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41.
42.
Here various approaches to understanding the complex relationship among the local atomic arrangements, the distribution of charge/holes and the superconductivity characteristics are discussed for a variety of multi-layered copper-oxide superconductors. Regarding the structural parameters, i.e. bond lengths and angles, no single parameter is revealed to control the superconductivity characteristics alone. As a matter of fact, superconductivity properties are found to be correlated with the whole delicately balanced fine-structure that is described by a set of multiple parameters: it is shown that T
c and Hirr are enhanced in somewhat opposite ways. Expressing the delicately balanced fine-structure through the charge/hole distribution, it is concluded that the more homogeneously distributed the charge carriers are the more enhanced is the Hirr characteristics, while the opposite is likely to apply to the T
c value. 相似文献
43.
A Skeleton-based Approach for Detection of Perceptually Salient Features on Polygonal Surfaces 总被引:1,自引:0,他引:1
The paper presents a skeleton‐based approach for robust detection of perceptually salient shape features. Given ashape approximated by a polygonal surface, its skeleton is extracted using a three‐dimensional Voronoi diagramtechnique proposed recently by Amenta et al. [ 3 ]. Shape creases, ridges and ravines, are detected as curvescorresponding to skeletal edges. Salient shape regions are extracted via skeleton decomposition into patches.The approach explores the singularity theory for ridge and ravine detection, combines several filtering methodsfor skeleton denoising and for selecting perceptually important ridges and ravines, and uses a topological analysisof the skeleton for detection of salient shape regions. ACM CSS: I.3.5 Computational Geometry and Object Modeling 相似文献
44.
《Diamond and Related Materials》2007,16(9):1765-1769
We have examined the possibility of synthesis of 12C-enriched diamond single crystal by a conventional temperature gradient method at high pressure and high temperature using a starting material of a carbon powder source prepared via pyrolysis of 12C-enriched methane. 12C-enriched diamond single crystal (about 3 mm in diameter) was successfully grown at 1430 °C, 6.1 GPa using a 12C-enriched pyrolytic carbon source prepared from 12C-enriched methane (1 to 5 Torr) at 1800 °C. Thermal conductivity of the 12C-enriched diamond single crystal was measured by a modified specimen arrangement of a cut-bar steady-state conduction technique. The result showed that thermal conductivity of the 12C-enriched diamond single crystal (99.97% 12C) was 29.9 W/cm-K, and it was found to be 32% higher than that of similarly synthesized naturally abundant diamond single crystal (99.0% 12C), indicating the isotope effect of diamond. 相似文献
45.
A new type of arc plasma reactor with 12-phase alternating current (AC) discharge for synthesis of carbon nanotubes (CNTs) is proposed. A couple of six discharge electrodes by which have mutually electrical connection between them to enlarge the high-temperature regions in the reactor are arranged to three-dimensional locations. A new method of CNTs fabrication by this reactor, which accomplishes to enlarge the suitable growth region in high purity and at high yield, was developed. 相似文献
46.
《Journal of Parallel and Distributed Computing》2006,66(2):307-321
During the past few years, multimedia traffic with quality of service (QoS) requirements has become of widespread use. Media servers are usually built as clusters of workstations connected by a high-performance interconnection network. However, these high-performance networks do not usually offer differentiated support for multimedia traffic. The MultiMedia Router (MMR) is a proposal to address the QoS issue in cluster networks within a compact architecture, while also integrating conventional best-effort traffic. This paper describes the main architectural features of the MMR, such as the use of a hybrid switching technique, credit-based flow control, or small input buffers. Also, the main design parameters are tuned by means of simulation. It can be seen how proper differentiation among the different traffic classes is achieved, while retaining a compact design with small buffers. 相似文献
47.
Swelling degrees of poly(N-vinyl-2-pyrrolidone) (PVP) gel were measured in aqueous salt solutions and in water/organic solvent mixtures to find marked ion- and solvent-specificities. In order to investigate any correlation of those specificities with hydration or solvation of PVP, IR spectra band of the CO group was monitored by means of ATR method both for PVP gel and the relevant solution systems. Dependence of the peak frequency on the swelling ratio suggested that hydration of PVP carbonyl group in deswollen gel systems is different from that in the corresponding solution systems. In the solution systems, PVP carbonyl band showed a high-wavenumber shift for deswollen systems, which can be well correlated with changes in water proton charge through ionic hydration and with Gutmann's acceptor number of organic solvents. In the deswollen gel systems, the CO band showed a low-wavenumber shift, suggesting a strong hydration or doubly hydrated state. This unexpected behavior was interpreted by assuming an intermolecular hydrogen bond of two carbonyl groups intermediated by water molecules. 相似文献
48.
Phase-separated domains prepared in the two-phase region were dissolved at a temperature in the single-phase region, and their dissolution dynamics was studied by using the time-resolved light scattering (TRLS) technique and a scanning electron microscope (SEM). The time tps of preparation of domains was chosen to be long enough for phase separation to proceed into the late stage. The scattered light intensity at small wavenumbers increased before it attenuated. As tps increased, the increase at smaller wavenumbers became more significant and the peak intensity decreased only slightly with dissolution time. The characteristic wavenumber qm evaluated from TRLS and SEM followed the power-law relation qmt−0.3. 相似文献
49.
Takakazu Yamamoto Kouichi ShiraishiMahmut Abla Isao YamaguchiL.“Bert” Groenendaal 《Polymer》2002,43(3):711-719
Neutral and non-doped poly(3,4-ethylenedioxythiophene), PEDOTh(Ni), and its hexyl derivative, PEDOTh-C6(Ni), have been prepared by organometallic dehalogenation polycondensation of 2,5-dichloro-3,4-ethylenedioxythiophene and its hexyl derivative with a zerovalent nickel complex. PEDOTh-C6(Ni) was soluble in organic solvents and 1H NMR data indicated that it had an Mn of 11,000. MALDI-TOF mass analysis of PEDOTh(Ni) gave Mn and Mw of about 1700 and 2400, respectively. PEDOTh-C6(Ni) showed a UV-Vis absorption peak at 546 nm in CHCl3. Electrochemical oxidation of PEDOTh-C6(Ni) started at about −0.40 V vs Ag+/Ag and gave a peak at 0.20 V vs Ag+/Ag. Chemical and electrochemical oxidation (or p-doping) of PEDOTh-C6(Ni), both in solutions and in a solid state, led to weakening of the original π-π∗ peaks and rise of new peak(s) in a region of 800-1500 nm. The p-doping of PEDOTh-C6(Ni) caused not only a decrease in the intensity of 1H NMR signals of the bridging ethylene hydrogens but also a decrease in that of the hexyl side chain, suggesting a strong interaction of the p-dopant with the side chain. NMR data of poly(3-methoxythiophene-2,5-diyl) also supported an assumption that p-doping brings about a severe change in electronic state of the substituent attached to the polythiophene main chain. PEDOTh(Ni) had a density of 1.71 g cm−3; the molecular packing mode of PEDOTh(Ni) is discussed based on the density of the polymer and its XRD data. 相似文献
50.
《Diamond and Related Materials》2007,16(10):1806-1812
We report about the electron paramagnetic resonance and nuclear magnetic resonance signals in bulk and thin film-type ultrananocrystalline diamond with and without nitrogen. The localization and nature of defects for powder and compact film samples were analyzed. From the analysis of spin–lattice and spin–spin relaxation times, we have found that spin states sit in sp2 enriched region belonging to the grain boundaries. 相似文献