光纤传感信号中小波去噪的最优分解尺度确定方法

小波分解尺度选择是小波去噪中的关键,分解尺度 过大或过小,都会直接影响传感信号去噪的质量。本文 通过分析常规的分解尺度选择方法,引用指标融合算法原理从图形和统计两个角度出发选用 信噪比(SNR)、均方 根误差(RMSE)、平滑度r以及信号偏差(BIAS)4项评价指标融合 成一项指标,采用指数函数对融合指标进行拟合,并提出 一种拐点判别公式来准确判定最优分解尺度。然后,采用所提方法,结合改进的阈值和阈值 函数,对实验 信号进行最佳分解尺度寻优,实验验证结果表明,本文方法所确定的最优分解尺度对应的中 心波长反射率与实际值相符,因此能够获得更优的去噪效果。     

Mimic Drug Dosage Modulation for Neuroplasticity Based on Charge-Trap Layered Electronics

The human brain is often likened to an incredibly complex and intricate computer, rather than electrical devices, consisting of billions of neuronal cells connected by synapses. Different brain circuits are responsible for coordinating and performing specific functions. The reward pathway of the synaptic plasticity in the brain is strongly related to the features of both drug addiction and relief. In the current study, a synaptic device based on layered hafnium disulfide (HfS₂) is developed for the first time, to emulate the behavioral mechanisms of drug dosage modulation for neuroplasticity. A strong gate-dependent persistent photocurrent is observed, arising from the modulation of substrate-trapping events. By controlling the polarity of gate voltage, the basic functions of biological synapses are realized under a range of light spiking conditions. Furthermore, under the control of detrapping/trapping events at the HfS₂/SiO₂ interface, positive/negative correlations of the A_n/A₁ index, which significantly reflected the weight change of synaptic plasticity, are realized under the same stimulation conditions for the emulation of the drug-related addition/relief behaviors in the brain. The findings provide a new advance for mimicking human brain plasticity.     

Analysis of alternating current driven electroluminescence in organic light emitting diodes: A comparative study

The alternating current (AC) responses of double-injection and double-insulated organic light-emitting diodes (OLEDs) were investigated and compared. To reveal the electroluminescent (EL) processes in these devices, the AC voltage and frequency dependence of the EL intensity and capacitive current were studied in the time domain with a focus on phase difference analysis. It was found that the voltage-dependent transit time and frequency-dependent carrier distribution were important for the AC-driven performance of the double-injection OLEDs. In contrast, although the double-insulated OLEDs shared some similarities with the double-injection OLEDs, they had some unique characteristics, which were the absence of resistive current and phase shift of EL profiles. It was revealed that the EL in the double-insulated OLEDs was driven by the displacement current generated by the ionization of the doped layers, which, however, formed space charge regions and undermined the EL emission. The space charge redistributed the electric field across the devices after the initiation of EL, making the EL maintain for a limited time interval. This effect was significant under low frequency and high AC voltage. Comparing the phase difference between both devices, it was indicated that the space charge effect was responsible for the observed EL phase shift and the asymmetric EL profiles at low frequency and high AC voltage in the double-insulated OLEDs. The proposed model was also of help to understand the EL saturation phenomena with AC frequency and voltage in those devices.     

Catfish Effect Induced by Anion Sequential Doping for Microwave Absorption

Heteroatom doping engineering is desirable in tuning crystal structures and electrical properties, which is considered an opportunity to further develop microwave absorption materials. However, the competition mechanism and priority among doped atoms have not been revealed, which are insufficient to guide the most reasonable dielectric coupling model and design high-performance absorbers. In this work, based on in situ N and O, ex situ S is introduced through external thermal driving, leading to fierce competition among anions. Specifically, S atoms replace pyrrole N, drive out lattice O, and create O vacancies, bringing more extensive local charge redistribution and stronger electron interaction, thus activating the defect-induced polarization (3–6 times higher than conduction loss) in the middle/high-frequency region. Therefore, the effective absorption bandwidth (EAB) of 9.03 GHz and the minimum reflection loss (RL_min) of −64.05 dB at a filling rate of 10 wt.% are obtained, which improves the record of carbon absorbers as reported. Through macro-designs, i.e., multi-layer gradient metamaterial, or utilizing other advantages, e.g., cost-effective, stable chemical properties and wide-angle absorption, porous carbon may possess a great application prospect in the naval field.     

Organic light-emitting diodes fabricated on recessed anodes for light extraction enhancement

Circular recesses have been fabricated on indium tin oxide (ITO) anodes to enhance light extraction of organic light-emitting diodes (OLEDs). The effects of recess depth and recess coverage ratio on the performance of a green OLED were systematically investigated. Results showed that the current efficiency could be enhanced from 40.7 cd/A of a planar device to 47.2 cd/A of the device with a recess depth of 100 nm and a recess coverage ratio of 14.1%. The enhanced light extraction by the recess wall effect was realized to be the major factor leading to the improved efficiency. The efficiency is however limited by the accompanying increase in electrical resistivity of the ITO films at deep recesses and high recess coverage ratios. Despite of the insignificant efficiency enhancement (up to 16%) in this study, this recessed ITO approach provides a simple architecture to enhance waveguide mode light extraction without adding an internal medium.     

兆赫兹飞秒激光脉冲制备“珍珠串”光波导

对纳焦量级的高重频飞秒激光在玻璃内部制备"珍珠串"光波导进行了研究。在制备过程中向外辐射出白光连续光谱,实验结果表明飞秒激光脉冲能量和运行速度对"珍珠串"光波导的形成有较大影响,在激光脉冲能量10.5 nJ,玻璃运行速度为0.2 mm/s情况下制备的"珍珠串"光波导结构较好,"珍珠串"的横向宽度为19μm,"珍珠串"的间隔周期为20μm。制备的"珍珠串"光波导能对玻璃内传输的He-Ne激光进行有效约束。最后对玻璃内部制备"珍珠串"光波导的机制进行了分析。     

Bulky rigid substitutions: A route to high electron mobility and high solid-state luminescence efficiency of perylene diimide

In this paper, we report that a kind of perylene diimide derivative with bulky rigid substituents, 1,7-bis(p-tert-butylphenoxy)-N,N′-dicyclohexyl-perylene-3,4,9,10-tetracarboxylic diimide (TBPCHPDI) possesses both high electron mobility (1.8 cm² V⁻¹s⁻¹) and high fluorescence quantum yield (0.32) in the solid state. Through X-ray diffraction (XRD), UV–Vis absorption and fluorescence spectra, and differential scanning calorimetry (DSC) measurements, it is demonstrated that the above phenomenon can be ascribed to the unique crystal structure of TBPCHPDI: due to steric hindrance of bulky rigid substituents, the intermolecular π–π actions are neglectable, providing high luminescence efficiency; in the mean time, the spacing between perylene chromophores is still very short (3.47 Å), which is favorable for the hopping transportation of charge carrier from one molecule to neighboring molecule. Therefore, our finding would help design and synthesize novel organic semiconductive materials with potential applications in electrically pumped lasers which require high emission efficiency when large current density is applied.     

Biomimetic Hygroscopic Fibrous Membrane with Hierarchically Porous Structure for Rapid Atmospheric Water Harvesting

Sorption-based atmospheric water generation (SAWG) is a promising strategy to alleviate the drinkable water scarcity of arid regions. However, the high-water production efficiency remains challenging due to the sluggish sorption/desorption kinetics. Herein, a composite sorbent@biomimetic fibrous membrane (PPy-COF@Trilayer-LiCl) is reported by mimicking nature's Murray networks, which exhibits outstanding water uptake performance of 0.77–2.56 g g⁻¹ at a wide range of relative humidity of 30%–80% within 50 min and fast water release capacity of over 95% adsorbed water that can be released within 10 min under one sun irradiation. The superior sorption–desorption kinetics of PPy-COF@Trilayer-LiCl are enabled by the novel hierarchically porous structure, which is also the critical factor to lead a directional rapid water transport and vapor diffusion. Moreover, as a proof-of-concept demonstration, a wearable SAWG device is established, which can operate 10 sorption–desorption cycles per day in the outdoor condition and produce a high yield of clean water reaching up to 3.91 kg m⁻² day⁻¹. This study demonstrates a novel strategy for developing advanced solar-driven SAWG materials with efficient water sorption–desorption properties.     

Versatile Graphene‐Promoting Photocatalytic Performance of Semiconductors: Basic Principles,Synthesis, Solar Energy Conversion,and Environmental Applications

Graphene‐semiconductor nanocomposites, considered as a kind of most promising photocatalysts, have shown remarkable performance and drawn significant attention in the field of photo‐driven chemical conversion using solar energy, due to the unique physicochemical properties of graphene. The photocatalytic enhancement of graphene‐based nanocomposites is caused by the reduction of the recombination of electron‐hole pairs, the extension of the light absorption range, increase of absorption of light intensity, enhancement of surface active sites, and improvement of chemical stability of photocatalysts. Recent progress in the photocatalysis development of graphene‐based nanocomposites is highlighted and evaluated, focusing on the mechanism of graphene‐enhanced photocatalytic activity, the understanding of electron transport, and the applications of graphene‐based photocatalysts on water splitting, degradation or oxidization of organic contaminants, photoreduction of CO₂ into renewable fuels, toxic elimination of heavy metal ions, and antibacterial applications.     

膜式水冷壁多焊机群控系统

基于DSP的多焊接电源群控系统被应用于膜式水冷壁焊机中.该系统引入优先级群控策略,多台焊接电源在外部参数发生波动时,按不同优先级的群控策略进行有序调整,减小了调整时间和调整误差.同时,根据焊接区域和焊接过程中管屏温度场分布规律,引入焊接参数实时调整策略,实现多台焊接电源在起弧段、稳弧段和收弧段等不同焊接过程的参数动态调整.结果表明,使用该系统控制焊机中的多台焊接电源,膜式水冷壁管屏焊接变形得到有效控制,焊接质量有较明显的提高.