一种车载自组织网络路况信息的数据信任模型

动态寻路是解决城市交通拥堵的重要手段。在动态寻路中,一些车辆产生和转发路况信息,使其他车辆能够避开拥堵路段。但一般车载自组织网络寻路算法缺乏验证路况信息的真实性的措施,导致恶意车辆能轻易篡改路况信息,误导其他车辆选择错误路线。提出了一种路况信息鉴别模型,该模型将基于数据的信任模型应用到路况信息真伪的鉴别中,并在一般投票算法的基础上利用D-S理论增加不确定情况下的鲁棒性。仿真实验表明,该算法在不增加额外信息交互的前提下,有效规避了恶意伪造信息,改进了车辆的行程时间。     

特定事件微博与新闻报道话题对比研究

该文描述了基于特定事件的新闻报道和微博在话题层面的对比研究。首先利用LDA话题模型抽取两种媒体上关于特定事件的话题,然后提出了话题关注度、差异度、演化度的定义和计算公式,改进了不同媒体话题差异度的计算方法,最后,选取四个不同种类的事件,进行实验对比与分析,结果显示,关于同一事件,1)微博上评论性话题较多,话题关注度值比较接近;新闻报道上事实性话题较多,话题关注度值差异较大;2)微博与新闻报道对评论性话题词汇差异度大,事实性话题词汇差异度小;3)微博上评论性话题持续时间较长,内容变化较少;新闻报道上事实性话题持续时间较长,内容变化较少。     

Preparation and characterization of a series of polyamides with long alkylene segments: Nylons 12 20, 10 20,s 20,6 20, 4 20 and 2 20

Summary A series of nylons with long alkylene segments between amide groups were newly prepared by step-heating melt-polycondensation of 1,lS-octadecanedicarboxylic acid with various diamines. The prepared polyamides were characterized carefully. The results show that many properties of the prepared nylons change regularly with the length of methylene segments in diamines. In addition, nylon 2 20 has a relatively low molecular weight and much different melting and thermal decomposition behaviors in comparison with other nylons. Received: 21 June 2OO2/Revised version: 18 September 2002/ Accepted: 18 September 2002 Correspondence to Deyue Yan E-mail: dyyan@mail.sjtu.edu.cn Tel: 0086-21-54742863 Fax: 0086-21-54741297     

局部表面改性紫铜方柱阵列池沸腾传热特性和机理

以局部表面改性的紫铜直方柱和梯度方柱阵列为研究对象，实验研究了表面润湿性、表面形貌和表面活性剂对池沸腾换热性能和气泡生长特性的影响。实验工质为去离子水，浓度分别为100、200、400、800 mg·L^-1的异丙醇溶液和正庚醇溶液。实验结果表明：方柱阵列表面镀银之后润湿性变差，表面产生的气泡数量减少。向去离子水中添加异丙醇或正庚醇后，在热通量为66.1～202 kW·m^-2时，气泡脱离直径变小、数目减少，而当热通量增至413 kW·m^-2时，活性剂能够有效阻碍气泡合并，故池沸腾传热系数随着浓度增加先减小后增大。上下层宽分别0.5 mm和1 mm、间距为2 mm的梯度方柱阵列结构有助于气泡的合并，但由于促进了固体表面气膜的形成，从而降低了沸腾换热性能。     

A study on capacity fading of lithium-ion battery with manganese spinel positive electrode during cycling

The capacity fading mechanism of lithium-ion cell was studied by disassembling the charge-discharged cells and analyzing their electrodes using scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS), etc. Cu ion dissolved from current collector of anode and Mn ion dissolved from LiMn₂O₄ spinel (cathode) were all existing in solid electrolyte interface (SEI) layer on carbon anode as Cu₂O and MnO or MnO₂, respectively. These depositions of Cu and Mn oxides did not uniformly deposited on the anode side, and most of them were detected on the carbon surface nearby to the separator side. The SEI layer is hard and about 0.3 μm in thickness. Furthermore, the cycling performance of the cells can be improved by adding 1,2,3-benzotrazole (a corrosion inhibitor of Cu) before assembling the cell, it then coordinates strongly with Cu ions into the electrolyte. From the results, it is obvious that the existing of Cu oxide as well as Mn oxide in the SEI layer, which blocks the normal intercalation of the lithium ions, is one of the factors for the capacity fading of the cells.     

Synthesis, characterization and thermal properties of hexaarmed star-shaped poly(ε-caprolactone)-b-poly(d,l-lactide-co-glycolide) initiated with hydroxyl-terminated cyclotriphosphazene

Hexakis[p-(hydroxymethyl)phenoxy]cyclotriphosphazene was prepared by the reaction of hexachlorocycltriphosphaneze with the sodium salt of 4-hydroxybenzaldehyde and subsequent reduction of aldehyde groups to alcohol groups by using sodium borohydride. Hexaarmed star-shaped hydroxyl-terminated poly(ε-caprolactone) (PCL) were successfully synthesized via ring-opening polymerization of ε-caprolactone (CL) with the above hydroxyl-terminated cyclotriphosphazene initiator and stannous octoate catalyst in bulk. The number-average molecular weight of PCL linearly increased with the molar ratio of monomer to initiator. The star-shaped PCL with hydroxy end groups could be used as a macroinitiator for block copolymerization with d,l-lactide (d,l-LA) and glycolide (GA) using stannous octoate catalyst. IR, ¹H NMR and GPC analysis showed the star-block copolymers were successfully synthesized and the molecular weights and the unit composition of the star-shaped block copolymers were controlled by the molar ratios of d,l-LA and GA monomers to CL. The copolymer presented a two-phase structure, namely, PCL crystalline and d,l-LAGA amorphous domains, which made the copolymer different from linear PCL and star-shaped PCL in crystallinity and thermal behaviors.     

Construction of two-dimensional supramolecular structure containing water tetramer and octamer

The complex [Cd₂(phen)₄(p-phth)(H₂O)₂](p-phth) · 10H₂O (1) has been synthesized by the reaction Cd(NO₃)₂ with phen and p-phth (where phen = 1,10-phenanthroline, p-phth = p-phthalic acid) in a solution of ethanol and distilled water. The crystal structure was characterized by X-ray single-crystal diffraction and infrared spectrum. In 1, a novel 2D supramolecular structure was formed, containing water octamer and tetramer.     

Properties of lightweight expanded polystyrene concrete reinforced with steel fiber

Expanded polystyrene (EPS) concrete is a lightweight, low strength material with good energy-absorbing characteristics. However, due to the light weight of EPS beads and their hydrophobic surface, EPS concrete is prone to segregation during casting, which results in poor workability and lower strength. In this study, a premix method similar to the ‘sand-wrapping’ technique was utilized to make EPS concrete. Its mechanical properties were investigated as well. The research showed that EPS concrete with a density of 800-1800 kg/m³ and a compressive strength of 10-25 MPa can be made by partially replacing coarse and fine aggregate by EPS beads. Fine silica fume greatly improved the bond between the EPS beads and cement paste and increased the compressive strength of EPS concrete. In addition, adding steel fiber significantly improved the drying shrinkage.     

Modeling bond strength of corroded reinforcement without stirrups

Deterioration of bond strength between concrete and reinforcement is of great importance in studying the strength of structural members with corroded reinforcements. A simple analytical model is proposed to demonstrate the effect of corrosion of reinforcing bar on reduction of bond strength. The corrosion pressure due to expansive action of corrosion products before and after corrosion cracking is firstly estimated. Then, reduction of bar confinement caused by cover cracking, change of friction coefficient between the steel and the concrete, and reduction of the friction force on the bearing face as well as deterioration of the ribs of the deformed bars due to steel corrosion are considered in calculating the mechanical interactions between reinforcing bar and concrete. As a result, the bond strength of corroded bars is calculated. The theoretical results are compared with the experimental results and agree with those results well.