Preparation and capacitance performance of nitrided lithium titanate nanoarrays

Nitrided lithium titanate (N-Li₄Ti₅O₁₂) nanoarrays with nanowire and nanotube structures were designed as the electrode materials of lithium-ion supercapacitor for electrochemical energy storage. Two types of TiO₂ nanoarrays were used as the precursor which involved TiO₂ nanowire array prepared by hydrothermal process and TiO₂ nanotube array prepared by anodization process. Li₄Ti₅O₁₂ nanoarrays were formed through hydrothermal reaction or sonochemical reaction of TiO₂ nanoarrays with lithium hydroxide and then calcination treatment process. Finally, N-Li₄Ti₅O₁₂ nanoarrays were formed through nitriding treatment of Li₄Ti₅O₁₂ using ammonia as nitrogen source. The electroactive N-Li₄Ti₅O₁₂ nanowire array and nanotube array exhibited the specific capacitance of 607.2 F g⁻¹ and 814.4 F g⁻¹ at a current density of 1 A g⁻¹, respectively. The corresponding capacitance retention was determined to be 92.1% and 94.2% after 1000 cycles at high current density of 5 A g⁻¹. The corresponding capacitance still kept 182.9 and 352.1 F g⁻¹ at much higher current density of 20 A g⁻¹, presenting reasonable rate capability for N-Li₄Ti₅O₁₂ nanoarrays. The improved capacitance performance of N-Li₄Ti₅O₁₂ nanotube array was ascribed to the more amount of TiN and more accessible nanotube surface area, which contributed to the improved conductivity and fast diffusion of electrolyte ions on the surface of electrode. Both N-Li₄Ti₅O₁₂ nanowire array and nanotube array with well-aligned integrative structure exhibited an excellent cycling stability during continuous charge/discharge process. Well-designed N-Li₄Ti₅O₁₂ nanoarrays with high capacitance, good cycling stability and rate capability presented the promising application as feasible electrode materials of lithium-ion supercapacitors for the energy storage.     

Canada to move out of Kyoto agreement…

The Canadian government, under pressure from energy producers worried about the costs of the Kyoto climate change protocol, has given a clear sign that it might not ratify the Kyoto treaty.     

Hazard and operability (HAZOP) analysis. A literature review

Hazard and operability (HAZOP) methodology is a Process Hazard Analysis (PHA) technique used worldwide for studying not only the hazards of a system, but also its operability problems, by exploring the effects of any deviations from design conditions. Our paper is the first HAZOP review intended to gather HAZOP-related literature from books, guidelines, standards, major journals, and conference proceedings, with the purpose of classifying the research conducted over the years and define the HAZOP state-of-the-art.     

Hybrid TFET-MOSFET circuit: A solution to design soft-error resilient ultra-low power digital circuit

In this work, to increase the reliability of low power digital circuits in the presence of soft errors, the use of both III-V TFET- and III-V MOSFET-based gates is proposed. The hybridization exploits the facts that the transient currents generated by particle hits in TFET devices are smaller compared to those of the MOSFET-based devices while MOSFET-based gates are superior in terms of electrical masking of soft errors. In this approach, the circuit is basically implemented using InAs TFET devices to reduce the power and energy consumption while gates that can propagate generated soft errors are implemented using InAs MOSFET devices. The decision about replacing a subset of TFET-based gates by their corresponding MOSFET-based gates is made through a heuristic algorithm. Furthermore, by exploiting advantages of TFETs and MOSFETs, a hybrid TFET-MOSFET soft-error resilient and low power master-slave flip-flop is introduced. To assess the efficacy of the proposed approach, the proposed hybridization algorithm is applied to some sequential circuits of ISCAS’89 benchmark package. Simulation results show that the soft error rate of the TFET-MOSFET-based circuits due to particle hits are up to 90% smaller than that of the purely TFET-based circuits. Furthermore, energy and leakage power consumptions of the proposed hybrid circuits are up to 79% and 70%, respectively, smaller than those of the MOSFET-only designs.     

Soft switching based on analysis of transient and steady-state characteristics: Application to a single-ended high-frequency inverter

A single-ended resonant-type high-frequency inverter using a static induction transistor (SIT) described in this paper can be performed as a zero current switching (ZCS) operation without dc reactor. The SIT high-frequency inverter is a low-cost one which has no transformer and it would be developed for a high-intensity ultrasonic power supply and dc-dc converter. The circuit operation regions, not only ZCS but also ZCS-ZVS (zero current switching and zero voltage switching), were elucidated in the normalized plane. The characteristics of the inverter including the power control by frequency regulation were discussed. Furthermore, the switching characteristics in the transient-state were investigated. These characteristics were substantiated on the basis of the numerical analysis and experimental results.     

Bioleaching and chemical leaching as an integrated process in the zinc industry

This work sought to integrate bioleaching and chemical leaching as a cost-effective process to treat zinc sulphides. The continuous bioleaching of a sphalerite concentrate, assaying 51.4% Zn, 1.9% Pb, 31.8% S and 9.0% Fe with mesophile iron and sulphur-oxidizing bacteria followed by chemical leaching of the bioleaching residue were assessed. In the bioleaching step, the first reactor was used to produce Fe(III) concentrations as high as 20 g/L. This solution was fed to the subsequent bioleaching reactors to oxidize sphalerite. It was possible to achieve 30% zinc extraction for 70 h residence time. In chemical leaching experiments, carried out with the residue of the bioleaching step, the effects Fe_total and acidity on zinc extraction were studied. It was noticed that Fe(III) concentrations over 12 g/L did not affect zinc recoveries. Furthermore, the higher the acidity, the larger the zinc recovery, for experiments carried out up to 181 g/L sulphuric acid. The results have demonstrated that it is possible to devise a new process capable of achieving 96% zinc extraction, similarly to the conventional roasting–leaching–electrolysis process.