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《International Journal of Hydrogen Energy》2023,48(32):11899-11913
The development of sustainable processes for the recycling of plastic is a major environmental issue to reduce the pollution by this kind of waste. The electro-oxidation of plastic wastes in electrolysers powered by renewable energies is a promising option to produce hydrogen at low temperature while diminishing the energy demand compared to Oxygen Evolution Reaction (OER). Poly (methyl-methacrylate) (PMMA) particles, a widely used polymer, were dissolved (0.1–2% wt.) in an isopropanol(IPA)/H2O binary solvent and electro-oxidized on Pt/C-based electrodes in a liquid batch electrochemical cell at 70 °C in acidic media. Despite the dissolution strategy, polymer macromolecules partially block the accessibility of the active sites of a commercial electrode and strongly degrades its electrochemical performances mainly linked to IPA electro-oxidation. The preparation of a more porous electrode supported on carbon paper was found to strongly hinder this deactivation. Furthermore, the electrooxidation of PMMA or PMMA-derived molecules can be performed during cyclic voltammetries up to 1.4 V and chrono-amperometries at 1.4 V. 相似文献
33.
J. García-Nieto E. Alba A. Carolina Olivera 《Engineering Applications of Artificial Intelligence》2012,25(2):274-283
Congestion, pollution, security, parking, noise, and many other problems derived from vehicular traffic are present every day in most cities around the world. The growing number of traffic lights that control the vehicular flow requires a complex scheduling, and hence, automatic systems are indispensable nowadays for optimally tackling this task. In this work, we propose a Swarm Intelligence approach to find successful cycle programs of traffic lights. Using a microscopic traffic simulator, the solutions obtained by our algorithm are evaluated in the context of two large and heterogeneous metropolitan areas located in the cities of Málaga and Sevilla (in Spain). In comparison with cycle programs predefined by experts (close to real ones), our proposal obtains significant profits in terms of two main indicators: the number of vehicles that reach their destinations on time and the global trip time. 相似文献
34.
《International Communications in Heat and Mass Transfer》2006,33(9):1079-1087
The transient problem for fully developed mixed convection considering the effect of viscous dissipation is investigated for the laminar flow in a parallel-plate vertical channel by means of the Network Simulation Method. The thermal boundary condition considered is a forced convection. The combined effects of viscous dissipation and buoyancy forces are determined in the solutions for different time intervals, being obtained in all the cases, the velocity field and the temperature field. The times taken to reach steady-state is obtained in all the cases. The numerical procedure employed, which satisfies the conservation law for the heat flux variable and the uniqueness law for temperature, also permits the direct visualisation and evolution of the local and/or integrated transport variables at any point or section of the medium. 相似文献
35.
分析了基于AutoCAD绘图软件进行图纸文字信息提取的几种常用方法,提出了实现正确构建产品装配明细(BOM)的基本思路。详细阐述了提取带有属性值的标题栏及明细栏图块信息的实现方法和程序控制流程,并给出关键程序代码。依据企业实际审图步骤和审图内容,总结了由计算机辅助审核的实现方案和审核流程。根据产品明细项备注标示,实现自动进行明细项分类,能够快速准确生成产品综合明细、分类明细及图样目录等报表,并能导出符合企业格式化要求的电子表格文件。 相似文献
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通过推出试验研究型钢翼缘外侧焊短钢筋时与轻骨料混凝土的黏结滑移性能。短钢筋采用垂直焊和水平焊两种方式,间距设置了100 mm和200 mm。试验中考虑未设置剪力连接件的对比试件,试件均发生推出破坏。根据实测的荷载、加载端滑移数据建立二者的关系模型,分析特征黏结强度和特征滑移值。研究结果表明:剪力连接件的设置不宜过密,宜垂直于型钢翼缘焊接;型钢翼缘外侧焊短钢筋没有提高试件的黏结强度,但增加了试件抵抗滑移的能力;设计中应单独考虑自然黏结强度或剪力连接件传递剪力,不能对二者进行叠加。 相似文献
38.
生物工程综合性专业实验的教学改革与实践 总被引:4,自引:1,他引:3
生物工程专业是以培养应用型人才为目标。从改变实验设置方式、优化实验教学体系及教学内容、改进教学方法入手,对生物工程综合性专业实验进行教学改革与实践,取得了良好的教学效果。 相似文献
39.
Gang Xue Fengxia Liu Ying Wang Kaixun Huang 《Journal of the American Oil Chemists' Society》2009,86(1):77-82
Orthogonal experiments were employed to optimize the correlated parameters of reduction, sulfonation, substitution and hydrolysis.
These reactions were used to convert γ-linolenic acids into dihomo-γ-linolenic acids (DGLA). For the reduction, the best reaction
conditions were at 35 °C for 4.5 h with LiAlH4 and γ-linolenic acid (in the ratio of 40 g:100 g); for the sulfonation, reaction at 29 °C for 3.5 h with 150 g γ-linolenic
alcohol and 65 mL mesyl chloride, then the water phase being extracted with dichloromethane (3 × 100 mL); for the substitution,
the reaction at 80 °C for 2.5 h with metallic sodium and sulfonate (at a ratio of 8 g:100 g); and for the hydrolysis, reaction
at 80 °C for 2.5 h with NaOH and dihomo dioate (at a ratio of 50 g:100 g). The four reactions gave yields that exceeded 90%
for each step. Finally, crystallization and decarboxylation provided DGLA in an overall yield of 60% and >95% purity. 相似文献
40.