模拟企业生产的现代机械制造大实验平台构建的研究

针对在知识经济和全球市场经济的形式下,剧烈竞争的焦点将聚集于创新人才的竞争,探讨了机械制造业创新型人才的培养途径;设计了适合机械制造业创新人才培养模式的实验独立设计课,构建出模拟现代企业生产的现代机械制造大实验平台.     

富水土壤源热泵供冷采暖机组运行特性研究

介绍了作者自主设计实施的土壤换热器与冷却塔并联的耦合型地源热泵空调系统,运用单因素方法,研究了冬夏两季热泵机组的运行特性;研究结果表明:夏热冬暖地区,本实验系统夏季采用热泵机组匹配土壤源释热的制冷效果一般,制冷工况热泵机组能效比约3.66,系统能效比约2.7;冬季采用热泵机组向建筑物供暖效果较佳,系统能效比达3.4以上.     

Nanocrystalline LaMnO3 preparation and kinetics of crystallization process

Precursor of nanocrystalline LaMnO₃ was synthesized by solid-state reaction at low heat using La(NO₃)₃·6H₂O, MnSO₄·H₂O, and Na₂CO₃·10H₂O as raw materials. XRD analysis showed that precursor was a mixture containing orthorhombic La₂(CO₃)₃·8H₂O and rhombohedral MnCO₃. When the precursor was calcined at 800 ^°C for 2 h, pure phase LaMnO₃ with rhombohedral structure was obtained. Magnetic characterization indicated that rhombohedral LaMnO₃ behaved weak magnetic properties. The thermal process of the precursor experienced four steps, which involved the dehydration of crystallization water at first, and then decomposition of manganese carbonate into MnO₂, and decomposition of La₂(CO₃)₃ and MnO₂ together into La₂O₂CO₃ and Mn₂O₃, and lastly reaction of monoclinic La₂O₂CO₃ with Mn₂O₃ and formation of rhombohedral LaMnO₃. Based on the Kissinger equation, the value of the activation energy associated with the formation of rhombohedral LaMnO₃ was determined to be 260 kJ mol^?1. The value of the Avrami exponent, n, was equal to 1.68, which suggested that crystallization process of LaMnO₃ was the random nucleation and growth of nuclei reaction.     

Effects of Bi excess on the structure and electrical properties of high-temperature BiFeO3–BaTiO3 piezoelectric ceramics

BiFeO₃–BTiO₃(BF–BT) ceramics as a promising candidate for lead-free high-temperature piezoelectric ceramics were studied with a special emphasis on the compositional dependence of piezoelectric properties. Excess Bi was added to compensate for the evaporation of Bi³⁺ ions during sintering and this addition was found to be effective in improving the piezoelectric properties of BF–BT ceramics. The microstructure, dielectric and piezoelectric properties of excess Bi doped BF–BT ceramics were investigated. Maximum piezoelectric constant d ₃₃ = 142 pC/N and k _p = 0.302 were obtained with 0.04 Bi doping. At the same time, an enhanced Curie temperature T _c, 452 °C, was obtained. The combination of improved piezoelectric properties and increased T _c makes these ceramics suitable for elevated temperature piezoelectric devices.     

Lead-free (Li, Na, K)(Nb, Sb)O3 piezoelectric ceramics: effect of Bi(Ni0.5Ti0.5)O3 modification and sintering temperature on microstructure and electrical properties

Lead-free (1 ? x)(K_0.475Na_0.475Li_0.05)(Nb_0.95Sb_0.05)O₃–xBi(Ni_0.5Ti_0.5)O₃ [(1 ? x)KNNL–xBNiT] piezoelectric ceramics were prepared by conventional solid-state sintering. The effect of BNiT addition and sintering temperature on phase structure, microstructure, and dielectric and piezoelectric properties of (1 ? x)KNNL–xBNiT ceramics was investigated. The results reveal that the addition of small amounts of BNiT causes significant changes in microstructures, crystalline structures, and dielectric and piezoelectric properties. The T _c values and dielectric constant at T _c of (1 ? x)KNNL–xBNiT ceramics are increased obviously with 0.2 % BNiT addition and decreased with further increasing BNiT content. Enhanced piezoelectric properties are obtained for the sample with x = 0.4 % and synthesized at optimal temperature of 1100 °C, in which d ₃₃ and k _p are 253 pC/N and 0.52, respectively. These results show that (1 ? x)KNNL–xBNiT ceramics are promising lead-free piezoelectric materials.     

Phase diagram of Er-Sn-Te system for diluted magnetic semiconductor developments

Phase diagrams of the RE (rare earth)-IV-VI systems are very important for the design of rare earth doped diluted magnetic semiconductors (DMSs), but related information is very limited. In this work, ...     

假乙内酰硫脲酸在铜-钼浮选分离中的抑制性能(英文)

将合成的假乙内酰硫脲酸(PGA)用作铜-钼分离抑制剂。该药剂闭路实验结果表明:假乙内酰硫脲酸在较小的用量下对黄铜矿有较强的抑制作用,经一次粗选、一次扫选、两次精选,可获得Mo品位大于26%、回收率大于89%的浮选指标,而用Na2S做抑制剂时钼的回收率下降了2%。药剂吸附量测试结果表明,PGA与丁基黄药在矿物表面发生竞争吸附,PGA在黄铜矿表面上的吸附量远大于在辉钼矿表面的。红外光谱分析表明,PGA在黄铜矿表面是化学吸附,而在辉钼矿表面属于物理吸附。前线轨道计算结果表明,在PAG分子中,硫原子是反应活性的中心。利用矿物、丁黄药及PGA的费米能级能量大小可以从电化学作用角来度解释PGA的抑制机理。     

Experimental Investigation of the Al-Fe-Gd System at 773 K

The phase equilibrium of the Al-Fe-Gd plays an important role of development of bulk amorphous alloys and magnetocaloric materials. The entire isothermal section of the phase diagram for Al-Fe-Gd ternary system at 773 K has been investigated by means of x-ray powder diffraction, scanning electron microscopy with energy dispersive analysis, and optical microscopy. The existences of 13 binary compounds for the Al-Fe, Al-Gd, and Fe-Gd binary systems were confirmed. The binary phases, i.e., Al₂Gd, Fe₂Gd, and α-Fe₁₇Gd₂ present appreciable ternary solubility. Three ternary compounds: τ₁-Al₁₀Fe₂Gd, τ₂-Al_8+x Fe_4-x Gd (0 ≤ x ≤ 2), and λ-Al_2?x Fe _x Gd (0.951 ≤ x ≤ 1.245) were determined. The isothermal section consists of 19 single-phase regions, 40 binary-phase regions, and 20 ternary-phase regions.     

基于专用DCS的煤矿工业锅炉监控系统设计

简要介绍了一种煤矿工业锅炉的专用DCS监控系统设计方案,并进行了造价预算。实践证明采用专用DCS设计的煤矿工业锅炉监控系统较传统的PLC监控系统而言,具有更高的稳定性和更好的易用性,即插即用的设计非常适合现有技术人员。     

煤矿自备电厂锅炉给水控制策略改进

文章结合某煤矿自备电厂锅炉给水系统扰动因素分析,在传统三冲量给水控制策略的基础上,提出以汽包压力微分迟滞信号作为给水流量跟踪副环的前馈量,并延迟给水指令。通过燃烧扰动、蒸发量扰动试验证明,该控制方案具有较强的抗扰动能力。