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51.
Methane was pulsed over pure CuO and NiO as well as Cu/La2O3 and Ni/La2O3 catalysts at 600° C. Results indicate that the mechanisms for methane activation over copper and nickel are quite different. Over CuO, methane is converted to CO2 and H2O, most likely via the combustion mechanism; whereas metallic copper does not activate methane. Over NiO in the presence of metallic nickel sites, methane activation follows the pyrolysis mechanism to give CO, CO2, H2 and H2O. Similar results were obtained over the Cu/La2O3 and Ni/La2O3 catalysts. XRD investigations indicate that copper and nickel existed as CuLa2O4 and LaNiO3 respectively in the La2O3-supported catalysts. The effect of La2O3 on the activation of methane is discussed. 相似文献
52.
Hansan Liu 《Electrochimica acta》2004,49(7):1151-1159
Multiple substitution compounds with the formula LiNi0.8−yTiyCo0.2O2 (0≤y≤0.1) were synthesized by sol-gel method using citric acid as a chelating agent. The effects of titanium substitution on the structural, electrochemical and thermal properties of the cathode materials are investigated. A solid solution phase (R-3m) is observed in the range of 0≤y≤0.1 for the titanium-doped materials. X-ray photoelectron spectroscopy (XPS) shows that there are Ni3+, Ni2+, Co3+, Co2+ and Ti4+ five transition metal ions in titanium-doped materials. Rietveld refinement of X-ray diffraction (XRD) patterns indicates that titanium substitution changes the materials’ structure with different cationic distribution. An increase of the Ni/Co amount in the 3a Li site is found with the addition of titanium amount. An improved cycling performance is observed for titanium-doped cathode materials, which is interpreted to a significant suppression of phase transitions and lattice changes during cycling. The thermal stability of titanium-doped materials is also improved, which can be attributed to its lower oxidation ability and enhanced structural stability at delithiated state. 相似文献
53.
Processing of a Silicon-Carbide-Whisker-Reinforced Glass-Ceramic Composite by Microwave Heating 总被引:1,自引:0,他引:1
Lifu Chen Cristina Leonelli Tiziano Manfredini Cristina Siligardi 《Journal of the American Ceramic Society》1997,80(12):3245-3249
A calcium magnesium aluminosilicate-based glass that contained 10 wt% of silicon carbide whiskers (SiC w ) as reinforcement was prepared by tape casting, followed by sintering either in a conventional furnace or in a microwave oven. The results were consistent with retardation of glass sintering through whisker bridging. The glass, by itself, was sintered to almost-full density at 750°C for 4 h by conventional furnace sintering; the best sintered composite, with an estimated density of ∼90%, was obtained at 800°C with a dwell time of 4 h. Sintering at a temperature of >800°C did not improve the densification but rather resulted in severe whisker oxidation. A reduced densification rate was observed for the samples that were sintered in nitrogen. By contrast, in the microwave oven, almost-full density for the glass and ∼95% of the theoretical density for the composite were obtainable at 850°C for 15 min, which represented a reduction of ∼10 h of the total processing time and a reduced SiC w oxidation. 相似文献
54.
The confined etchant layer technique has been applied to fabricate complex three-dimensional microstructures on nitinol for the first time. HF and HNO3 were locally and simultaneously electrogenerated at the mold surface to etch a nitinol workpiece. NaOH was used as an efficient scavenger to confine the etchant close to the mold. Cyclic voltammetry was employed to study the electrochemical behavior of a Pt electrode in the etching solution in order to choose an appropriate potential for etchant generation on the mold. The thickness of the confined etchant layer was estimated to be several micrometers by inspecting the deviation of the sizes of the etched spots from the sizes of those on the microelectrode. Thus, the composition of the electrolyte could be optimized for better etching precision. By optimizing the composition of the electrolyte, complex microstructures on a Pt-Ir mold bearing the logo “XMU” of Xiamen University were successfully fabricated on nitinol. The etched patterns were approximately negative copies of the mold, and the precision of duplication could easily reach the micrometer scale. 相似文献
55.
《Journal of the European Ceramic Society》2020,40(15):5226-5237
Polycarbonsilane (PCS) is an important precursor of silicon carbide (SiC) fibers and ceramics. The ceramic yield of PCS is relatively low, about 60 %, which may bring some deficiencies in its applications. In this work, a novel precursor cyano-polycarbosilane (PCSCN) is synthesized by hydrosilylation reaction between PCS and acrylonitrile using a rhodium-containing catalyst, although acrylonitrile is generally not easy for hydrosilylation. After introducing tiny amounts of cyano (-C≡N) groups into the PCS molecules, the ceramic yield of PCSCN can increase largely to over 80 %. The ceramization mechanism of PCSCN is investigated by FTIR, TG, XPS, ESR, NMR, Raman and XRD analyses. It is found that some crosslinking structures in PCSCN are formed between SiH bonds and CN groups from about 200 ℃, which can be responsible for the high ceramic yield. The existence of a little more N, O and free C elements in the pyrolysis products may inhibit the growth of crystalline β-SiC. Moreover, the PCSCN precursor can also be melt-spun into continuous fibers by tailoring its molecular weight and softening point. The oxidized PCSCN fiber with relatively low oxygen content can be pyrolyzed without melting, and the final SiC fiber with an oxygen content as low as 8.5 % is obtained. 相似文献
56.
为了将知识、信念、愿望和意图以及害怕、焦虑和自信对决策行为的影响的强烈程度进行形式化,把无穷值的卢卡斯维茨逻辑的真值取值范围从[0,1]扩展到[-1,1]。知识情感等级BDI主体的决策行为通过添加了具体条件的不同背景的不同测度来决定;知识情感等级BDI主体模型清晰地表示了主体的知识状态、心智状态和情感状态的不确定性;此模型可以轻易地向其他类型的主体进行推广。在给出了知识情感等级BDI模型的语言、语义以及此模型的不同背景之间的相互关系之后,对知识情感等级BDI主体的军事决策行为进行了实例分析。此研究旨在为分布式人工智能和军事仿真提供形式支持。 相似文献
57.
Nano-sized TiO2 powder was prepared by electrochemical dissolution of spongy titanium in an ethanol solution following direct hydrolysis of the electrolyte solution. Characterization of the electrochemical product revealed that Ti(OEt)4 was formed by anodic dissolution of spongy titanium in ethanol solution. X-ray diffraction and transmission electron microscope were, respectively, used to investigate the structure of TiO2. This study showed that nano-sized TiO2 prepared by this method has a structural and thermal stability with a narrow size distribution of 5-10 nm. The optimum electrochemical operating conditions established were a temperature of 333-343 K, current density of 400 A m−2 and faradaic efficiency of 86%. Experiments showed that this process might be recommended as a promising technique for synthesis of nano-sized powder. 相似文献
58.
ZHANG Yu-hua ZENG Xiao-ming 《计算机辅助绘图.设计与制造(英文版)》2014,(3):6-12
In this paper, we propose a face recognition approach-Structed Sparse Representation-based classification when the measurement of the test sample is less than the number training samples of each subject. When this condition is not satisfied, we exploit Nearest Subspaee approach to classify the test sample. In order to adapt all the eases, we combine the two approaches to an adaptive classification method-Adaptive approach. The adaptive approach yields greater recognition accuracy than the SRC approach and CRC_RLS approach with low ~ample rate on the Extend Yale B dataset. And it is more efficient than other two approaches. 相似文献
59.
Lihua Wang Xiaodong Yi Weizheng Weng Chunxi Zhang Xin Xu Huilin Wan 《Catalysis Letters》2007,118(3-4):238-243
By using the in situ IR spectroscopy, the superoxide species (O2−), characterized by the O–O stretching peak at 1130 cm−1, was detected on the SrF2/La2O3 catalyst at temperatures up to 973 K. The introduction of 18O2 isotope caused the 1130 cm−1 peak to shift to lower wavenumbers (1095 and 1064 cm−1), consistent with the assignment of the spectra to the superoxide species. A good correlation between the rate of the disappearance
of the O2− species and that of the formation of C2H4 was observed, suggesting that O2− was the active oxygen species responsible for the oxidative coupling of methane (OCM) on the SrF2/La2O3 catalyst. This conclusion was reinforced by the EPR experiments (gxx = 2.0001, gyy = 2.0045, gzz = 2.0685), showing that O2− was the only paramagnetic oxygen species detectable on the O2-preadsorbed SrF2/La2O3 catalyst. These results suggest that superoxide O2− can be a stable active oxygen species, whose role in the OCM reaction cannot be overlooked. 相似文献
60.
阮育娇 《上海电力学院学报》2010,(8)
采用金属键合技术结合激光剥离技术将GaN基LED从蓝宝石衬底成功转移到Si衬底上。利用X射线光电子谱(XPS)研究不同阻挡层对Au向GaN扩散所起的阻挡作用,确定键合所需的金属过渡层。利用多层金属过渡层,在真空、温度400℃和加压300 N下实现GaN基LED和Si的键合,通过激光剥离技术将蓝宝石衬底从键合结构上剥离下来,形成GaN基LED/金属层/Si结构。用金相显微镜及原子力显微镜(AFM)观察结构的表面形貌,测得表面粗糙度(RMS)为12.1 nm。X射线衍射(XRD)和Raman测试结果表明,衬底转移后,GaN基LED的结构及其晶体质量没有发生明显变化,而且GaN与蓝宝石衬底间的压应力得到了释放,使得Si衬底上GaN基LED的电致发光(EL)波长发生红移现象。 相似文献