Synthesis of bristlegrass-like Co-doped Ni2P composites on Ni foam for overall seawater splitting

Seawater is the most abundant resource on earth, so developing cost-effective, highly durable corrosion resistance and efficient electrocatalysts are crucial to enhance seawater splitting. Herein, we prepared 3D bristlegrass-like Co-doped Ni₂P (Co-Ni₂P) composites supported on Ni foam (NF) through a facile solvothermal method combined and a subsequent phosphatization treatment. Benefiting from the unique structure, Co-Ni₂P shows excellent electrocatalytic activity as an electrode material for both the hydrogen evolution reaction (HER, low overpotential of 116 mV at 50 mA cm^?2) and oxygen evolution reaction (OER, low overpotential of 266 mV at 50 mA cm^?2). Moreover, the as-prepared Co-Ni₂P composites exhibit excellent stability and corrosion resistance in an alkaline medium. Density functional theory (DFT) calculations were employed to evaluate the H1 adsorption of Co-Ni₂P, and the results proved the high catalytic activity for the HER. This study provides new materials with a unique morphology for overall water splitting.     

Irradiation-induced large bubble formation and grain growth in super nano-grained ceramic

In this work, 0.5TRPO•0.5Gd₂Zr₂O₇ ceramic with an average grain size of only ∼15 nm was prepared by a high pressure (5 GPa/520 °C) sintering method. Phase evolutions and microstructure changes of the as-fabricated super nano and micron-grained ceramics under a high-dose displacement damage induced by 300 keV Kr²⁺ ions were investigated. The results show that the super nano-grained ceramic has low degree of amorphization, obvious grain growth (2–3 times in grain size) and big Kr bubbles (10–68 nm) formation after irradiation. The micron-grained ceramic was severely amorphized after irradiation and many microcracks were formed parallel to its surface. The formation mechanism of Kr bubbles in the super nano-grained ceramic is on account of grain boundary diffusion and migration induced by the accumulation of the injecting Kr ions and irradiation defects. Nevertheless, microcracks formed in the micron-grained sample are caused by the accumulation of Kr atoms.     

Optimised phase compositions and improved microwave dielectric properties based on calcium tin silicates

The Ca_(1+2y)Sn_(1-x)Si_(1+y)O_(5-2x+4y) low-permittivity microwave dielectric ceramics were prepared through solid-state reaction at 1350–1450 °C for 5 h. The relations between microwave dielectric properties and phase compositions for non-stoichiometric Ca_(1+2y)Sn_(1-x)Si_(1+y)O_(5-2x+4y) ceramics have been investigated. A single CaSnSiO₅ phase with abnormally positive temperature coefficient of resonant frequency (τ_f = + 62.5 ppm/°C) was synthesised at 1450 °C. This composition was an effective τ_f compensator of CaSiO₃ and Ca₃SnSi₂O₉ phases with typically negative τ_f value. The CaSiO₃ second phase was related to the Sn deficiency in the CaSn_(1-x)SiO_(5-2x) (0 < x < 1.0) composition, whereas the Ca₃SnSi₂O₉ second phase was obtained by controlling the Ca:Sn:Si ratios on the basis of the Ca_(1+2y)SnSi_(1+y)O_(5+4y) (0 < y < 1.0) composition. A promising low-permittivity millimetre-wave ceramic with most excellent microwave dielectric properties (ε_r = 10.2, Q×f = 81,000 GHz and τ_f = −4.8 ppm/°C) was produced from the Ca_(1+2y)SnSi_(1+y)O_(5+4y) (y = 0.4) ceramic.     

Disappearance and recovery of colossal permittivity in (Nb+Mn) co-doped TiO2

We investigate the effects of doping and annealing on the dielectric properties of metal ions doped TiO₂ ceramics. Colossal permittivity (CP) above 10⁴ was observed in single Nb ion doped TiO₂, which was dominated by electron transport related interfacial polarization. Moreover, the CP can be dropped to 120 when simultaneously introducing Mn ion into the sample. The disappearance of CP behaviors maybe due to the multivalence of Mn which would inhibit the reduction of Ti⁴⁺ to Ti³⁺, and thus reduce delocalized electrons. Interestingly, the CP was recovered for the (Nb+Mn) co-doped TiO₂ after post-sintering heat treatment in N₂ atmosphere. The recovery of CP in the sample after annealing can be ascribed to the semiconducting grain and the insulating grain boundary, according to impedance spectroscopy. We therefore believe that this work can help us understand the mechanism of CP from a new perspective.     

Inverse analyses of diffusion processes in type 13X zeolite particles

To determine effective surface self-diffusion coefficients of CO₂ within type 13X zeolite particles, at various temperatures (25–70 °C), inverse analyses of observed CO₂-uptake curves were successfully performed. The obtained effective surface self-diffusion coefficients increase with both the amount adsorbed and the temperature and ranged from 7.8 × 10⁻¹⁰ to 1.95 × 10⁻⁹ m²/s under the present experimental conditions.     

苦味酸钾点火药在电点火头中的应用

通过理论分析和试验,从机械感度、燃烧精度、热安定性、性能、长贮等方面,对比分析了苦味酸钾点火药与DDNP点火药.结果表明:在电点火头制造中,采用苦味酸钾作为点火药的主要组分,具有热稳定性好、药头机械强度高、生产过程废品少、无环境污染等优点,尤其有利于提高电雷管的发火可靠性和一致性.     

单孔护壁爆破数值模拟

运用LS-DYNA软件对单孔护壁爆破和切缝药包爆破进行了三维数值模拟,结果显示,由于PVC-U套管的存在,作用于孔壁的爆炸应力波峰值被显著削弱,降低率达到30%～46%,并推迟了其到达保留岩体孔壁时间.与传统的切缝药包爆破相比,保留岩体损伤更小.     

基于Sql Server BI平台和决策树技术的CET-4成绩分析

文章首先对Sql Server 2008商业智能平台及决策树技术相关理论作了介绍,然后对挖掘数据源数据进行了一系列预处理。利用Sql Server 2008商业智能平台下的决策树技术并采用数据挖掘扩展语言即DMX语言创建了CET-4成绩分析决策树模型。分类矩阵和挖掘提升图分别对该模型的评估结果表明了模型具有较高的可靠性和分类准确度,同时模型对应的一些规则可作为英语教学管理和改革的重要参考依据。     

基于山区地质灾害危险性分区的建设用地适宜性评价

地质灾害是建设用地选址时考虑的关键因素之一,也是危险性区划的主要参考要素,其直接或间接危害到人类安全并给社会和经济建设造成重大损失。为了降低建设用地规划中地质灾害的影响,应将地质灾害危险性分区考虑到建设用地适宜性评价当中。以干旱河谷山区丹巴县为研究区,运用确定系数和逻辑回归相结合的方法,构建地质灾害危险性评价体系对该区进行地质灾害危险性分区。选择安全因子、自然因子、社会因子和生态因子共同构成建设用地适宜性评价指标体系,利用层次分析法对研究区进行建设用地适宜性评价。结果表明:(1)对丹巴县进行危险性分区,极高危险区217.20km2,高危险区744.95km2,中度危险区1352.44km2,低度危险区1295.08km2以及极低危险区875.32km2。(2)丹巴县建设用地最适宜区面积为115.72km2,占县域总面积的2.57%,适宜建设的土地少且多集中在小金川、革什扎河、东谷河和大渡河沿岸河谷地区。较适宜区、基本适宜区、较不适宜区和禁止建设区面积分别为683.47km2、623.21km2、590.66km2、2494.21km2。(3)已建成的城镇空间中38.50%和37.62%分布在最适宜区和较适宜区,整体分布状况良好。有5.85%的城镇空间建设在较不适宜区,2.67%在禁止建设区,存在生态安全风险,该区域应加强灾害预警与防灾减灾工作,有条件地适度搬迁。     

不同土性地基考虑 ＳＳＩ效应的隔震结构地震响应分析

为探究不同土性地基的ＳＳＩ效应对层间隔震结构影响机理与动力响应规律,选取一个典型层间隔震结构,对其简化并制作缩尺模型,采用振动台试验的方法,分别在硬土、软土这两种地基上单向输入4条地震波来研究模型的动力响应。结果表明:土体具有明显的放大效应,随着地基土由硬变软,隔震结构周期延长倍数降低。隔震结构在硬土地基上能发挥较好的减震效果,而软土地基上减震效果明显减弱。软土地基上塔楼的动力响应较硬土地基增大,塔楼容易成为薄弱部位,其抗震设计应重点关注。