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111.
112.
高锌粉含量的单组分环氧富锌底漆的研制 总被引:2,自引:0,他引:2
以自制的改性环氧树脂为基料,锌粉为防锈颜料,制备出干膜中锌粉含量达96%以上的单组分环氧富锌底漆。同时考察了影响漆膜防腐蚀性能和涂料贮存稳定性的因素。实验表明:锌粉的含量在95%~97%时,漆膜的防腐蚀效果最好,经过1 000 h的耐盐雾试验后,漆膜保持完好;采用0.2%有机膨润土和1%聚酰胺蜡搭配使用,有效地解决了单组分环氧富锌底漆中锌粉沉降结块的问题,根据实验结果得到最佳单组分环氧富锌底漆配方,同国外同类型的产品相比具有更好的性价比。漆膜性能优异,VOC含量较低,环保性能好。 相似文献
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M.M. Rashad M.M. Hessien E.A. Abdel-Aal K. El-Barawy R.K. Singh 《Powder Technology》2011,205(1-3):149-154
Silica nanoparticles have been synthesized from silica fume using alkali dissolution–precipitation process. The dissolution efficiency of 99% at a temperature of 80 °C and a time of 20 min was achieved. Sodium silicate solution was obtained by dissolving the fume with NaOH solution. Then, silica nanoparticles were precipitated using sulfuric acid. Silica nanoparticles (175 nm) were achieved using 12% sulfuric acid at pH 7 and 200 ppm sodium dodecyl sulfate (SDS). The silica morphologies appeared as a spherical shape with narrow particle size distribution. The silica samples were used for the formulation and testing of chemical mechanical polishing (CMP) slurries. The morphology of the polished wafer surface and its roughness were examined by atomic force microscope (AFM).The results indicated that the surface roughness was greatly improved after application of CMP. It was found that the surface roughness of the polished wafer is 0.226 nm at an applied pressure of 7 psi. The removal rate was found to be 1200 Å. These values confirm the quality of polished wafers. 相似文献
116.
为了解济南市市场中短链氯化石蜡(C10-13,short-chain chlorinated paraffins,SCCPs)与中链氯化石蜡(C14-17,medium-chain chlorinated paraffins,MCCPs)在食品中的分布现状与摄入风险,于2020年在济南市采集了82种不同类别食品样品,采... 相似文献
117.
针对协同过滤算法推荐效果依赖于相似度度量方法的问题,提出了一种基于项目层次结构相似度的推荐算法REHIS(recommendation hierarchical similarity)。首先利用关联规则挖掘和KNN(K nearest neighbor)算法完善项目层次结构,然后利用TopK算法计算项目之间的相似度,最后利用基于项目的协同过滤算法框架预测用户评分。为解决协同过滤算法扩展性差的问题,还把TopK算法推广到余弦距离和皮尔逊相关系数等常见的相似度度量方法。实验结果表明,与传统的协同过滤算法相比,REHIS能够获得更优的均方根误差,TopK算法可以减少最近邻项目的查找时间。 相似文献
118.
Meng Shen Wenru Li Ming-Yu Li Huan Liu Jianmei Xu Shiyong Qiu Guangzu Zhang Zixiao Lu Honglang Li Shenglin Jiang 《Journal of the European Ceramic Society》2019,39(5):1810-1818
Pyroelectrics are attracting increasing attention because they enable pyroelectric generators to extract energy from low-gradient-temperature heat for portable electronic devices. High pyroelectric coefficient around room temperature is essential for high-performance energy harvesters, which, unfortunately, is only commonly achieved in lead-based ferroelectrics. Herein we report a high room temperature pyroelectric response of 27.2 × 10?4 C m-2 K-1 in 0.94(Bi0.5Na0.5)TiO3-0.06Ba(Ti0.75Zr0.25)O3 lead-free ceramics by modulating the Zr4+/Ti4+ ratio to tune the ferroelectric-relaxor antiferroelectric-like phase transition point to around ambient temperature, whose pyroelectric response is one order of magnitude higher than that of the sample without Zr and even comparable to those of lead-containing pyroelectrics. The theoretical analysis revealed that introduced Zr4+ could incorporate into the TiO6 octahedral lattices and break the long-range translational symmetry of BaTiO3 lattices, resulting in the reduction of B-site ion displacement activation energy and transition point of ferroelectric-relaxor antiferroelectric-like phase, giving rise to a pronounced room-temperature pyroelectric effect in BNT-BZT. 相似文献
119.
《Carbon》2015
We describe a preparation of sulfur-doped mesoporous amorphous carbon (SMAC) from a commercially available alkyl surfactant sulfonate anion-intercalated NiAl-layered double hydroxide precursor via thermal decomposition and subsequent acid leaching. The resultant amorphous carbon is endowed with the integrated advantage of featuring high reversible capacity and long cycling stability: intrinsic doping of sulfur, large specific area, and broad mesopore size distribution. Electrochemical evaluation shows that the SMAC electrode exhibits highly enhanced electrochemical performances, compared with the electrode of non-doped mesoporous and amorphous carbon prepared by using a different surfactant (sodium laurate). A high reversible capacity of 958 mA h g−1 is achieved for the SMAC electrode after 110 cycles at 200 mA g−1, and especially a superlong cycle life with a reversible capacity of 579 mA h g−1 after 970 cycles at 500 mA g−1. Moreover, the SMAC electrode can facilitate the reversible insertion/extraction of Na ion, owing to the proper specific area and mesopore size distribution, as well as the improved electronic conductivity resulted from doping of sulfur. 相似文献
120.
《Ceramics International》2015,41(4):5232-5238
Y2O3 stabilized HfO2 ceramics with 5 mol% and 8 mol% Y2O3, respectively, were successfully fabricated by pressureless sintering at 1600 °C for 1 h. The phase distribution and transformation, microstructure, and relative density were investigated for Y2O3 stabilized HfO2 ceramics. Cubic phase was observed in the Y2O3 stabilized hafnium dioxide while pure HfO2 showed monoclinical phase only. The SEM images of fractured surface indicated two kinds of structures existed in modified HfO2, the solid solution region and uniform polygon grains, and some holes caused by Kirkendall effect. Refractoriness test showed that high temperature volumetric stability of the material can be effectively enhanced by adding Y2O3 into HfO2. 相似文献