芴甲氧羰基酪氨酸苄醚的合成研究

研究了硫酸铜存在下溴苄与酪氨酸反应生成酪氨酸苄醚,收率45%。反应中,铜盐先与酪氨酸的羧基作用,生成4∶1的酪氨酸铜配合物,从而有效地保护了酪氨酸的羧基,使苄基化反应选择性地发生在侧链酚基氧原子上。酪氨酸苄醚与芴甲氧羰酰氯在THF中反应得标题化合物,收率98%。     

基于三级签名的安卓恶意软件分析方法

智能手机上的恶意软件数量呈现爆炸式增长,目前迫切需要一个安全分析与检测方法.一个有效的检测与分析方法需要解决的最大问题就是如何从应用程序和恶意软件的汪洋大海中识别重新包装的应用程序.论文提出了基于三级签名的恶意软件分析方法MSAnalytics,根据API调用序列,提取在操作码级的恶意软件特征,生成应用程序三级签名.实验证明,MSAnalytics对重新包装恶意软件具有良好的分析能力.     

水性UV图案化功能涂膜技术研究

研究了一种新型水性UV涂料制备技术,可得到用传统方法无法获得的图案化涂膜。利用扫描电镜、DSC、凝胶渗透色谱等对该图案化聚合物进行分析表征;考察了不同功能添加剂对涂膜形貌的影响;并讨论了光照时间、光引发剂用量与聚合物相对分子质量间的关系。     

A new result on the delay‐dependent stability of discrete systems with time‐varying delays

This paper proposes an improvement to the delay‐dependent stability of discrete systems with time‐varying delays. The approach is based on the observation that the positive definiteness of a chosen Lyapunov–Krasovskii functional does not necessarily require all the involved symmetric matrices to be positive definite, which has been overlooked in the literature. The derived delay‐dependent stability conditions are in terms of linear matrix inequalities. It is theoretically proved that our results are less conservative than the corresponding ones obtained by requiring the positive definiteness of all the symmetric matrices in a chosen Lyapunov–Krasovskii functional. The importance of the present approach is that a great number of delay‐dependent analysis and synthesis results obtained by the aforementioned requirement in the literature can be improved by the present approach without introducing any new decision variables. Copyright © 2013 John Wiley & Sons, Ltd.     

Investigation of LSM/8YSZ cathode within an all-ceramic SOFC,Part II: Optimization of performance and co-sinterability

This paper focuses on the cathode and current collector layers of a co-sintered, all-ceramic solid oxide fuel cell (SOFC) concept. Challenges to reach good electrochemical performance have to be overcome, due to more demanding manufacturing conditions, including a relatively high co-sintering temperature. Master sintering curves show that the sintering activity of lanthanum strontium manganite (LSM) is significantly higher than that of 8-mol% yttria stabilized zirconia (8YSZ). By applying a double-layered cathode and a current collector with optimized microstructures the best electrochemical performance of the cathode is 0.26 $\mathrm{\Omega }$cm${}^2$ at 800 $°$C, evaluated from polarization resistances of 8YSZ electrolyte-supported symmetric cells post-sintered at 1150 $°$C $<T<1250$ $°$C. The cathode and current collector materials are adapted to fit the co-sintering process by adjustment of the paste compositions. Half-cells consisting of silicate mechanical support, LSM current collector, LSM mixed with 8YSZ composite cathode and 8YSZ electrolyte are co-sintered porous and defect-free at 1150 $°$C $<T<1250$ $°$C.     

基于蚁群算法的离散救援问题出救点选址研究

为解决应急物流中的出救点选址问题,建立了相应数学模型,引入蚁群算法解决问题。多数应急物流可以归为点对点的支援问题,出救点的设置应该在保证出救有效的条件下使出救点最少、救援时间最短,属于双层规划问题。双层规划问题是NP难题,可以应用蚁群算法解决。出救点选址问题在蚁群算法中可以视为蚁群的聚类,通过对信息素衰减及相邻蚂蚁的吸引作为启发因子,可以得到蚁群的聚类效果。实验结果表明,基于蚁群算法的选址问题解决方案能获得理想的选址效果,收敛速度较快。     

基于不变量的程序修复进化扩展模型*

为了有效解决程序修复进化中搜索空间过大和正常功能牺牲的问题,提出了一种基于不变量约束的扩展的程序修复进化模型（extended repair evolutionary model,EREM）,利用程序不变量约束对搜索空间进行划分和约简以降低消耗,通过使用表达程序正常功能的正测试用例学习的不变量约束（称为正不变量约束）来保证程序不牺牲正常的功能,在适应度函数的设计上考虑测试用例通过数的同时也考虑了正不变量约束的保持数,对于破坏正不变量约束的个体适应度给予一定的惩罚值。最后通过实验对模型进行了验证,结果表明了     

金属卟啉仿生催化剂进展

细胞色素P-450是一种生物体内催化分子氧氧化内源底物的单加氧酶,其活性片段的核心结构是金属卟啉络合物。人工合成的金属卟啉络合物可作为细胞色素P-450的有效模拟物,应用于烯烃、直链烷烃、环烷烃、芳烃、芳烃侧链、及各种杂原子等多种底物的催化氧化。人工合成的金属卟啉络合物可分为：对称型金属卟啉、非对称型金属卟啉、μ-氧代双核金属卟啉、负载型金属卟啉4大类。现以金属卟啉络合物的结构为线索,论述了结构与催化活性及稳定性的内在联系,重点介绍了近几年国内外金属卟啉仿生催化剂的氧化应用研究进展,及仿生催化氧化的工业化发展前景。     

基于连续分布方向图的复合指纹图像分割算法

实现了一种结合连续分布方向图与方差分割的复合指纹分割算法,改进了指纹图像分割效果并提高了指纹图像分割的精确度。对FVC2000、FVC2002和FVC2004数据库的实验结果表明,该算法能有效地对指纹图像进行自动分割,具有较快的速度和较好的鲁棒性。