过程工业大数据建模研究展望

人们对大数据的认识已从"3Vs" (Volume-大容量; Variety-多样性; Velocity-处理实时性)、"4Vs" ("3Vs"与Value-价值)、到现今的"5Vs" ("4Vs"与Veracity-真实性).在此背景下, 首先分析过程工业大数据的"5Vs"特性; 接下来, 综述现有数据建模方法, 并结合过程工业大数据特有性质 (包括:多层面不规则采样性、多时空时间序列性、不真实数据混杂性) 论述现有数据建模方法应用于工业大数据建模时的局限; 最后, 探讨过程工业大数据建模有待研究的问题, 包括:1) 多层面不规则采样数据的潜结构建模; 2) 用于事件发现、决策和因果分析的多时空时间序列数据建模; 3) 含有不真实数据的鲁棒建模; 4) 支持实时建模的大容量数据计算架构与方法.     

Industrial architectural assessment using TARA

Scenario based architectural assessment is a well-established approach for assessing architectural designs. However scenario-based methods are not always usable in an industrial context, where in our experience, they can be perceived as complicated and expensive to use. In this paper we explore why this may be the case and define a simpler technique called TARA, which has been designed for use in situations where scenario based methods are unlikely to be successful. The method is illustrated through an experience report that explains how it was applied to the assessment of two quantitative financial analysis systems, and its strengths, weaknesses and relationship to other methods are briefly discussed.     

CFD simulation of an industrial hydrocyclone with Eulerian–Eulerian approach: A case study

In the present study, a three-dimensional computational fluid dynamics simulation together with experimental field measurements was applied to optimize the performance of an industrial hydrocyclone at Sarcheshmeh copper complex. In the simulation, the Eulerian–Eulerian approach was used for solid and liquid phases, the latter being water. In this approach, nine continuous phases were considered for the solid particles with different sizes and one continuous phase for water. The continuity and momentum equations with inclusion of buoyancy and drag forces were solved by the finite volume method. The k–ɛ RNG turbulence model was used for modeling of turbulency. There was a good agreement between the simulation results and the experimental data. After validation of the model accuracy, the effect of inlet solid percentage, pulp inlet velocity, rod inserting in the middle of the hydrocyclone and apex diameter on hydrocyclone performance was investigated. The results showed that by decreasing the inlet solid percentage and increasing the pulp inlet velocity, the efficiency of hydrocyclone increased. Decreasing the apex diameter caused an increase in the hydrocyclone efficiency.     

A sol-powder coating technique for fabrication of yttria stabilised zirconia

Yttria stabilised zirconia has been prepared using a simple sol-powder coating technique. The polymeric yttria sol, which was prepared using 1,3 propanediol as a network modifier, was homogeneously mixed with nanocrystalline zirconia powder and it showed a dual function: as a binder which promoted densification and a phase modifier which stabilised zirconia in the tetragonal and cubic phases. Thermal analysis and X-ray diffraction revealed that the polymeric yttria sol which decomposed at low temperature into yttrium oxide could change the m → t phase transformation behaviour of the zirconia, possibly due to the small particle size and very high surface area of both yttria and zirconia particles allowing rapid alloying. The sintered samples exhibited three crystalline phases: monoclinic, tetragonal and cubic, in which cubic and tetragonal are the major phases. The weight fractions of the individual phases present in the selected specimens were determined using quantitative Rietveld analysis.     

Sliding wear behavior of copper alloy contact wire against copper-based strip for high-speed electrified railways

This paper reports the study of the sliding wear behavior of the Cu–Ag–Cr wire. Cu–Ag–Cr alloy is a promising contact wire material for high-speed electrified railways, which has an excellent combination of mechanical strength and electrical conductivity. Wear tests were conducted under laboratory with a special sliding wear apparatus, which simulated the tribological conditions of sliding current collectors on overhead wires in the railway system. The Cu–Ag–Cr alloy wire was slid against a copper-based powder metallurgy strip under unlubricated conditions. The same strip as those in the train systems were used. Worn surfaces of the Cu–Ag–Cr alloy wire were analyzed by scanning electron microscopy (SEM) and energy dispersive X-ray spectrum (EDS). Within the studied range of electrical current, normal pressure and sliding speed, the wear rate increased with the increasing electrical current and the sliding distance. Compared with a Cu–Ag contact wire under the same conditions, the Cu–Ag–Cr alloy wire had much better wear resistance. Adhesive wear, abrasive wear and arc erosion were the dominant mechanisms during the electrical sliding processes.     

On the stability of conventional and nano-structured carbon-based catalysts in the oxidative dehydrogenation of ethylbenzene under industrially relevant conditions

Relevant carbon-based materials, home-made carbon–silica hybrids, commercial activated carbon, and nanostructured multi-walled carbon nanotubes (MWCNT) were tested in the oxidative dehydrogenation of ethylbenzene (EB). Special attention was given to the reaction conditions, using a relatively concentrated EB feed (10 vol.% EB), and limited excess of O₂ (O₂:EB = 0.6) in order to work at full oxygen conversion and consequently avoid O₂ in the downstream processing and recycle streams. The temperature was varied between 425 and 475 °C, that is about 150–200 °C lower than that of the commercial steam dehydrogenation process. The stability was evaluated from runs of 60 h time on stream. Under the applied reactions conditions, all the carbon-based materials are apparently stable in the first 15 h time on stream. The effect of the gasification/burning was significantly visible only after this period where most of them fully decomposes. The carbon of the hybrids decomposes completely rendering the silica matrix and the activated carbon bed is fully consumed. Nano structured MWCNT is the most stable; the structure resists the demanding reaction conditions showing an EB conversion of ∼30% (but deactivating) with a steady selectivity of ∼80%. The catalyst stability under the ODH reaction conditions is predicted from the combustion apparent activation energies.     

Interstitial effects of B addition on the metamagnetic transition and magnetocaloric effect in tetragonal Cu2Sb-type Mn1.95Cu0.05Sb alloys

Mn_1.95Cu_0.05SbB_x (x = 0, 0.06 and 0.1) alloys had been prepared and B interstitial effects on metamagnetic transition were studied. The metamagnetic transition temperature was reduced and thermal hysteresis was widened by higher B concentration. The saturation magnetization and the magnetic entropy change were increased by moderate amount of B addition. However, too high B composition led into the sluggish metamagnetic transition. By relating with crystallographic structure, our results further indicated that the electron density of the atoms at MnⅡ position plays critical role on influencing the metamagnetic transition in tetragonal Cu₂Sb-type Mn_1.95Cu_0.05Sb alloys.     

Application of near infrared sensors to preconcentration of hydrothermally-formed copper ore

Near infrared sensors can be a very useful technique for the qualitative analysis of complex ores, and thus could be useful for the preconcentration of ores. In this paper, individual particles of hydrothermally-formed copper ore sampled from a mine in the Los Pozos mining district, northern Chile, were classified as product, middling and waste based on their near infrared response. The classification of copper bearing minerals (product) from gangue (waste) was considered for vibration combination bands at longer wavelengths from 2000 to 2400 nm. This region exhibits characteristic features for carbonates and hydroxyl gangue bearing minerals. The near infrared features at 1400 and 1900 nm were not considered favourable for classification and subsequent discrimination because they can be influenced by moisture and other environmental factors and are easily suppressed by iron-rich minerals.Two near infrared preconcentration strategies were applied for particle discrimination. Results indicate that targeting only the calcite (carbonate) dominated particles for discrimination as waste provided the best option for preconcentration. The near infrared discrimination analysis correlates well with mineralogical (QEMSCAN® and XRD) and elemental (XRF) data classification. The results indicate that near infrared spectroscopy is a suitable preconcentration method for supergene copper ore.     

Recent progress in magnetocaloric effect: Mechanisms and potential applications

Recent results in understanding of the magnetocaloric effect (MCE) mechanisms in the framework of thermodynamic approach are regarded and discussed. Importance of relation between ΔS_MT (magnetic entropy change at constant temperature) and ΔS_MH (magnetic entropy change at constant field) and it influence on MCE value is considered. The main contributions to the MCE are discussed. The importance of further development of models of interactions between magnetic and structural subsystems in vicinity of magnetic phase transitions is stressed. It is stated that the present level of MCE parameters (in particular, adiabatic temperature change) can be increased up to 3 times. The necessity of investigation of MCE parameters in dynamic mode and development of new experimental methods and apparatuses for MCE measurements is discussed. The most obvious application for MCE for today is magnetic refrigeration, but MCE also can be used for other applications such as medicine (hyperthermia, drug delivering), etc., which are regarded.     

Numerical analysis of hydrocyclones with different vortex finder configurations

This paper presents a numerical study of the multiphase flow and performance of hydrocyclone by means of two-fluid model, with special reference to the effects of diameter, length and shape of vortex finder at a wide range of feed solids concentrations. The considered shapes include the conventional cylindrical style and the new conical and inverse conical styles. The simulation results are analysed with respect to cyclone flow and performance in term of cut size d₅₀, water split, Ecart probable E_p and inlet pressure drop. It is shown that when vortex finder diameter or shape varies, a compromised optimum performance can be identified, resulting in relatively small inlet pressure drop, E_p, and water split. Both d₅₀ and E_p are more sensitive to feed solids concentration than inlet pressure drop and water split. Overall, the effect of vortex finder length on the separation efficiency of particles is much less significant than diameter and shape, which shows opposite trends at low and high feed solids concentrations. All these results can be well explained using the predicted tangential and axial velocities and solid volume fraction.