A comparison between the advection-dispersion and the Kolmogorov-Dmitriev model for groundwater contaminant transport

The growing interest of the scientific and public community in environmental problems has sparked the undertaking of several activities of protection from pollutants, of remediation of contaminated sites and of design of deposits for toxic or radioactive waste. The implementation and management of these activities require the use of mathematical models for predicting the behaviour of the pollutant in the geosphere; of particular interest is the study of the transport of contaminants in the groundwater system, which provides an important pathway of return of the hazard to the biosphere.In this paper a comparison is made between the traditional advection-dispersion model, which is the most widely used model of groundwater contaminant transport, and a stochastic model based on the Kolmogorov-Dmitriev theory of branching processes. The behaviour of the two models is analysed in the case of transport with and without retardation of contaminant in the solid matrix and, in the latter case, both equilibrium and non-equilibrium processes are considered.The results obtained show that for non-reactive contaminant and for reactive contaminant under equilibrium, the Kolmogorov-Dmitriev parameters are related by simple relations with the advection-dispersion parameters. Moreover, the Kolmogorov-Dmitriev model is capable of describing more realistic non-equilibrium phenomena, that the advection-dispersion cannot treat. This capability arises from the fact of treating explicitly the reactions of contaminant interchange between the liquid and solid phases.     

Characterization of green composites from biobased epoxy matrices and bio-fillers derived from seashell wastes

The seashells, a serious environmental hazard, are composed mainly by calcium carbonate, which can be used as filler in polymer matrix. The main objective of this work is the use of calcium carbonate from seashells as a bio-filler in combination with eco-friendly epoxy matrices thus leading to high renewable contents materials. Previously obtaining calcium carbonate, the seashells were washed and grinded. The powder obtained and the resin was characterized by DSC, TGA, X-ray diffraction (XRD), X-ray fluorescence spectroscopy (XRF), and rheology plate-plate. The results show that addition of 30 wt.% of seashell bio-filler increase mechanical properties as flexural modulus (over 50%) and hardness Shore D (over 6%) and thermal properties as an increase around 13% in glass transitions temperature. The results show that the addition of calcium carbonate from seashells is an effective method to increase mechanical properties of bio-composite and to reduce the residue of seashells from industrial production.     

Using the genetic algorithm to enhance nonnegative matrix factorization initialization

Nonnegative matrix factorization (NMF) algorithms have been utilized in a wide range of real applications; however, the performance of NMF is highly dependent on three factors including: (1) choosing a problem dependent cost function; (2) using an effective initialization method to start the updating procedure from a near‐optimal point; and (3) determining the rank of factorized matrices prior to decomposition. Due to the nonconvex nature of the NMF cost function, finding an analytical‐based optimal solution is impossible. This paper is aimed at proposing an efficient initialization method to modify the NMF performance. To widely explore the search space for initializing the factorized matrices in NMF, the island genetic algorithm (IGA) is employed as a diverse multiagent search scheme. To adapt IGA for NMF initialization, we present a specific mutation operator. To assess how the proposed IGA initialization method efficiently enhances NMF performance, we have implemented state‐of‐the‐art initialization methods and applied to the Japanese Female Facial Expression dataset to recognize the facial expression states. Experimental results demonstrate the superiority of the proposed approach to the compared methods in terms of relative error and fast convergence.     

A silica supported Fe-Co bimetallic catalyst prepared by the sol/gel technique: Operating conditions, catalytic properties and characterization

A Co/Fe catalyst was prepared using the sol/gel technique in order to study its catalytic activity and selectivity in the Fischer-Tropsch synthesis. The effect of a range of operation variables such as pressure, temperature and H₂/CO molar feed ratio on the catalytic performance of 40%Fe/60%Co/15 wt.%SiO₂/1.5 wt.%K catalyst was investigated. It was found that the optimum operating conditions is a H₂/CO = 2/1 molar feed ratio at 350 °C temperature and 3 bar pressure. Characterization of both precursor and calcined catalysts was carried out using XRD, SEM, EDS, TPR, BET surface area measurements and thermal analysis methods such as TGA and DSC. It was observed that all of the different operation variables influenced the structure, morphology and catalytic performance of the catalysts.     

Electrospray modeling of highly viscous and non‐Newtonian liquids

The electrohydrodynamic spraying of highly viscous and non‐Newtonian aqueous solutions of sodium alginate were experimentally modeled with high direct‐current electric fields. A prototype electrospray setup comprising a nozzle connected to a high‐voltage counter electrode connected to earth and a curing facility to solidify the droplets was used. The main aim was initially set to extend the knowledge of the electrospray to highly viscous liquids, where shear thinning was the main rheological feature of fluid flow through the nozzle of the spray system. To model the process, the effects on the size of beads of the electric field strength, nozzle diameter, flow rate, and the material properties of density, viscosity, surface tension, and electrical conductivity were characterized. The size distribution of the beads was obtained after the droplets were cured in a calcium chloride solution with an image analyzer system. The rheological study, carried out on different concentrations of alginate solution (i.e., 1–3 w/v %), showed a significant reduction in the viscosity as a function of the shear rate. Considering the shear‐thinning behavior of the solutions, in the modeling we applied the viscosity at the operational shear rate in the nozzle. Four dimensionless groups were introduced to obtain the relationship between the dimensionless group representing diameter and the other groups in the dripping and jet modes with statistical analysis of the experimental data. The proposed equations correlated the size of beads within ±10% deviations as compared to the experimental results. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Effects of Y2O3 on the microstructure and wear resistance of cobait-based alloy coatings deposited by plasma transferred arc process

Cobalt-based alloys with different Y2O3 contents were deposited on Q235A-carbon steel using plasma transferred arc （PTA） welding machine. The effect of Y2O3 on the microstructure and wear resistance properties of the cobait-based alloys were investigated using an optical microscope, a scanning electron microscope （SEM）, X-ray diffraction （XRD）, and transmission electron microscopy （TEM）. It was found that a cobalt-based solid solution with a face-centered cubic crystal structure was presented accompanied by the secondary phase M7C3 with a hexagonal crystal structure in the Y2O3-free cobalt-based alloy coating. Several stacking faults exist in the cobalt-based solid solution. The addition of Y2O3 leads to the existence of the Y2O3 phase in the Y2O3-modified coatings. Though stacking fault exists in the Y2O3-modified coatings, its density increases. The addition of Y2O3 can refine the microstructure and can increase the wear resistance properties when its contents are less than or equal to 0.8 wt.%. However, further increase of its contents will lead to the agglomeration of undissolved Y2O3 particles at the γ-Co grain boundary, and will lead to a coarse microstructure and lower wear resistance properties.