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71.
Vapor-liquid equilibrium,coexistence curve,and critical locus for binary HFC-32/HFC-134a mixture 总被引:2,自引:0,他引:2
Y. Higashi 《International Journal of Thermophysics》1995,16(5):1175-1184
Two kinds of equilibrium measurements of binary R-32/134a mixtures were carried out. The vapor-liquid equilibria were measured by the static method in the temperature range between 283 and 313 K. On the basis of the present experimental data, the temperature dependence of the binary interaction parameterk
12 for two equations of state, namely, the Soave-Redlich-Kwong equation and Carnahan-Starling-De Santis equation, was discussed. The vapor-liquid coexistence curve near the critical point was also measured by the observation of meniscus disappearance. The critical temperatures and critical densities of 30 and 70 wt% R-32 mixtures were determined on the basis of the saturation densities along the coexistence curve in the critical region. In addition, a correlation of the critical locus for this mixture is proposed as a function of composition.Paper presented at the Twelfth Symposium on Thermophysical Properties, June 19–24, 1994, Boulder, Colorado, U.S.A. 相似文献
72.
A single phase of Li2CuO2 was successfully prepared by solid state reaction. The crystal structure was refined by Rietveld method using a synchrotron radiation source. Electronic structures of x = 0 and 1 in Li2−xCuO2 were determined using the first principle calculation. We will discuss electrochemical properties of Li2CuO2 and changes in electronic structure of Li2−xCuO2, using both the information obtained from the calculation and that obtained experimentally. These results confirmed that Li-extraction of Li2CuO2 resulted in the oxidation of Cu2+ or O2−. The cuprate-based cathode materials have the potential showing high energy density. The calculation of electronic state will play a major role in designing the materials for Li-batteries. 相似文献
73.
Y. Higashi 《International Journal of Thermophysics》1999,20(2):507-518
The vapor–liquid equilibrium of the mixture composed of difluoromethane (R-32) and propane (R-290) was studied in the temperature range between 273.15 and 313.15 K. The experimental uncertainties of temperature, pressure, and composition measurements were estimated to be within ±10 mK, ±3 kPa, and ±0.4mol%, respectively. Comparisons between the present data and available experimental data were made using the Helmholtz free energy mixture model (HMM) adopted in the thermophysical properties program package, REFPROP 6.0, as a baseline. In addition, the existence of an azeotrope and the determination of new adjustable parameters for HMM for the R-32 + R-290 mixture are discussed. 相似文献
74.
Evolved gas analysis−ion attachment mass spectrometry (EGA−IAMS) was utilised to study the real-time non-isothermal decomposition of vitamin C. Dehydro-l-ascorbic acid, which has until this study been undetectable from the solid phase degradation of vitamin C, was observed as a decomposition product. While it is an important compound because it possesses some biological activity, dehydro-l-ascorbic acid is difficult to measure due to its chemical instability. In the present study using EGA−IAMS, we were able to detect dehydro-l-ascorbic acid from the thermal degradation of vitamin C. Our EGA−IAMS results obtained from the thermal decomposition of vitamin C were compared with a previous study employing pyrolysis-gas chromatography−mass spectrometry (Pyr-GC−MS). The observed quantitative and qualitative differences of the pyrolysis products obtained by the two techniques (EGA−IAMS vs. Pyr-GC–MS) are in part due to the difference in transportation time of the products out of the pyrolysis chamber. 相似文献
75.
Water-soluble polyaniline/graphene nanocomposites have been prepared via a simple in situ polymerization of aniline in graphene dispersion. TEM measurement confirmed that polyaniline was homogeneously coated on the graphene sheets. The nanocomposites solution can be used for film fabrication by common technology, such as drop coating. When these different polyaniline/graphene nanocomposites were applied as the counter electrode materials for dye-sensitized solar cells, the short-circuit current density and power-conversion efficiency of the devices were measured to be 12.19 mA cm−2 and 4.46%, respectively, which was comparable to 5.71% for the cell with a Pt counter electrode under the same experimental conditions. 相似文献
76.
Katsuyuki Tanaka Takuya Yasuno Yukihiro Higashi Shunichi Okuzaki Tatsuo Katakura 《亚洲传热研究》2009,38(8):507-519
A temperature‐change sensor by thermoelectric elements that is directly connected to a p‐type element and an n‐type element was developed. A β‐FeSi2 thermoelectric semiconductor made by a spark plasma sintering method was used as a prototype sensor. Evaluation of this thermoelectric temperature‐change sensor was carried out by measuring its electromotive force when it was dropped into a thermostated water bath. It was confirmed that there existed a correlation between the temperature difference and the electromotive force of the sensor, i.e., approximately 5 mV of electromotive force was generated at a temperature difference of 30 K. In addition, the dependence of electromotive force on the size and properties of the thermoelectric elements was evaluated by carrying out FEM analysis. © 2009 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.20268 相似文献
77.
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79.
Accurate measurements of gyration tensors g11 (=-g22) and electrogyration effect of KH2PO4 were made by applying the improved HAUP method. g11 diverges conspicuously when the temperature approaches Tc from above and below it, the behaviour being analyzed as obeying the Curie-Weiss law with a Curie-Weiss constant of 7.35×10-4 K. An electrogyration coefficient π13 referring to the polarization manifests a characteristic nature of improper ferroelectrics. 相似文献
80.
A series of new amphoteric surfactants, sodium salts of N-(2-hydroxyethyl)-N-(2-hydroxyalkyl)-β-alanines (Na-HAA) was prepared
by adding methyl acrylate to N-(2-hydroxyalkyl)-ethanolamine and subsequent saponification. Neutralization with HCl gave N-(2-hydroxyethyl)-N-(2-hydroxyalkyl)-β-alanines,
and the addition of ethylene oxide to Na-HAA gave oxyethylated drivatives. The structures of these compounds prepared were
confirmed by infrared spectra, proton magnetic resonance spectra, elementary analyses, etc. Solubility in water, surface tension,
foaming power, and critical micelle concentration were determined. 相似文献