Emissions from distributed vs. centralized generation: The importance of system performance

Distributed generation (DG) offers a number of potential benefits, but questions remain about environmental performance. Air emissions from five key DG technologies; gas engines, diesel engines, gas turbines, micro-turbines, and fuel cells, were systematically compared with total energy supply systems based on centralized gas turbines (CCGT) and coal steam turbines plus distributed heating (DH) using gas-fired boilers. Based on emissions and operational factors from existing commercially marketed DG-CHP technologies, combined heat and power (CHP) applications are considered, which are remotely monitored and operated as base-load supply. Emissions results are characterized using heat-to-power ratios (HPRs), which concisely describe different types of energy demand under different applications or seasonal conditions. At an HPR of zero (i.e. the special case of electricity-only), CCGT with DH gives the lowest emissions portfolio, but at HPR values typical for buildings in the United States, efficiency advantages ensure gas-fired combustion DG-CHP technologies become broadly competitive across the range of key emissions. Fuel cell DG-CHP provides a very low emissions portfolio, but at a significant cost premium. At higher HPR values, emissions from heat supply can become a key issue, leading to the surprising finding that some combustion-based DG-CHP systems have lower total emissions than fuel cell-based systems. Based on these insights, the paper concludes with a discussion of streamlined yet rigorous regulatory approaches for DG-CHP technologies.     

Development of a small DMFC bipolar plate stack for portable applications

The direct methanol fuel cell (DMFC) is regarded as a promising candidate in portable electronic power applications. Bipolar plate stacks were systematically studied by controlling the operating conditions, and by adjusting the stack structure design parameters, to develop more commercial DMFCs. The findings indicate that the peak power of the stack is influenced more strongly by the flow rate of air than by that of the methanol solution. Notably, the stack performance remains constant even as the channel depth is decreased from 1.0 to 0.6 mm, without loss of the performance in each cell. Furthermore, the specific power density of the stack was increased greatly from ∼60 to ∼100 W l⁻¹ for stacks of 10 and 18 cells, respectively. The current status of the work indicates that the power output of an 18-cell short stack reaches 33 W in air at 70 °C. The outer dimensions of this 18-cell short stack are only 80 mm × 80 mm × 51 mm, which are suitable for practical applications in 10–20 W DMFC portable systems.     

Molecular imprinting strategy for solvent molecules and its application for QCM-based VOC vapor sensing

Cross-linked polymers made of methyl methacrylate (MMA) as a monomer and divinylbenzene (DVB) as a cross-linking agent were prepared in the presence of toluene or p-xylene as a solvent. The cross-linked polymer prepared in toluene tended to sorb toluene vapor preferably, while the cross-linked polymer prepared in p-xylene sorbed p-xylene vapor preferably. The observed molecular recognition ability can be explained on the bases of an imprinting effect by solvent molecules. Molecularly imprinted polymer (MIP) powders were blended with PMMA, and the blended films were coated on a piezoelectric quartz crystal with a view to preparing QCM-based VOC sensors. The imprint effect was clearly observed, even in these blended films. The response of the sensor towards toluene or p-xylene vapor was reversible; however, the response time was slow due to the existence of the matrix polymer around the MIP particles.     

Steam reforming of gasoline promoted by partial oxidation reaction on novel bimetallic Ni-based catalysts to generate hydrogen for fuel cell-powered automobile applications

Steam reforming of gasoline fuels combined with partial oxidation reaction on ZSM-5-supported Ni-based bimetallic catalysts and Al₂O₃-supported Ni-Re bimetallic catalysts with different Ni/Re ratios for hydrogen generation at a relatively lower reaction temperature was studied. The ZSM-5-supported Ni-Ce and Ni-Mo bimetallic catalysts exhibited a higher activity than the Ni/ZSM-5 catalyst for the oxidative reforming of gasoline. Steam reforming of gasoline to produce hydrogen was remarkably promoted by partial oxidation reaction by addition of molecular oxygen to the reaction system on ZSM-5-supported Ni-Ce catalyst. Al₂O₃-supported Ni-Re catalyst with suitable Ni/Re ratios exhibits unique high activity and sulfur tolerance because of the alloying of Ni with Re to form a new active sites for oxidative steam reforming of gasoline to generate hydrogen. The crystal structure of Al₂O₃-supported bimetallic Ni-Re catalyst and monometallic catalysts of Ni and Re were characterized by XRD method. Structured changes resulting from the alloying of Ni with Re were found.     

Stress concentration analysis of fibre-reinforced multilayered composites with pin-loaded holes

The problem of stress concentrations in the area of pin-loaded holes is of particular significance in the design of multilayered fibre-reinforced composite structures. For the purpose of simulating such problem zones in anisotropic multilayered composites, analytical methods offer decisive advantages since they, in comparison to numerical methods, allow weighting of influencing parameters and in this way permit a physical interpretation of complicated notch phenomena. At the Institut für Leichtbau und Kunststofftechnik (ILK) sophisticated analytical solution methods for the stress concentration problem in multilayered composites with pin-loaded holes were developed on the basis of layer-related solutions and have been confirmed in numerical calculations.     

Solution-chemistry analysis of ammonium bicarbonate consumption in rare-earth-element precipitation

A solution-chemistry analysis is applied to estimating the consumption of ammonium bicarbonate in the recovery of rare-earth (RE) elements from leachates of weathered clays. The theoretical analysis shows that a two-step process is needed for recovering RE from the leachates of the weathered clays by precipitation using ammonium bicarbonate. The first step is a precipitation at solution pH 5 to remove impurities such as Fe and Al. The second step is to precipitate RE by adjusting the solution pH above 8. The consumption of ammonium bicarbonate was found to depend on the concentration of RE elements and impurities in the leachates. The total amount of ammonium bicarbonate consumption for the entire process was determined experimentally, and the results showed an excellent agreement with that calculated based on solution-chemistry analysis. The decomposition of H₂CO₃ was identified as one of the main causes of ammonium bicarbonate overdose, accounting for up to 41 pct in comparison to 20 pct consumption for the removal of impurities. The amount of ammonium bicarbonate required in terms of the NH₄HCO₃: RE₂O₃ (RE oxides) molar ratio was found to be 4:1 for maximal RE recovery. An overall RE recovery around 90 pct was achieved with a product purity being about 90 pct.     

Fouling study of silicon oxide pores exposed to tap water

We report on the fouling of Focused Ion Beam (FIB)-fabricated silicon oxide nanopores after exposure to tap water for two weeks. Pore clogging was monitored by Scanning Electron Microscopy (SEM) on both bare silicon oxide and chemically functionalized nanopores. While fouling occurred on hydrophilic silicon oxide pore walls, the hydrophobic nature of alkane chains prevented clogging on the chemically functionalized pore walls. These results have implications for nanopore sensing platform design.     

The Cold Chain,one link in Canada’s food safety initiatives

The Cold Chain has always played an important role in food safety within the global market. The Canadian government has recognized it has an important role in the food continuum. In partnership with industry, national voluntary enhanced food safety systems, based on Codex Alimentarius (HACCP) principles, are being developed within Canada. These efforts will contribute towards food safety and will build confidence in foodstuffs grown, prepared and sold at all levels of trade and abroad.     

Research on better use of wood for sustainable development: Quantitative evaluation of good tactile warmth of wood

Wood is a prospective material against the problems of mineral resource shortage and global warming from the viewpoint of sustainable development. The continuous cycle of felling, planting and growing of trees is essential prerequisite for sustainability. The engineering evaluation of advantages of wood can increase its use more widely as a substitute for other industrial materials and save the finite mineral resources. The increase of wood use can support the continuous cycle for the sustainable forestry as an industry. This paper treats good tactile warmth of wood as one of its advantages. The relationship between contact surface temperature and thermal effusivity is derived from the theoretical analysis of governing heat transfer phenomenon on tactile warmth. Some knowledge on tactile warmth of wood is reviewed with these physical properties. The sensory tactile warmth of wood has a high and positive linear correlation with the logarithm of the contact surface temperature. The materials with lower thermal effusivity feel warmer than the ones with higher thermal effusivity. The relationship between contact surface temperature and thermal effusivity explains rationally why each wood has a large difference of tactile warmth in spite of their small difference of material properties. It also explains the reason why wood has good tactile warmth regardless of seasons against metals, which feel too hot in summer and too cold in winter to touch. The contact surface temperature and the thermal effusivity are proposed as engineering measures to evaluate the tactile warmth of wood and other materials.     

Performance parameters of an ejector-absorption heat transformer

Ejector-absorption heat transformers (EAHTs) are attractive for increasing a solar-pond's temperature and for recovering low-level waste-heat. Thermodynamic analysis of the performance of an EAHT is complicated due to the associated complex differential equations and simulation programs. This paper proposes the use of artificial neural-networks (ANNs) as a new approach to determine the performance parameters, as functions of only the working temperatures of the EAHT, which is used to increase the solar pond's temperature under various working conditions. Thus, this study is helpful in predicting the performance of an EAHT where the temperatures are known. Scaled conjugate gradient (SCG) and Levenberg–Marquardt (LM) learning algorithms and a logistic sigmoid transfer-function were used in the network. The best approach was investigated for performance parameters with developed software using various algorithms. The best statistical coefficients of multiple determinations (R²-values) equal 0.99995, 0.99997 and 0.99995 for the coefficient of performance (COP), exergetic coefficient of performance (ECOP) and circulation ratio (F), respectively obtained by the LM algorithm with seven neurons. In the comparison of performances, results obtained via analytic equations and by means of the ANN, the COP, ECOP and F for all working situations differ by less than 1.05%, 0.7% and 3.07%, respectively. These accuracies are acceptable in the design of the EAHT. The ANN approach greatly reduces the time required by design engineers to find the optimum solution. Apart from reducing the time required, it is possible to find solutions that make solar-energy applications more viable and thus more attractive to potential users. Also, this approach has the advantages of high computational speed, low cost for feasibility, rapid turn-around, which is especially important during iterative design phases, and ease of design by operators with little technical experience.