Hydrogen storage of dual-Ti-doped single-walled carbon nanotubes

The hydrogen adsorption capacity of dual-Ti-doped (7, 7) single-walled carbon nanotube (Ti-SWCNTs) has been studied by the first principles calculations. Ti atoms show different characters at different locations due to local doping environment and patterns. The dual-Ti-doped SWCNTs can stably adsorb up to six H₂ molecules through Kubas interaction at the Ti₂ active center. The intrinsic curvature and the different doping pattern of Ti-SWCNTs induce charge discrepancy between these two Ti atoms, and result in different hydrogen adsorption capacity. Particularly, eight H₂ molecules can be adsorbed on both sides of the dual-Ti decorated SWCNT with ideal adsorption energy of 0.198 eV/H₂, and the physisorption H₂ on the inside Ti atom has desirable adsorption energy of 0.107 eV/H₂, ideal for efficient reversible storage of hydrogen. The synergistic effect of Ti atoms with different doping patterns enhances the hydrogen adsorption capacity 4.5H₂s/Ti of the Ti-doped SWCNT (VIII), and this awaits experimental trial.     

Experimental investigation of hydrogen production by CH4–CO2 reforming using rotating gliding arc discharge plasma

Hydrogen produced from CH₄–CO₂ reforming by an optimized rotating gliding arc discharge plasma reactor is investigated in this study. The effect of CH₄/CO₂ ratio (mole ratio), total input flow rate, discharge gap, voltage, and discharge frequency are analyzed. The results show that H₂ yield increases with the increase of CH₄/CO₂ ratio. Arc can be stretched effectively by increasing total input flow rate, then the discharge region is enlarged. Increasing discharge gap can enlarge the discharge region, but the reaction of the gas mixture would be suppressed if the discharge region was excessively large. The discharge region decreases with the increased discharge frequency to a certain degree. Based on the experimental results, the optimal experimental condition is concluded as applied voltage 60 V, discharge frequency 20 kHz, and minimum discharge gap 3 mm. It is anticipated that the results would serve as a good guideline to the application of hydrogen production from hydrocarbon fuels by plasma reforming onboard.     

Hydrogen storage in TiO2 functionalized (10, 10) single walled carbon nanotube (SWCNT) – First principles study

Hydrogen storage in titanium dioxide (TiO₂) functionalized (10, 10) armchair single walled carbon nanotube (SWCNT) is investigated through first principle calculations using density functional theory (DFT). This first principles study uses Vienna Ab-initio Simulation Package (VASP) with ultrasoft pseudopotentials and local density approximation (LDA). The necessary benchmark and other systematic calculations were carried out to project the hydrogen storage capability of the designed system. Interestingly, the TiO₂ molecules functionalized on the outer surface of SWCNT do not undergo any dimerization/clustering thus giving excellent stability and usable gravimetric hydrogen storage capacity of 5.7 wt.% and the value nearly fulfills the US DOE target (i.e. 6 wt.%). The band structure and density of states (DOS) plots suggest that the functionalization can lead a way to transform the nature (metallic → semiconducting) of the pristine SWCNT. The nominal values of H₂ storage capacity and binding energies give much hope for using CNT functionalized with TiO₂ as a practical and reversible hydrogen storage medium (HSM).     

Design of a security-aware routing scheme in Mobile Ad-hoc Network using repeated game model

Security is a crucial factor in Mobile Ad hoc Networks (MANET) where inaccessible environments cause assorted categories of security intimidations to provide the malicious-free network. Game theory plays a crucial part in scheming well-organized security methodologies in computer networks. In this work, an Infinitely-repeated game and cooperation approach is designed to detect malicious nodes and also to enhance energy-efficiency. The goal of an Infinitely-repeated game aims to ensure the defector or malicious node in the network has a short run gain and a long-run loss. The prime objective of the proposed scheme is to attack detection and defense, accuracy for preventing the packet drops. The proposed method is verified via simulation.     

Heat transfer enhancement of concentrated solar absorber using hollow cylindrical fins filled with phase change material

A concentrated solar absorber with finned phase change materials was experimentally studied using a Scheffler type parabolic dish concentrator. The absorber's inner surface was fixed with hollow cylindrical containers filled with phase change material (PCM) for heat transfer augmentation. The absorber's selected PCM was acetanilide (Melting point of 116 °C)—the cylindrical capsules protruding into the fluid side to create turbulence and mixing and acting as fins. The absorber surface temperature was observed to be about 130–150 °C during the outdoor tests while passing fluid through the absorber. The fluid flow rate varied from 60 to 100 kg/h during the outdoor experiments. The peak energy and exergy efficiency of parabolic dish collector (PDC) at the fluid flow rate of 80 kg/h with PCM integrated solar absorber was found to be about 67.88% and 6.96%, respectively. The integration of cylindrical PCM containers resulted in more heat transfer augmentation in the solar absorbers. The optimized solar absorber could be suitable for various applications like steam generation, biomass gasification, space heating, and hydrogen generation.     

Construction of cultural industry development factor model based on factor analysis,artificial intelligence and big data

The rapid development of the level of social informatization has allowed the content related to computer science to advance with the times and have derived two fields of big data and artificial intelligence. Specifically, the theory and methods of artificial intelligence themselves provide key support for big data. On the other hand, big data also provides auxiliary means for the research and analysis of artificial intelligence. Artificial intelligence will become the mainstream development trend of the future society, and the application of big data technology under the background of artificial intelligence will also be systematic in many fields. This paper analyzes the internal and external factors in the development of cultural industry by means of econometric research methods and big data and artificial intelligence, principal component analysis, factor analysis and multiple regression analysis, establishes the model of cultural industry development factors, breaks through the traditional research methods, analyzes the impact of the core, foundation, environment, kinetic energy, efficiency, potential and other factors on the comprehensive index of the development of cultural industry, and analyzes the comparative advantages and development trend of cultural industry in all provinces and municipalities of China. In this paper, the "three elements" model is comprehensively demonstrated by quantitative and qualitative methods, which solves the problem of lack of qualitative and quantitative research methods in cultural industry.     

Simulation of quantum key distribution in a secure star topology optimization in quantum channel

The field of quantum cryptography is mostly theoretical therefore in this paper we represent its implementation by means of virtual scenarios. The central issue in cryptography is the secure transmission of the key between nodes. Thus, in this paper we establish a secure channel using Quantum Key Distribution (QKD) for the transfer of the key material between the nodes and help to identify an eavesdropper in the channel. A graphical representation of the quantum channel traffic at the ideal state and also during network disruption has been established. Due to the complex nature of quantum networks and high cost of establishment, a physical implementation of the same is not feasible. Hence a simulation has been implemented via the use of NS-3 (Network Simulator Version 3) which has QKDNetSim module built into it. Finally, our simulation indicates the presence of an intruder by virtue of various network implementations within the quantum channel.     

Investigation on effects of system parameters on transmission depth in underwater wireless optical communication

Photonic Network Communications - Performance of underwater wireless optical communication (UWOC) with different vertical water channel conditions is experimentally analyzed. Experiment has been...     

Electrochemical energy storage applications of carbon nanotube supported heterogeneous metal sulfide electrodes

Electrochemical system centered on hierarchically carbon-based metal sulphide assemblies are of great fame for competent supercapacitors. Herein, the synthesis of a hierarchical CNT anchored MoS₂–Bi₂S₃ nanocomposite is reported. Attractively, a vertically grown Bi₂S₃ nanorods supported on MoS₂ nanosheets with carbon framework acts as a highly effective electrode in alkaline electrolyte. More interestingly, this hierarchical structure and synergetic upshot of CNT and composites provide excess coverage of active sites with improved conductivity and stability. Advancing from the physical and compositional properties of nanocomposites, the specific capacitance of MoS₂–Bi₂S₃@CNT composites is measured to be 1338 F/g at 10 mV/s, columbic efficiency of 99.5% over 10000 cycles and long-term stability (60% retention at 0.5 A g^?1 over 2000 cycles and 34.6% up to 10000 cycles). The success of this MoS₂–Bi₂S₃@CNT composite may be attributed to the structural advantages, admirable cyclic stability, and better capacitance retention for supercapacitor applications.     

Rapid synthesis of TiC/Ti3SiC2 composites by laser melting

TiC/Ti₃SiC₂ composites were successfully synthesized by laser melting (LM) technique using Ti–Si–TiC with a molar ratio of 1:1.2:2 as starting powders in the holding time range of 15–60 s. Phase content and microstructure of the synthesized samples were analyzed by X-ray diffraction (XRD) and scanning electron microscopy (SEM) and X-ray energy dispersive spectrometer (EDS). The synthesis was extremely fast because the migration of solute mainly depended on the convection mixing of molten pool caused by intense laser beam which was far faster than the solid state diffusion by traditional methods. The apparent density and hardness of the composites are higher than Ti₃SiC₂ because of the existence of TiC phase.