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21.
This paper is devoted to fault diagnosis of nonlinear analog CMOS circuits designed in nanometer technology. A method that allows diagnosing a single soft short and local parameter variations, occurring simultaneously, is developed. The method exploits DC measurements at limited number of points in the test phase. The diagnostic test leads to a system of nonlinear algebraic equations, not given in explicit analytical form, that may have multiple solutions. The solutions determine the sets comprising one soft short value and several values of the preliminary selected parameters. To find them an extended simplicial algorithm is developed. It allows tracing different space curves, leading to different solutions. Moreover, a procedure for selecting the actual solution from among the obtained ones is proposed. For illustration a representative numerical example is discussed in detail. 相似文献
22.
《International Journal of Hydrogen Energy》2019,44(7):3824-3833
The displacement chromatography technique with a tri-column system was used to reduce the protium (H) in the deuterium-tritium (D-T) mixture, and the separation performance was studied numerically by ANSYS FLUENT. The experimental results showed that the isotopic abundance of H in the D-T mixture dropped from 2.7% to an acceptable level of 0.88%. The simulation results showed that a lower porosity (θ) of the filling material made a higher separation factor, but a lower separation efficiency. The velocity of the product gas at the outlet of the separation column approximately had a linear relationship with θ5/3/(1-θ)2, which partly indicated the pore diffusion resistance. The mixed gas could contact the filling materials more sufficiently under a lower flow rate resulting in a lower protium concentration in the product gas. The separation column with a thin and long shape had a better separation performance and a lower product gas loss. 相似文献
23.
《International Journal of Hydrogen Energy》2019,44(5):2960-2975
The hydrogen adsorption capacity of dual-Ti-doped (7, 7) single-walled carbon nanotube (Ti-SWCNTs) has been studied by the first principles calculations. Ti atoms show different characters at different locations due to local doping environment and patterns. The dual-Ti-doped SWCNTs can stably adsorb up to six H2 molecules through Kubas interaction at the Ti2 active center. The intrinsic curvature and the different doping pattern of Ti-SWCNTs induce charge discrepancy between these two Ti atoms, and result in different hydrogen adsorption capacity. Particularly, eight H2 molecules can be adsorbed on both sides of the dual-Ti decorated SWCNT with ideal adsorption energy of 0.198 eV/H2, and the physisorption H2 on the inside Ti atom has desirable adsorption energy of 0.107 eV/H2, ideal for efficient reversible storage of hydrogen. The synergistic effect of Ti atoms with different doping patterns enhances the hydrogen adsorption capacity 4.5H2s/Ti of the Ti-doped SWCNT (VIII), and this awaits experimental trial. 相似文献
24.
《International Journal of Hydrogen Energy》2019,44(16):8178-8187
Macaroon-like FeCo2O4 nanomaterial was prepared and used as electrocatalyst in direct glucose alkaline fuel cell (DGAFC), which exhibited high catalytic activity towards glucose oxidation reaction. Maximum power density of 35.91 W m−2 was achieved in the DGAFC equipped with a FeCo2O4 modified activated carbon (AC) anode, which was almost 151% higher than the control. Physical and electrochemical characterizations were performed to provide further understanding of the origin of its high activity. Our results show that the introduction of FeCo2O4 into the AC anode remarkably increase the exchange current density and reduce the charge transfer resistance. It is supposed that there is a synergistic effect between Fe (III) and Co (III), which accelerates electron transfer from glucose to external circuits. This study will promote the development of cost effective and environmentally benign catalysts for electrochemical energy applications. 相似文献
25.
《International Journal of Hydrogen Energy》2019,44(39):21569-21576
As is reported, the photocatalytic activity will increase significantly when TiO2 nanoparticles are agglomerated into TiO2 nanofibers (NFs), but the photocatalytic activity enhancement mechanisms are still not fully understood. As is widely accepted, the optical absorption process plays a key role in photocatalysis, and it can even be said that the optical absorption capability of the photocatalyst directly determines its photocatalytic activity, while the influence of the structure on the optical absorption characteristics of TiO2 has largely been ignored in the existing explanations. In this paper, optical simulations are introduced into analyzing optical characteristics of TiO2 Nanofibers with which, the photocatalytic activity enhancement mechanism is further discussed, and a photocatalytic activity enhancement mechanism of TiO2 Nanofibers is proposed. 相似文献
26.
《International Journal of Hydrogen Energy》2019,44(43):23936-23946
Construction of transition metal selenides with high electrocatalytic performance is of significant importance, but it is still a challenge to develop the corresponding counter electrodes (CEs) by an electrodeposition technique. In the present work, nickel cobalt selenide (NixCoySe) films are prepared in situ on fluorine-doped tin oxide (FTO) glasses through a potential reversal electrodeposition technique. The morphology and electronic structure of NixCoySe films can be tuned by controlling the Ni/Co molar ratio in electroplating solution. Specially, NixCoySe-6 film (the Ni/Co molar ratio of 1:1) with the optimized interaction between the Ni and Co elements displays numerous particles composed of sheets attached with nanocrystals, resulting in the more electrocatalytic active sites. Benefiting from the unique morphology and optimized synergistic effect, NixCoySe-6 CE exhibits superior electrocatalytic activity for the triiodide reduction. Then, the dye-sensitized solar cell (DSC) fabricated by NixCoySe-6 CE has demonstrated a power conversion efficiency (PCE) over 7.40%, which is higher than that of platinum (Pt)-based device (6.32%). Furthermore, NixCoySe-6 array CE is also prepared by using polystyrene array as template. The PCE of the DSC with NixCoySe-6 array CE reaches its maximum value of 7.64% and 20.9% larger than that of Pt-based device. 相似文献
27.
《Journal of Materials Processing Technology》2014,214(4):775-783
The stress relaxation behavior of age-forming for an Al–Zn–Mg–Cu alloy was studied using a designed device that can simulate the age forming process. The mechanism of stress relaxation was also revealed through calculating thermal activation parameters and analyzing the microstructures. The results suggested that the stress relaxation behavior of the Al–Zn–Mg–Cu alloy in the simulated age-forming process can be divided into three stages according to the stress level. The three stages of stress relaxation are: (i) the initial high stress stage, (ii) the subsequent middle stress transition stage and (iii) the last low stress equilibrium stage, respectively. The deformation activation energies are 132 kJ/mol in the initial high stress stage, 119 kJ/mol in the subsequent middle stress transition stage and 91 kJ/mol in the last low stress equilibrium stage, respectively. The analysis of the thermal activation parameters and microstructures revealed that dislocation creep was the dominant deformation mechanism in the initial and subsequent stages of the stress relaxation; whereas diffusion creep is the mechanism in the last stage of the stress relaxation. Additionally, a special threshold stress phenomena was present in the stress relaxation of the age-forming process, which was scribed to the interaction between precipitation and dislocation in the Al–Zn–Mg–Cu alloy 相似文献
28.
The absolute free energy difference of binding (ΔG) between neuraminidase and its inhibitor was evaluated using fast pulling of ligand (FPL) method over steered molecular dynamics (SMD) simulations. The metric was computed through linear interaction approximation. Binding nature was described by free energy differences of electrostatic and van der Waals (vdW) interactions. The finding indicates that vdW metric is dominant over electrostatics in binding process. The computed values are in good agreement with experimental data with a correlation coefficient of R = 0.82 and error of σΔGexp = 2.2 kcal/mol. The results were observed using Amber99SB-ILDN force field in comparison with CHARMM27 and GROMOS96 43a1 force fields. Obtained results may stimulate the search for an Influenza therapy. 相似文献
29.
《中国有色金属学会会刊》2016,26(11):2900-2909
The thermal expansion behavior, microhardness and electrochemical corrosion resistance of Au52Cu27Ag17–x(NiZn0.5)x (x=0, 6 and 12) alloys were investigated by dilatometer (DIL), microhardness tester, electrochemical workstation, X-ray diffractometer (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). With increasing x, the relative length expansion and DIL maximum temperature Tl m (i.e., thermal stability) of the alloys increase in thermal expansion measurements, which can be explained by the change of the atomic binding energy, mismatch entropy together with phase transformation. With the increase of x, the microhardness can be improved, but the corrosion resistance decreases; in addition, the anodic peak current densities of polarization curves decrease, which are related closely with the solid solution degree and dissolution of Ag, Ni and Zn alloying elements in Cl−-containing solution. 相似文献
30.
Lidong Wang Zongwei Xue Yingjie Qiao W.D. Fei 《Materials Science and Engineering: B》2012,177(11):873-876
A β-eucryptite/copper composite was fabricated by spark plasma sintering process. The thermal expansion behaviors of Cu matrix of the composite were studied by in situ X-ray diffraction during heating process. The results show that Cu matrix exhibits anisotropic thermal expansion behaviors for different crystallographic directions, the expansion of Cu{1 1 1} plane is linear in the temperature range from 20 °C to 300 °C and the expansion of Cu{2 0 0} is nonlinear with a inflection at about 180 °C. The microstructures of Cu matrix before and after thermal expansion testing were investigated using transmission electronic microscope. The anisotropic thermal expansion behavior is related to the deformation twinning formed in the matrix during heating process. At the same time, the deformation twinning of Cu matrix makes the average coefficient of thermal expansion of the composite increase. 相似文献