金属镍电沉积中枝晶分形生长的研究

将分形几何与电化学原理相结合,通过改进的有限扩散凝聚模型(diffusion-limited aggregation,DLA),采用基于Microsoft Visual C 6.0的Open GL编程,对点电极为阴极进行二维电沉积时沉积产物的形貌进行了模拟.以环形金属镍为阳极,石墨为阴极,用自行设计的试验设备制备了二维的金属镍枝晶以验证模拟结果.结果表明,在保持电压恒定的条件下,镍沉积层的形貌特征为具有分形结构的枝晶,这与采用DLA模型模拟所得的二维枝晶形貌具有相似性,表明该模型对枝晶电沉积的实验研究具有很好的指导意义.     

Nanotribological study of PECVD DLC and reactively sputtered Ti containing carbon films

Amorphous carbon film, also known as DLC film, is a promising material for tribological application. It is noted that properties relevant to tribological application change significantly depending on the method of preparation of these films. These properties are also altered by the compositions of these films. DLC films are well known for their self-lubricating properties, as well. In view of this, the objective of the present work is to compare the tribological properties of diamond like carbon (DLC) film obtained by plasma enhanced chemical vapour deposition (PECVD) with the Ti containing nanocrystalline carbon (Ti/a-C:H) film obtained by unbalanced magnetron sputter deposition (UMSD) in nN load range. Towards that purpose, DLC and Ti/a-C:H films are deposited on silicon substrate by PECVD and UMSD processes respectively. The microstructural features and the mechanical properties of these films are determined by scanning electron microscope (SEM), transmission electron microscope (TEM) and nano indenter. The surface topographies and the friction force surfaces of these films are evaluated by means of an atomic force microscope (AFM). The results show that although PECVD DLC film has higher elastic modulus and higher hardness than UMSD Ti/a-C:H film, the surface roughness and the friction coefficient of PECVD film is significantly higher than that of UMSD Ti/a-C:H film.     

基础影响下车载飞轮电池动态性能的联合仿真分析

以车载飞轮电池为研究对象,利用ADAMS软件建立了飞轮转子与等效基础的机械模型,并利用MATLAB软件建立了相应的不完全微分PID控制器模型.通过联合仿真分析了基础的加速、减速、转弯和爬坡运动,以及因路面不平整引起的基础纵向振动、横向振动和俯仰振动对高速飞轮转子系统动态性能的影响.仿真结果表明,基础的不同运动状态均会对高速飞轮转子的稳定运行产生显著影响,仿真分析结果可对车载飞轮电池的设计提供有益参考.     

数控超声磨削陶瓷叶片型面刀位轨迹计算

介绍了陶瓷超声磨削加工现状,建立了平行直纹面数学模型.分析了用圆柱磨轮四轴数控超声磨削平行直纹面时原理误差,并提出减小误差的措施,计算出磨轮空间轨迹,并进行陶瓷叶片型面超声磨削加工工艺试验.试验结果表明,超声磨削加工陶瓷叶片型面是可行的,所完成的刀位计算可有效减小原理误差.     

GM(1,1)模型在虚拟仪器测量过程控制中的应用

虚拟仪器的测量过程控制是保证测量数据有效的重要手段,利用灰色系统GM(1,1)模型对虚拟仪器的测量过程进行控制,由少量数据信息得到未来的预期测量结果,通过与核查标准的测量结果相比较来判别测量过程是否受控.论文给出了测量过程控制判别限、适用灰色系统GM(1,1)模型的条件以及模型精度检验判据.     

“箱中箱”结构立滑板的有限元分析及其优化设计

为了提高机床"箱中箱"结构立滑板的动静态特性,增强机床整机的刚性,在CAD/CAE集成仿真设计平台下,对立滑板分别进行静力学和模态分析,结果表明Y、X向的静刚度有待提高,凸振和摆动较为明显。对此,设计4种改进的立滑板,提出基于模糊变换的动静态性能综合评价法,并从中优选出最佳的改进方案。对改进后的立滑板进行动态优化设计,得到最优的立滑板结构。研究表明:对立滑板进行结构改型和尺寸优化设计能有效地提高动静态性能。     

Refrigerated cooling air cutting of difficult-to-cut materials

One approach to enhance machining performance is to apply cutting fluids during cutting process. However, the use of cutting fluids in machining process has caused some problems such as high cost, pollution, and hazards to operator's health. All the problems related to the use of cutting fluids have urged researchers to search for some alternatives to minimize or even avoid the use of cutting fluids in machining operations. Cooling gas cutting is one of these alternatives. This paper investigates the effect of cooling air cutting on tool wear, surface finish and chip shape in finish turning of Inconel 718 nickel-base super alloy and high-speed milling of AISI D2 cold work tool steel. Comparative experiments were conducted under different cooling/lubrication conditions, i.e. dry cutting, minimal quantity lubrication (MQL), cooling air, and cooling air and minimal quantity lubrication (CAMQL). For this research, composite refrigeration method was adopted to develop a new cooling gas equipment which was used to lower the temperature of compressed gas. The significant experimental results were: (i) application of cooing air and CAMQL resulted in drastic reduction in tool wear and surface roughness, and significant improvement in chip shape in finish turning of Inconel 718, (ii) in the high-speed milling of AISI D2, cooling air cutting presented longer tool life and slightly higher surface roughness than dry cutting and MQL. Therefore, it appears that cooling air cutting can provide not only environment friendliness but also great improvement in machinability of difficult-to-cut materials.     

Interfacial reaction between cubic boron nitride and Ti during active brazing

Thermodynamic and reaction process analyses were performed to understand the joining characteristic during high temperature brazing between cubic boron nitride (CBN) grit and a silver-base filler alloy containing Ti as an active element. Experimental information on the microstructure of the brazed joint, the composition of the interface, and the shape of the compounds formed on the surface of the grit was obtained by scanning electron microscopy, energy-dispersive x-ray, and x-ray diffraction. The results indicate that Ti in the molten filler alloy facilitated good wetting between the solid CBN crystals and braze filler alloy. The transition layer formed by the interaction of TiN and TiB₂ was one of the key factors in joining the CBN and steel substrate.     

Synthesis and characterization of LiNi0.95-xCoxAl0.05O2 for lithium-ion batteries

Samples of LiNi0.95-xCoxAl0.05O2 （x = 0.10 and 0.15） and LiNiO2, synthesized by the solid-state reaction at 725℃ for 24 h from LiOH-H2O, Ni2O3, Co2O3, and AI（OH）3 under an oxygen stream, were characterized by TG-DTA, XRD, SEM, and electrochemical tests. Simultaneous doping of cobalt and aluminum at the Ni-site in LiNiO2 was tried to improve the cathode performance for lithium-ion batteries. The results showed that co-doping （especially, 5 at.% A1 and 10 at.% Co） definitely had a large beneficial effect in increasing the capacity （186.2 mA.h/g of the first discharge capacity for LiNio.s.42OoaoAlo.0502） and cycling behavior （180.1 mA-h/g after 10 cycles for LiNio.85CooaoAlo.osO2） compared with 180.7 mA.h/g of the first discharge capacity and 157.7 mA.h/g of the tenth discharge capacity for LiNiO2, respectively. Differen- tial capacity versus voltage curves showed that the co-doped LiNio.95_xCoxmlo.osO2 had less intensity of the phase transitions than the pristine LiNiO2.     

Development of a noise prediction software NASEFA and its application in medium-to-high frequency ranges

For the analysis of noise problems in medium-to-high frequency ranges, the energy flow boundary element method (EFBEM) has been studied. EFBEM is numerical analysis method of energy flow analysis (EFA), and solves energy governing equations using a boundary element method in complex structures. Based on EFBEM, a noise prediction software, “noise analysis system by energy flow analysis” (NASEFA), was developed. For effective maintenance, NASEFA is composed of three main modules: the translator, the model converter, and the main solver. The translator changes the FE model to the NASEFA BE model, and the model converter changes the BE model to an EFBE model, including various data, such as structural materials, medium properties, sources, and boundary conditions. NASEFA then solves the acoustic energy density and intensity on boundary and in the field. Moreover, it analyzes interior and exterior noise problems for single and multiple domains in two and three dimensions. Finally, for the validation of the software developed, interior and exterior noise predictions of various structures were performed. The results obtained with NASEFA were compared with those of the commercial SEA program and experiment. From these comparative studies, the usefulness of NASEFA was established.