换酶（angiotensin-converting enzyme,ACE）抑制率表征乳饼蛋白肽的生物活性。SDS-PAGE结果表明,两种酸化技术均能促进乳饼蛋白质的降解,发酵酸化技术对乳清蛋白的降解程度更高,能促进游离氨基酸的释放。从发酵酸化乳饼中鉴定出潜在的ACE抑制肽23?条、抗氧化肽6?条和降糖肽5?条,而传统的直接酸化乳饼中分别为13、4?条和1?条。发酵酸化技术能显著提升乳饼蛋白肽的α-葡萄糖苷酶抑制活性和ACE抑制活性（P＜0.05）,其中分子质量＜3?kDa超滤组分对二者抑制率的IC50分别为1.250?mg/mL和0.416?mg/mL。发酵酸化技术能促进乳饼蛋白质降解,释放生物活性多肽,同时产生游离氨基酸,提升乳饼的生物学价值。     

脱脂乳热处理对农家干酪品质及其加工的影响

乳制品生产离不开热处理，用于加工的脱脂乳的品质和微生物数量对农家干酪的品质和生产中关键环节的控制都有重要的影响。针对脱脂原料乳经不同热处理后对乳中蛋白质，农家干酪的产率厦加工品质的影响进行了探讨。     

一种基于高频量衰减特性的特高压直流输电线路故障测距方法

直流输电线路故障时,高频故障暂态信号将沿线路向两端传播,线路对故障暂态信号高频分量有衰减作用。研究双极特高压直流输电线路频率特性,得到特高压直流输电线路对高频量有衰减作用,线路越长,衰减作用越剧烈的结论。研究基于高频量衰减特性的特高压直流输电线路单端故障测距原理,推导出故障点距测距装置安装点的距离公式,得到基于高频量衰减特性的特高压直流输电线路单端故障测距原理难以准确实现直流输电点线路故障测距的结论。研究基于高频量衰减特性的特高压直流输电线路双端故障测距原理,推导出故障点距测距装置安装点的距离公式,提出频带衰减概念,推导出基于频带衰减的故障距离计算公式。建立云广特高压直流输电系统实际参数仿真模型,对提出的基于高频量衰减特性的特高压直流输电线路双端故障测距原理进行仿真验证,仿真测距结果有较高的准确度。     

可再生能源配额制实施中的市场力研究

可再生能源配额制(RPS)要求可再生能源在电力生产中占有一定比例,但实施过程中出现的市场力问题会对可再生能源证书(REC)市场和电能市场带来影响。针对RPS实施中的市场力问题,提出了主导企业竞争边缘模型,分析了不同主导企业的市场力对REC价格和上网电价的影响。在不同RPS要求下,通过实证研究得出不同主导企业的市场力对REC价格和上网电价的影响结果,说明REC价格太低将导致长期可再生能源发展的投资不足,REC价格太高也会扭曲投资的激励信号,导致长期发电资源的低效配置。因此,管制机构需要认真监督市场绩效,从而保障在RPS政策体制下可再生能源的健康发展。