多孔网幕泡破压力预测模型的建立及实验验证

金属多孔网幕具有比表面积大、物理稳定性好等诸多优点,广泛应用于推进剂在轨气液分离及相变传热等领域。泡破压力是衡量其相分离性能的关键参数,可根据多孔介质的有效泡破孔径确定。然而多孔网幕的孔隙结构极其复杂,泡破孔径计算仍未有通用且高效的方法。建立了一种基于三维孔隙结构的多孔网幕泡破压力的通用型解析模型。该模型仅依赖于多孔网幕的几何结构参数,无须实验即可有效预测多孔网幕的泡破压力。模型预测结果与本文实验及文献实验中不同网幕规格、低温及常温工质数据吻合良好,平均误差仅为8%,表明该解析模型具有普适性和准确性,可为基于多孔网幕的液体获取装置的设计与性能预测提供参考。     

自适应SA-PSO优化的威布尔混合分布参数估计方法及应用

针对采用传统参数估计方法得到的模型拟合误差较大的问题,建立多重威布尔混合分布参数估计的非线性最小二乘模型,并提出基于模拟退火（SA）思想的自适应粒子群（PSO）算法进行求解。在PSO算法优化过程中,采用自适应方法调整惯性权重和加速因子,加快其收敛速度;引入模拟退火机制,根据Metropolis准则确定最优粒子的取舍,改善其全局搜索能力。将该方法应用到某型柴油机喷油器失效分布的参数估计中,并与图解法、基于Levenberg-Marquardt的非线性最小二乘法、标准PSO算法、自适应PSO算法求解的结果进行比较,分析所提方法的优化性能及精度。结果表明,该方法能够有效提高多重威布尔混合分布模型参数估计的精度和效率。     

Methods for determining operation life and reactivity depletion for space reactors with fast energy spectra

Space reactors with fast neutron energy spectrums are preferred for their compactness and high fission power density, but require a high fissile inventory. The operation life estimates of these reactors are important to mission planning. This paper examines a number of fuel depletion and neutronics code packages for determining the operation lives of two space reactors with hard fast neutron energy spectra. These are: the lithium-cooled, Sectored, Compact Reactor (SCoRe-S₁₁), and the submersion subcritical safe space (S^4) reactor, cooled with a He–Xe binary gas mixture (40 g/mol). This work investigated the code packages of Monteburns 2.0, MCNPX 2.6C and TRITON and validated their prediction with fuel depletion data for a PWR fuel bundle, with satisfactory results. The operation life predictions of the two space reactors using these code packages are compared with those calculated using a simplified method that couples MCNP5 to a burnup analysis model using the Simulink^® platform. This method considers only the 10 most probable low-Z and high-Z elements of the fission yield peaks plus ¹⁴⁹Sm, and neglects the depletion of fission products due to capture and radioactive decay. The simplified method requires significantly shorter running time and its predictions of the operation lives for the two space reactors are within 0.29–12.5% of those obtained using Monteburns 2.0 and MCNPX 2.6C code packages. This method, however, is not recommended for operation life predictions for space or commercial reactors with thermal neutron spectrums.     

Effects of environment on dry sliding wear behavior of silver–copper based composites containing tungsten disulfide

Silver based composites containing different amounts of WS₂ were prepared by hot-pressing method and their tribological behaviors were investigated against coin silver under humid air, dry nitrogen and vacuum on a ball-on-disk tester with normal load of 5 N. The components of composites, microstructure of debris and worn surface were characterized using XRD SEM, EDS and XPS. It is demonstrated that environmental conditions significantly affect the tribological behavior of silver based composites. The friction coefficient is the highest in humid air, and the lowest in dry nitrogen. It is found that the friction and wear behavior of the composites are strongly depended on the characteristics of the lubrication film forming in different operating environments, such as thickness and composition. In addition, it is indicated that the dominant wear mechanisms of silver based composites are abrasive wear and delamination under different conditions.     

帆板驱动微振动对卫星的影响与对策

基于帆板驱动机构精确建模，对帆板及其驱动带来的影响进行分析；在分析帆板驱动特性的基础上，给出了微振动测试数据及其分析结果；并以某卫星为例给出了帆板驱动控制时微振动对姿态的影响，提出了频率约束和振动主动抑制控制相结合的解决措施及验证结果。     

Effects of shell thickness of polystyrene‐encapsulated Mg(OH)2 on flammability and rheological properties of high‐impact polystyrene composites

Polystyrene (PS)‐encapsulated magnesium hydroxide (Mg(OH)₂) particles with various shell thicknesses were successfully prepared using a method of in situ polymerization of styrene in a high‐speed mixer. High‐impact polystyrene (HIPS)/Mg(OH)₂ composites were prepared by melt blending. They were characterized using cone calorimetry, horizontal burning rate, rheology and scanning electron microscopy in order to investigate the effects of the shell thickness of the PS‐encapsulated Mg(OH)₂ on the flame retardancy and rheological properties of the resulting composites. Rheological tests showed that the composites containing encapsulated Mg(OH)₂ had a stronger solid‐like response at low frequency than that of the sample containing untreated Mg(OH)₂. However, with PS/Mg(OH)₂ ratio increasing up to 6.0 wt% and above, the dynamic viscosity, loss modulus and storage modulus of HIPS/Mg(OH)₂ composites decreased. The optimum PS/Mg(OH)₂ ratio, 4.5 wt%, was determined using a new ‘crossover point’ rheological method. The combustion tests showed that compared to the composites containing untreated Mg(OH)₂, the fire retardancy of the composites containing PS‐encapsulated Mg(OH)₂ was improved significantly. Also, there appeared to be a critical PS/Mg(OH)₂ ratio, namely 6.0 wt%, for optimum flame‐retarding properties. However with the continuous increase of PS/Mg(OH)₂ ratio, the fire resistance of the composites declined somewhat, which can be explained by acceleration of combustion of the composites due to the introduction of free PS chains of low molecular weight on the surface of Mg(OH)₂. Copyright © 2007 Society of Chemical Industry     

摩擦对电动直线负载模拟器的影响及其抑制研究

为抑制摩擦非线性因素对电动直线负载模拟器（ELLS）的影响,采用仿真与实验结合的方法分析摩擦对ELLS的影响。利用遗传算法对系统中的摩擦模型进行辨识,并得出了系统摩擦力与速度的关系;提出了一种摩擦前馈加变增益PID的混合控制方法,摩擦前馈用于消除摩擦对系统的影响,变增益PID用于进一步抑制系统在低速时的相位滞后;进行了对比仿真与实验。仿真分析与实验结果表明：与传统PID控制相比,采用摩擦前馈加变增益PID控制的ELLS加载波形畸变被抑制、加载误差与相位滞后均明显减少;所提出控制方法能够较好地抑制摩擦对ELLS的影响,提高加载精度。     

砂浆对固结磨具研磨垫研磨SiC工件的影响

为高效、稳定加工SiC工件,采用碳化硅砂浆辅助亲水性固结磨具研磨垫精研的方法,实验比较砂浆辅助固结磨具研磨垫研磨与传统固结磨具研磨垫研磨的差异,并研究砂浆中碳化硅的颗粒尺寸和质量分数对SiC工件精研去除率和表面形貌的影响。通过测算研磨垫的溶胀率和磨损率,探索碳化硅砂浆的作用机制。结果表明:在砂浆中添加颗粒尺寸为3~5 μm、质量分数为3%的SiC时,精研过程的平均材料去除率为1.424 6 μm/min,工件表面粗糙度R_a为84.6 nm;而没有砂浆辅助精研时,材料去除率为0.040 0 μm/min,表面粗糙度R_a为61.4 nm。碳化硅砂浆的加入能有效提高亲水性固结磨具研磨垫的自修整能力,其自修整能力随砂浆中碳化硅的尺寸和质量分数增大而增强,材料的去除率提高,工件表面质量略降。      

模拟海洋大气环境下铝合金表面锌黄环氧底漆/丙烯酸聚氨酯面漆涂层体系失效过程研究

目的研究5A06型铝基材所使用的锌黄环氧底漆/丙烯酸聚氨酯面漆涂层体系的失效过程。方法设计"紫外/冷凝3 d+中性盐雾3 d+低温暴露1 d"为一个周期的实验室循环加速试验,采用交流阻抗谱法,结合光泽度、色差值、红外光谱等数据,研究涂层体系性能。结果循环加速试验进行到16周,该过程中面漆的失光率、色差值上升,达到轻微失光等级和轻微变色等级。面漆的表面形貌及涂层的低频阻抗发生明显变化,第12周时在光学显微镜下明显可见微小鼓泡,涂层0.1 Hz阻抗保持在109W·cm~2以上,但此后鼓泡数量增加,部分鼓泡破损,颜填料流出;第14周时,0.1 Hz阻抗下降到108W·cm~2,此后鼓泡数量进一步增加,部分鼓泡处面漆脱落;第16周时,0.1 Hz阻抗下降到约为107W·cm~2。结论丙烯酸聚氨酯面漆树脂基体特征官能团、聚合物链发生断裂,面漆的完整性遭到破坏,这可能与紫外线照射相关。这将加速涂层中腐蚀性介质(如水、氧和侵蚀性氯离子)渗透,促进涂层的失效。     

Crystallization,melting behavior,and wettability of poly(ε‐caprolactone) and poly(ε‐caprolactone)/ poly(N‐vinylpyrrolidone) blends

Both wettability and crystallizability control poly(ε‐caprolactone)'s (PCL) further applications as biomaterial. The wettability is an important property that is governed by both chemical composition and surface structure. In this study, we prepared the PCL/poly(N‐vinylpyrrolidone) (PVP) blends via successive in situ polymerization steps aiming for improving the wettability and decreasing crystallizability of PCL. The isothermal crystallization of PCL/PVP at different PVP concentrations was carried out. The equilibrium melting point (T), crystallization rate, and the melting behavior after isothermal crystallization were investigated using differential scanning calorimetry (DSC). The Avrami equation was used to fit the isothermal crystallization. The DSC results showed that PVP had restraining effect on the crystallizability of PCL, and the crystallization rate of PCL decreased clearly with the increase of PVP content in the blends. The X‐ray diffraction analysis (WAXD) results agreed with that. Water absorptivity and contact angle tests showed that the hydrophilic properties were improved with the increasing content of PVP in blends. The coefficient for the water diffusion into PCL/PVP blends showed to be non‐Fickian in character. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010